• Title/Summary/Keyword: Rapid Mixing

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One-pot Syntheses of Metallic Hollow Nanoparticles of Tin and Lead

  • Lee, Gae-Hang;Choi, Sang-Il;Lee, Young-Hwan;Park, Joo-T.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1135-1138
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    • 2009
  • Hollow Sn and Pb nanoparticles have been prepared by a rapid injection of an aqueous solution of $SnCl_2$- poly(vinylpyrrolidone) (PVP, surfactant) and $Pb(OAc)_2${\cdot}$3H_2O-PVP$ into an aqueous solution of sodium borohydride (reducing agent) in simple, one-pot reaction at room temperature under an argon atmosphere, respectively. The two hollow nanoparticles have been fully characterized by TEM, HRTEM, SAED, XRD, and EDX analyses. Upon exposure to air, the black Pb hollow nanoparticles are gradually transformed into a mixture of Pb, litharge (tetragonal PbO), massicot (orthorhombic PbO), and $Pb_5O_8$. The order and speed of mixing of the reactants between the metal precursor-PVP and the reductant solutions and stoichiometry of all the reactants are crucial factors for the formation of the two hollow nanocrystals. The Sn and Pb hollow nanoparticles were produced only when 1:(1.5-2) and 1:3 ratios of the Sn and Pb precursors to $NaBH_4$ were employed with a rapid injection, respectively.

Improvement of Cooling Technology through Atmosphere Gas Management

  • Renard, Michel;Dosogne, Edgar;Crutzen, Jean-Pierre;Raick, Jean-Marc;Ma, Jia Ji;Lv, Jun;Ma, Bing Zhi
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.217-222
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    • 2009
  • The production of advanced high strength steels requires the improvement of cooling technology. The use of high cooling rates allows relatively low levels of expensive alloying additions to ensure sufficient hardenability. In classical annealing and hot-dip galvanizing lines a mixing station is used to provide atmosphere gas containing 3-5% hydrogen and 97-95% nitrogen in the various sections of the furnace, including the rapid cooling section. Heat exchange enhancement in this cooling section can be insured by the increased hydrogen concentration. Drever International developed a patented improvement of cooling technology based on the following features: pure hydrogen gas is injected only in the rapid cooling section whereas the different sections of the furnace are supplied with pure nitrogen gas; the control of flows through atmosphere gas management allows to get high hydrogen concentration in cooling section and low hydrogen content in the other furnace zones. This cooling technology development insures higher cooling rates without additional expensive hydrogen gas consumption and without the use of complex sealing equipments between zones. In addition reduction in electrical energy consumption is obtained. This atmosphere control development can be combined with geometrical design improvements in order to get optimised cooling technology providing high cooling rates as well as reduced strip vibration amplitudes. Extensive validation of theoretical research has been conducted on industrial lines. New lines as well as existing lines, with limited modifications, can be equipped with this new development. Up to now this technology has successfully been implemented on 6 existing and 7 new lines in Europe and Asia.

Analysis of the mixing effect of the confluence by the difference in water temperature between the main stream and the tributary (본류와 지류의 수온 차에 의한 합류부 혼합 양상 분석)

  • Ahn, Seol Ha;Lee, Chang Hyun;Kim, Kyung Dong;Kim, Dong Su;Ryu, Si Wan;Kim, Young Do
    • Journal of Korea Water Resources Association
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    • v.56 no.2
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    • pp.103-113
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    • 2023
  • The river confluence is a section in which two rivers with different topographical and hyrodynamic characteristics are combined into one, and it is a section in which rapid flow, inflow of sediments, and hydrological topographic changes occur. In the confluence section, the flow of fluid occurs due to the difference in density due to the type of material or temperature difference, which is called a density flow. It is necessary to accurately measure and observe the confluence section including a certain section of the main stream and tributaries in order to understand the mixing behavior of the water body caused by the density difference. A comprehensive analysis of this water mixture can be obtained by obtaining flow field and flow rate information, but there is a limit to understanding the mixing of water bodies with different physical properties and water quality characteristics of rivers flowing with stratigraphic flow. Therefore, this study attempts to grasp the density flow through the water temperature distribution in the confluence section. Among the extensive data of the river, vertical data and water surface data were acquired, and through this, the stratification phenomenon of the confluence was to be confirmed. It was intended to analyze the mixed pattern of the confluence by analyzing the water mixing pattern according to the water temperature difference using the vertical data obtained by measuring the repair volume by installing the ADCP on the side of the boat and measuring the real-time concentration using YSI. This study can supplement the analysis results of the existing water quality measurement in two dimensions. Based on the comparative analysis, it will be used to investigate the current status of stratified sections in the water layer and identify the mixing characteristics of the downstream section of the river.

Investigation of Vertical Profiles of Meteorological Parameters and Ozone Concentration in the Mexico City Metropolitan Area

  • Benitez-Garcia, Sandy E.;Kanda, Isao;Okazaki, Yukiyo;Wakamatsu, Shinji;Basaldud, Roberto;Horikoshi, Nobuji;Ortinez, Jose A.;Ramos-Benitez, Victor R.;Cardenas, Beatriz
    • Asian Journal of Atmospheric Environment
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    • v.9 no.2
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    • pp.114-127
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    • 2015
  • In the Mexico City Metropolitan Area (MCMA), ozone ($O_3$) concentration is still higher than in other urban areas in developed countries. In order to reveal the current state of photochemical air pollution and to provide data for validation of chemical transport models, vertical profiles of meteorological parameters and ozone concentrations were measured by ozonesonde in two field campaigns: the first one, during the change of season from wet to dry-cold (November 2011) and the second during the dry-warm season (March 2012). Unlike previous similar field campaigns, ozonesonde was launched twice daily. The observation data were used to analyze the production and distribution of ozone in the convective boundary layer. The observation days covered a wide range of meteorological conditions, and various profiles were obtained. The evolution of the mixing layer (ML) height was analyzed, revealing that ML evolution was faster during daytime in March 2012 than in November 2011. On a day in November 2011, the early-morning strong wind and the resulting vertical mixing was observed to have brought the high-ozone-concentration air-mass to the ground and caused relatively high surface ozone concentration in the morning. The amount of produced ozone in the MCMA was estimated by taking the difference between the two profiles on each day. In addition to the well-known positive correlation between daily maximum temperature and ozone production, effect of the ML height and wind stagnation was identified for a day in March 2012 when the maximum ground-level ozone concentration was observed during the two field campaigns. The relatively low ventilation coefficient in the morning and the relatively high value in the afternoon on this day implied efficient accumulation of the $O_3$ precursors and rapid production of $O_3$ in the ML.

Properties of Non-cement Artificial Stone Utilizing the Waste Porcelain and Waste Glass (폐유리 및 폐자기를 활용한 무시멘트계 인조석재의 특성)

  • Kim, Tae-Hyun;Lee, Seung-Ho;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.136-142
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    • 2016
  • As the rapid industrialization and modernization progress of the world it is becoming a fast-paced environment pollution. And, dust or environment pollution to solve reckless diggings of natural aggregate cause a serious problem. This study was used a Blast Furnace Slag and Combined Heat and Power Plant of Fly Ash as a cement substitute to reduce $CO_2$ emissions during cement production, this study intend to suggest it's result as basic data 'Properties of Artificial Stone interior or exterior materials type utilizing industrial by-product and waste resource' utilizing Waste Porcelain and Waste Glass. As a result, it was high strength that matrix added the Combined Heat and Power Plant of Fly Ash of addition ratio 40%. Also, pre-experiment was conduct as mixing ratio of waste glass, waste porcelain on the basis of the preceding experiment, proper mixing ratio was judged that proper of waste glass, waste porcelain was mixing ratio 60, 70 (%) of appeared surface aggregate ratio more than 45%.

Densification of $TiO_2$+Ti powder by Magnetic Pulsed Compaction (자기펄스 성형법에 의한 $TiO_2$+Ti 혼합 분말의 치밀화 거동)

  • Park, J.S.;Kim, H.S.;Lee, J.G.;Rhee, C.K.;Hong, S.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.394-397
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    • 2008
  • In this research, the fine-structure TiO2+Ti bulks have been fabricated by the combined application of magnetic pulsed compaction (MPC) and subsequent sintering, and their densification behavior was investigated. The obtained density of $TiO_2$+Ti bulk prepared by the combined processes was increased with increasing MPC pressure from 0.7 to 1.7 GPa. Relatively higher density (88%) in the MPCed specimen at 0.7Gpa was attributed to the decreasing of the inter-particle distance of pre-compacted component. High pressure and rapid compaction by Magnetic Pulsed Compaction could reduce shrinkage rate (about 10%) of the sintered bulks compared to that of general processing (about 20%). Mixing conditions of PVA, water, Ti and $TiO_2$ nano powder for compaction of $TiO_2$ nano powder did not affect on density and shrinkage of the sintered bulks due to high pressure of MPC.

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Quality Characteristics of White Bread with Arrowroot Powder (칡 분말을 첨가한 식빵의 품질 특성)

  • Han, Gyusang;Hwang, Seong-Yun;Rho, Sujung
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.6
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    • pp.778-788
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    • 2013
  • The objective of this study was to investigate the effects and availability of arrowroot powder in making white bread. The characteristics of pasting, farinogram and alveogram of the dough containing arrowroot powder were analyzed. Further, the physicochemical properties of white bread were analyzed by different mixing ratios (0, 3, 5 and 7%) of arrowroot powder during storage periods. When 7% of arrowroot powder was added, the initial pasting temperature of the dough by using a RVA (rapid visco analyzer) was significantly increased. Peak viscosity, holding strength, break down, final viscosity and set back were decreased by increasing added arrowroot powder. With the increasing amounts of arrowroot powder, the values of farinogram and alveogram parameter for the dough showed a tendency to decrement. The texture profile analysis of the white bread revealed that hardness, springiness, cohesiveness and gumminess were increased by adding arrowroot powder and further, the storage time was longer. By increasing the amount of added arrowroot powder, the L value of the white bread was decreased, whereas the a, b value were increased. In the sensory evaluation, the white bread of the control and that of the added 3% arrowroot powder showed the highest preference in total score.

Examining Three-Dimensional Flow Characteristics in the Distribution Channel to the Flocculation Basin using CFD (전산유체역학을 이용한 응집지 분배수로의 흐름 해석에 관한 연구)

  • Park, No-Suk;Beak, Heung-Ki;Kim, Jeong-Hyun;Min, Jin-Hui;Shin, Hang-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.500-507
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    • 2004
  • This study was conducted to evaluate the equity of the flow distribution from rapid mixing basin to the flocculation basins. Also, several types of inlet structures of the open channel affecting the flow pattern and distribution trend were studied using Computational Fluid Dynamics (CFD) simulation. For investigating the factual phenomena in distribution channel, we selected a certain domestic water treatment plant with capacity of $361,000m^3/d$. From the measurements of flow discharge, it is investigated that this existing inlet geometry resulted in significant inequitable distribution. The both largest deviations in the basins and rows were over 10%. In order to reduce the these deviation, this study suggested installing a baffle against the influent, and showed the effectiveness which the largest deviation was less than 3%. Also, it was concluded that the existing design method of open channel could be improved by three-dimensional hydrodynamic analysis for optimizing the even flow.

Pool Combustion of Iso-Propanol Fuel including IPA and PCBs in different Type Vessels

  • An Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.102-108
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    • 2006
  • On the refutation demanded for a control of various toxic substances. PCBs(poly chlorinated biphenyl) has a fatal poisonous matter in the ecosystem and the environmental pollution as it Is a kind of stable chemical substance. Especially, the gross Product of PCBs is estimated at about one million tonnage all over the world. However it is kept on storing in untreated state, then has a deterioration by the Prolonged storage and a risk of overflowing. Therefore, this research examined the fundamental characteristics of combustion and emission for the target of using the IPA (iso-propyl alcohol) solution as a part of PCBs control. IPA was filled to three kinds of Vessel, i.e. Vessel I, II, and III, and then was investigated as follows combustion shape, flame temperature. mass burning velocity, and PM(Particulate matter). A radial thermometer and a C-A thermocouple measured the flame temperature, and the optical extinction method by using He-Ne laser and the filter weight method used in the PM measurement. As a result, with an increasing of L/S ratio, the flame length become shorter and the burning velocity is more rapid, but the particulate matters is higher. It is supposed that the air flow rate is high on Vessel. and then the combustion is Promoted in the surface area of the upstream zone. The future works plan to investigate the characteristics with an using of the mixing of IPA and PCBs

Application of Coagulation-UF Hybrid Membrane Process for Reuse of Secondary Effluent (하수 2차 처리수 재이용을 위한 hybrid 응집-UF 막분리 공정의 적용)

  • Lee, Chul-Woo;Shon, Jung-Ki;Shon, In-Shik;Han, Seung-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.605-612
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    • 2005
  • The objective of this study was to evaluate the factors affecting the optimization of coagulation hybrid UF membrane processes for the reuse of secondary effluent from sewage treatment plant. The experimental results obtained from the UF membrane process showed that organic colloids in the size range of $0.2{\mu}m{\sim}1.0{\mu}m$ caused the most substantial influence on the fouling of UF membrane. When using a coagulation pretreatment to UF membrane, alum dosage of 50mg/L resulted in the least reduction in membrane permeate flux. Also, for the rapid mixing process, in-line mixer type was more efficient for organic removal than back mixer type. Therefore, it may be concluded that coagulation-UF hybrid membrane process comparing to UF alone process showed not only higher removal efficiency of organic matter, but also substantial improvement of permeate flux of UF membrane.