• Journal of Korean Society of Water and Wastewater
• /
• v.9 no.4
• /
• pp.87-96
• /
• 1995

The Electron/Hole Pair is generated when the activation energy produced by ultraviolet ray illuminates to the semiconductor and OH- ion produced by water photocleavage reacts with positive Hole. As a results, OH radical acting as strong oxidant is generated and then Photocatalytic oxidation reaction occurs. The photocatalytic oxidation can oxidate the non-degradable and hazardous organic substances such as pesticides and aromatic materials easier, safer and shorter than conventional water treatment process. So in this study, many factors influencing the oxidation of chlorophenols, such as inorganic electrolytes addition, change of oxygen and nitrogen atmosphere, temperature, pH, oxygen concentration, chlorophenol concentration, were throughly examined. According to the experiments observations, it is founded that the rate of chlorophenol oxidation follows a first-order reaction and the modified Langmuir-Hinshelwood relationship. And the photocatalytic oxidation occurs only when activation energy acting as Electron/Hole generation, oxygen acting as electron acceptor to prevent Electron/Hole recombination, $TiO_2$ powder acting as photocatalyst are present. The effects of variation of dissolved oxygen concentration, temperature and inorganic electrolytes concentration on 2-chlorophenol oxidation are negligible. And the lower the organic concentration, the higher the oxidation efficiency becomes. Therefore, the photocatalytic oxidation is much effective to oxidation of hazardous substances at very low concentration. The oxidation is effective in the range of 0.1 g/L-10 g/L of $TiO_2$. Finally when the ultra-violet ray is illuminated to $TiO_2$, the surface characteristics of $TiO_2$ change and Adsorption/Desorption reaction on $TiO_2$ surface occurs.

• Solar Energy
• /
• v.17 no.2
• /
• pp.35-42
• /
• 1997

Thermal diode is a device which allows heat to be transferred in one direction by convection due to difference of density of fluid, and blocks heat flow in the opposite direction. Vertical plate for heat collection and radiation are of utility for design of thermal diode. It was considered the transient and steady state of air filled thermal diode with guide vane which combined rectangular and parallelogrammic shape enclosures. $Gr^*$ was kept constantly on $1.11{\times}10^{10}{\sim}1.4{\times}10^{10}$ and error range was ${\pm}3%$ during the experiment. Nu was examined when inclined angle are $15^{\cir\c}\;and\;45^{\circ}$ and, also the experiments was carried out with and without guide vane as well. Specially, Nu was linearly increased due to increase of $Gr^*$, and the effect of guide vane and dimensionless channel depth was sensitive. Developed state of temperature began at dimensionless time $0.5{\sim}0.6$ due to variation of inclined angle, which is characteristic of system.

• Journal of Advanced Marine Engineering and Technology
• /
• v.36 no.2
• /
• pp.267-275
• /
• 2012

In this study, normal wind load and blast wind load are modeled mathematical. And the periodical torque and bending moments transmitted to the main shaft of wind turbine are investigated. A normal wind model assumed, of which the wind velocity is increased according to the height from ground. The average values and the harmonic terms of the transmitted moments are studied on the wind direction of range $-45^{\circ}{\sim}45^{\circ}$ and the bending moment characteristics are examined, which is regarded as the main source of the misalignment of gear train. In normal wind load case, excitation frequency is 3X (X : Rotor speed). When the wind direction is $+22.5^{\circ}$, the horizontal axis of bending moment occur the 50% of main torque. This result leads to edge contact of gear teeth by shaft elastic deformation. In blast wind load case, excitation frequency are 3X,6X,9X. Additional, in the (+) direction of wind load, relative harmonic percentage is increase.

• Korean Journal of Plant Taxonomy
• /
• v.42 no.1
• /
• pp.1-12
• /
• 2012

To clarify the morphological variations of Galium, its morphological characteristics were examined using maximum parsimony analysis. The key characteristics as well as the range of variation in each characteristic were investigated at the species level and were employed to elucidate the relationships between the taxa. This study confirmed that species belonging to genus Galium formed a monophyletic group and comprised two main clades. Sect. Cymogaliae and sect. Leptogalium are polyphyly groups, and other sections are monophyletic group. This study also suggests that the fruit hairs, the types of petal apexes, and the colors of the petals are the most valuable taxonomic characteristics for differentiating different sections. The numbers of the leaves and leaf shape provide useful taxonomic characteristics for the identification of different species.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.9
• /
• pp.915-921
• /
• 2012

In this study, we propose a new method for estimating the IMEP using difference pressure, which is the pressure difference between the cylinder pressure and the motoring pressure. The estimated IMEP, denoted as $IMEP_{diff}$, optimizes the theoretical IMEP calculation range based on the fact that the difference pressure exists between the start and the end of combustion. $IMEP_{diff}$ is verified to have a high linear correlation with IMEP with $R^2$ of 0.9955. The proposed method can estimate the IMEP with 21% of the cylinder pressure data and 31% of the calculation effort compared to the theoretical IMEP calculation method, and therefore, it has great potential for real-time implementations. The estimation and control performance of $IMEP_{diff}$ is validated by engine experiments, and by controlling $IMEP_{diff}$, the torque variation between the cylinders was reduced.

• Proceedings of the KSME Conference
• /
• 2001.11b
• /
• pp.185-190
• /
• 2001

Numerical Study with detailed chemistry has been conducted to investigate the flame structure and NOx formation characteristics in oxygen-enhanced$(CH_4/O_2-N_2)$ and oxygen-enhanced-EGR$(CH_4/O_2-CO_2)$ counter diffusion flame with various strain rates. A small amount of $N_2$ is included in oxygen-enhanced-EGR combustion, in order to consider the inevitable $N_2$ contamination by $O_2$ production process or air infiltration. The results are as follows : In $CH_4/O_2-CO_2$ flame it is very important to adopt a radiation effect precisely because the effect of radiation changes flame structure significantly. In $CH_4/O_2-N_2$ flame special strategy to minimize NO emission is needed because it is very sensitive to a small amount of $N_2$. Special attention is needed on CO emission by flame quenching, because of increased CO concentration. Spatial NO production rate of oxygen-enhanced combustion is different from that of air and oxygen-enhanced-EGR combustion in that thermal mechanism plays a role of destruction as well as production. In case $CH_4/O_2-CO_2$ flame contains more than 40% $CO_2$ it is possible to maintain the same EINO as that of $CH_4/Air$ flame with accomplishing higher temperature than that of $CH_4/Air$ flame. EINO decreases with increasing strain rate, and those effects are augmented in $CH_4/O_2$ flame. Complementary study is needed with extending the range of strain rate variation.

• 한국공간정보시스템학회:학술대회논문집
• /
• 2004.05a
• /
• pp.75-82
• /
• 2004

Many researcher's efforts have made a significant advancement of space frame structure with various portion, and it becomes the most outsanding one of space structures. However, with the characteristics of thin and long term of spacing, the unstable behavior of space structure is shown by initial imperfection, erection procedure or joint, especially space frame structure represents more. This kind of unstable problem could not be set up clearly and there is a huge difference between theory and experiment. Moreover, the discrete structure such as space frame has more complex solution, this it is not easy to derive the formulation of design about space structure. In this space frame structure, the character of rise-span ratio or load mode is represented by the instability of space frame structure with initial imperfection, and snap-through or bifurcation might be the main phenomenon. Therefore, in this study, space frame structure which has a lot of aesthetic effect and profitable for large space covering single layer is dealt. And because that the unstable behavior due to variation of inner force resistance in the elastic range is very important collapse mechanism, I would like to investigate unstable character as a nonlinear behavior with a geometric nonlinear. In order to study the instability. I derive tangent stiffness matrix using finite element method and with displacement incremental method perform nonlinear analysis of unit space structure, star dome and 3-ring star dome considering rise-span $ratio(\mu}$ and load $ratio(R_L)$ for analyzing unstable phenomenon.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.40 no.4
• /
• pp.328-336
• /
• 2004

This paper describes the effect of loading rate, specimen geometries and material properties for ModeⅠ and Mode Ⅱ interlaminar fracture toughness of hybrid composite by using double cantilever beam (DCB) and end notched flexure (ENF) specimen. In the range of loading rate 0.2~20mm/min, there is found to be no significant effect of loading rate with the value of critical energy release rate (Gc).The value of Gc for variation of initial crack length are nearly similar values when material properties are CF/CF and GF/GF, however, the value of Gc are highest with the increasing intial crack length at CF/GF. The SEM photographs show good fiber distribution and interfacial bonding of hybrid composites when the moulding is the CF/GF.

• Food Science of Animal Resources
• /
• v.35 no.1
• /
• pp.121-129
• /
• 2015

${\beta}$-agonists are anabolic compounds that promote fat loss and muscle gain, and their administration to livestock may provide economic benefits by increasing growth rate and feed efficiency. For these reasons, ${\beta}$-agonists are also commonly added to livestock feed as growth promoters. This can introduce a significant risk of secondary human poisoning through intake of contaminated meat. A new method for the simultaneous determination of three ${\beta}$-agonists (clenbuterol, ractopamine, and zilpaterol) was developed in this study and applied to various meat samples. The limits of quantification, derived through a validation test following Codex guidelines, were $0.2{\mu}g/kg$ for clenbuterol and zilpaterol, and $0.4{\mu}g/kg$ for ractopamine. The average recoveries for clenbuterol, ractopamine, and zilpaterol ranged from 109.1% to 118.3%, 95.3% to 109.0%, and 94.1% to 120.0%, respectively. The recovery and coefficient of variation (CV) values fell within the acceptable range according to the Codex guidelines. This method reduced the analysis time without decreasing detection efficiency by modifying the pretreatment steps. This method could be utilized to manage the safety of imported meat products from countries where zilpaterol use is still permitted, thereby improving public health and preventing ${\beta}$-agonist poisoning due to secondary contamination.

• New & Renewable Energy
• /
• v.6 no.4
• /
• pp.30-40
• /
• 2010

Syngas from gasification of coal can be converted to SNG(Synthesis Natural Gas) through gas cleaning, water gas shift, $CO_2$ removal, and methanation. One of the key technologies involved in the production of SNG is the methanation process. In the methanation process, carbon oxide is converted into methane by reaction with hydrogen. Major factors of methanation are hydrogen-carbon oxide ratio, reaction temperature and space velocity. In order to understand the catalytic behavior, temperature programmed surface reaction (TPSR) experiments and reaction in a fixed bed reactor of carbon monoxide have been performed using two commercial catalyst with different Ni contents (Catalyst A, B). In case of catalyst A, CO conversion was over 99% at the temperature range of $350{\sim}420^{\circ}C$ and CO conversions and $CH_4$ selectivity were lower at the space condition over 3000 1/h. In case of catalyst B, CO conversion was 100% at the temperature over $370^{\circ}C$ and CO conversions and $CH_4$ selectivity were lower at the space condition over 4700 1/h. Also, conditions to satisfy $CH_4$ productivity over 500 ml/h.g-cat were over 2000 1/h of space velocity in case of catalyst A and over 2300 1/h of space velocity in case of catalyst B.