• Journal of Korean Society for Atmospheric Environment
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• v.23 no.1
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• pp.97-109
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• 2007

Vertical distribution and optical properties of atmospheric aerosols above the Korean peninsula are quite important to estimate effects of aerosol on atmospheric environment and regional radiative forcing. For the first time in Korea, vertical microphysical properties of atmospheric aerosol obtained by inversion algorithm were analyzed based on optical data of multi-wavelength Raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST). Data collected on 14 June 2004 at Gwangju ($35.10^{\circ}N,\;126.53^{\circ}E$) and 27 May 2005 at Anmyeon island ($36.32^{\circ}N,\;126.19^{\circ}E$) were used as raw optical data for inversion algorithm. Siberian forest fire smoke and local originated haze were observed above and within the height of PBL, respectively on 14 June 2004 according to NOAA/Hysplit backstrajectory analysis. The inversion of lidar optical data resulted in particle effective radii around $0.31{\sim}0.33{\mu}m$, single scattering albedo between $0.964{\sim}0.977$ at 532 nm in PBL and effective radii of $0.27{\mu}m$ and single scattering albedo between $0.923{\sim}0.924$ above PBL. In the case on 27 May 2005, biomass burning from east China was a main source of aerosol plume. The inversion results of the data on 27 May 2005 were found to be particle effective radii between $0.23{\sim}0.24{\mu}m$, single scattering albedo around $0.924{\sim}0.929$ at 532 nm. Additionally, the inversion values were well matched with those of Sun/sky radiometer in measurement period.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.298-301
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• 2007

Vertical distribution and optical properties of atmospheric aerosols above the Korean peninsula are quite important to estimate effects of aerosol on atmospheric environment and regional radiative forcing. For the first time in Korea, vertical microphysical properties of atmospheric aerosol obtained by inversion algorithm were analyzed based on optical data of multi-wavelength Raman lidar system developed by the Advanced Environmental Monitoring Research Center (ADEMRC), Gwangju Institute Science and Technology (GIST). Data collected on 14 June 2004 at Gwangju ($35.10^{\circ}N$, $126.53^{\circ}E$) and 27 May 2005 at Anmyeon island ($36.32^{\circ}N$, $126.19^{\circ}E$) were used as raw optical data for inversion algorithm. Siberian forest fire smoke and local originated haze were observed above and within the height of PBL, respectively on 14 June 2004 according to NOAA/Hysplit backstrajectory analysis. The inversion of lidar optical data resulted in particle effective radii around 0.32 ${\mu}m$, single scattering albedo between 0.97 at 532 nm in PBL and effective radii of 0.27 ${\mu}m$ and single scattering albedo of 0.92 above PBL. In the case on 27 May 2005, biomass burning from east China was a main source of aerosol plume. The inversion results of the data on 27 May 2005 were found to be particle effective radii between 0.24 ${\mu}m$, single scattering albedo around 0.91 at 532 nm. Additionally, the inversion values were well matched with those of Sun/sky radiometer in measurement period.

• The Korea Journal of Herbology
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• v.35 no.4
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• pp.1-8
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• 2020

Objectives : Angelicae gigas, A. sinensis and A. acutiloba are three types of plants used as Angelicae Radix (Dang-Gui). Many doctors of Korean medicine want to know the difference in clinical use of these three species. This study aimed to compare the hemoglobin-related activity of the extracts of Angelicae gigas, A. sinensis and A. acutiloba roots by measuring the intensity of binding oxygen to hemoglobin using Raman spectroscopy. Methods : Hemoglobin activity was measured by chemical analysis and Raman spectroscopy to compare the pharmaceutical efficacy of three Angelica root extracts. The oxygenated hemoglobin intensity, blood decursinol and acetylcholinestrase(AChE) concentration in mice were measured. In addition, the effects of three Angelica root extracts on oxygenated hemoglobin intensity, decursinol and AChE concentration in red blood cells (RBC) from human were also investigated. Results : The contents of decursin, decursinol and decursinol angelate, which affected physiological activity and RBC properties, were higher in the extract of A. gigas root than in those of A. sinensis and A. acutiloba roots. Moreover, oxygenated hemoglobin intensity in the A. gigas extract was higher than that of other two species in the blood of mice and human RBCs. Also, the blood decursinol and AChE concentrations of A. gigas root extract were higher than that of A. sinensis and A. acutiloba roots. Conclusions : These results suggest that A. gigas is more effective in treating disease related oxygen deficiency in RBC deformation under oxidative stress.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.5
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• pp.205-210
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• 2008

Pearl is the organic gemstone which does not come from mines but from the biomineralization inside mollusc. Mollusc with nacre on inner surface of the shell is inevitable to make pearl. In this paper we researched and analyzed the pearls cultured using Pen shell (Atrina pectinata) which is not used in pearl farming industry but has potential to make pearls because it has thick and beautiful nacre inside the shell. SEM analysis was conducted to reveal the pattern of nacre on the Atrina pectinata pearl. Specific characteristics as sea-water pearl are detected by further analysis with ED-XRF. Aragonite specific peaks such as $1083cm^{-1}$ and $705cm^{-1}$ were shown by Raman analysis. UV-Vis analysis of Atrina pectinata pearl showed different pattern of spectrum compared with Pinctada margaritifera pearl. The reason for this discrepancy is assumed by the metabolic difference of each species.

• Applied Chemistry for Engineering
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• v.31 no.4
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• pp.360-367
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• 2020

In this study, the accumulation and distribution routes of microplastics in soil environment were examined, and their analytical methodologies were summarized. Density separation and removal process of inhibition materials were introduced for the separation of microplastics in soil and the basic principles and limitations of quantitative and qualitative analyses including pyrolysis gas chromatography mass spectrometry, µ-Raman spectrometry, fourier transform infrared spectrometry, and microscopes were investigated. Chemical extraction methods for the analysis of mediated hazardous substance (additives and sorbed matters) in microplastics were also discussed with focusing on in vitro bioaccessibility assay for the human oral exposure route. Based on the described methodologies for the analysis of microplastics in soil, it is expected that these methods enable to select appropriate analysis techniques in consideration of medium state, contamination level and sample quantity.

• Korean Journal of Materials Research
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• v.11 no.12
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• pp.1014-1019
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• 2001

The diamond thin film was deposited on Si(100) substrate from$CH_3OH/H_2O$mixtured gas using a hot filament chemical vapor deposition(HFCVD) method. The deposition condition for samples has been varried with the$CH_3OH/H_2O$composition. Scanning electron microscopy(SEM) and Raman spectroscopy has been employed for the sample analysis. The diamond sample has been obtained below 20Pa with$CH_3OH/H_2O$mixtured gas. The crystallinity of diamond film improved as the composition $CH_3OH$decreases from 60Vol% to 52Vol%, and the sample structure changed from the cauliflower to the diamond structure. But the sample structure was becomes cauliflower at 50Vol% of in$CH_3OH$ in the $CH_3OH/H_2O$. It was shown that the$CH_3OH$ has threshold composition.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.2
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• pp.173-179
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• 1999

The effect of the surface activation treatment on the crystallization of the amorphous silicon film was investigated. The amorphous silicon film was deposited on the silica substrate with LPCVD technique. Wet blasting with silica slurry or exposure with Nd:YAG laser beam was applied on the amorphous silicon film before annealing for the crystallization. For the analysis of the crystallinity, XRD, Raman, and SEM were employed. In this investigation, the prior surface activation treatment like silica wet blasting or Nd:YAG laser beam exposure before annealing for the crystallization were found to be effective in the enhancement of the crystallization. It is believed that these treatment lower the activation energy required for the crystallization of the amorphous silicon film.

• Korean Journal of Materials Research
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• v.4 no.4
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• pp.472-476
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• 1994

Phase transformation of PbO-precursor prepared from $Pb(NO_{3})_{2}$ by precipitation technique was observed by TG-DTA, XRD, FT-IR, and Raman spectral analysis. PbO-precursor was derived from an aqueous solution of $Pb(NO_{3})_{2}$ at $45^{\circ}C$ and pH of 9.0. The precipitate showed it to be the mixture of hydrous lead oxynitrate and lead hydroxynitrate. With increasing heat-treatment temperature ranging up to $560^{\circ}C$, the precursor changed to $3Pb(NO_{3})_{2}$ . 7Pb0, $Pb(NO_{3})_{2}$. 5Pb0 and PbO(litharge), in turn. Finally, it transformed to massicot form of PbO above $560^{\circ}C$.

• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.91-99
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• 2015

The Multi-wavelength Raman LIDAR (MRL) system was developed to enable a better understanding of the complex properties of aerosols in the atmosphere. In this study, the microphysical, optical, and radiative properties of mixed aerosols were retrieved using the discrete aerosol observation products from the MRL. The dust mixing ratio, which is the proportion of dust particles to the total mixed, was derived using the particle depolarization ratio. It was employed in the retrieval of backscattering and extinction coefficient profiles for dust and non-dust particles. The vertical profiles of aerosol optical properties were then used as input parameters in the inversion algorithm for the retrieval of microphysical parameters including the effective radius, refractive index, and the single scattering albedo (SSA). Those products were successfully applied to an analysis of radiative flux using a radiative transfer model. The relationship between the MRL derived extinction and aerosol radiative forcing (ARF) in short-wavelength was assessed over Gwangju, Korea. The results clearly demonstrate that the MRL-derived extinction profiles are a good surrogate for use in the estimation of optical, microphysical, and radiative properties of aerosols. It is considered that the analytical results shown in this study can be used to provide a better understanding of air quality and the variation of local radiative effects due to aerosols.

• Carbon letters
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• v.13 no.3
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• pp.161-166
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• 2012

Carbon materials were synthesized by pyrolysis from fibers of Corn-straw (Zea mays), Rice-straw (Oryza sativa), Jute-straw (Corchorus capsularis) Bamboo (Bombax bambusa), Bagass (Saccharum officinarum), Cotton (Bombax malabaricum), and Coconut (Cocos nucifera); these materials were characterized by scanning electron microscope, X-ray diffraction (XRD), and Raman spectra. All carbon materials are micro sized with large pores or channel like morphology. The unique complex spongy, porous and channel like structure of Carbon shows a lot of similarity with the original anatomy of the plant fibers used as precursor. Waxy contents like tyloses and pits present on fiber tracheids that were seen in the inherent anatomy disappear after pyrolysis and only the carbon skeleton remained; XRD analysis shows that carbon shows the development of a (002) plane, with the exception of carbon obtained from bamboo, which shows a very crystalline character. Raman studies of all carbon materials showed the presence of G- and D-bands of almost equal intensities, suggesting the presence of graphitic carbon as well as a disordered graphitic structure. Carbon materials possessing lesser density, larger surface area, more graphitic with less of an $sp^3$ carbon contribution, and having pore sizes around $10{\mu}m$ favor hydrogen adsorption. Carbon materials synthesized from bagass meet these requirements most effectively, followed by cotton fiber, which was more effective than the carbon synthesized from the other plant fibers.