• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.319-322
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• 2008

The viability of acetylene addition in each step of aromatic formation initiated by vinyl radical and acetylene also with its competition with structure rearrangement is investigated by determining optimal geometries and barrier and reaction energies using quantum mechanical methods. In principle, the addition reaction has more difficult in term of free energy and enthalpy compared to geometry arrangement. Under combustion conditions, i.e. T = 1200 K, acetylene addition is unfavorable mechanism as the barrier energy values rise much higher than that of geometry arrangement. However, in longer chain hydrocarbon case, e.g. n-CxHx+1 where x ³ 8, C-C bond rotation is rather difficult and requires high energy to form a ring structure, elongation chain is preferable.

• Journal of the Korean Society of Combustion
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• v.9 no.4
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• pp.28-34
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• 2004

Numerical simulations of freely propagating flames burning $H_2/HCl/Air$ Air mixtures were performed at atmospheric pressure in order to understand the effect of hydrogen chloride on flame structures. The chemical and physical effects of hydrogen chloride on flame structures were observed. A chemical kinetic mechanism was developed, which involved 26 gas-phase species and 198 forward elementary reactions. Under several equivalence ratios the flame speeds were calculated and compared with those obtained from the experiments, the results of which were in good agreement. As hydrogen chloride as additive was added into $H_2/Air$ flame, the flame speed, radical concentration and NO production rate were decreased. The chemical effect of hydrogen chloride caused the reduction of radical concentration, and then the decrease of the net rate of NO production. It was found that the influence in the reduction of $EI_{NO}$ with the addition of hydrogen chloride was attributed more due to the chemical effect than the physical effect.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.215-218
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• 2012

In this study, syngas laminar burning velocities with various hydrogen contents were studied using both experimental measurements and kinetic simulations. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including burning velocities were made using CHEMKIN Package with USC-Mech II. A large range of syngas mixture compositions such as 10:90%, 25:75%, 50:50%, 75:25% and equivalence ratio from lean condition of 0.5 to rich condition of 5.0 have been conducted. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increasing of $H_2$ content although the flame speed of hydrogen is faster about ten times than carbon monoxide. This phenomenon is attributed to the rapid production of the hydrogen related radicals such as H and OH at the early stage of combustion, which is confirmed the linear increasing of radical concentrations on kinetic simulation.

• Journal of the Korean Society of Combustion
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• v.8 no.3
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• pp.38-48
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• 2003

OH, CH and NO radical distributions have been measured and compared with the numerical analysis results in methane/air partially premixed laminar flames using 2-D LIF technique. The pick intensity of OH LIF signal is insensitive to fuel equivalence ratio: however, CH LIF intensity decreases as equivalence ratio increases and the NO concentration increases with equivalence ratio. The contribution of the prompt NO, formed near premixed reaction zone, to the total NO formation is evident from the OH, CH, and NO PLIF images in which the dilution effect of nitrogen is minimal for the highest equivalence ratio. Measured OH and NO LIF signals in counterflow flames agree with the computed concentration distributions. Both numerical and experimental results indicate that the structural change in a flame alters the NO formation characteristics of a partially premixed counterflow flame. The nitrogen dilution also changes flame structure, temperature and OH radical distributions and results in the decreased NO concentrations in a flame. The levels of decrease in NO concentrations, however, depends on the premixedness(${\alpha}$) of a flame. The larger change in the flame structure and NO concentrations have been observed in a premixed flame(${\alpha}=1.0$), which implies that the premixedness is likely to be a factor in the dilution effect on NO formation of a flame.

• Journal of the Korean Society of Combustion
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• v.10 no.2
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• pp.1-8
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• 2005

Incomplete combustion due to quenching in a narrow confinement has been a major problem for realization of a reliable micro combustion device. In most micro combustors, effects of flows are absent in the quenching because the flow is laminar and no severe stretch is present. In such circumstance, quenching is caused either by heat loss or by removal of active radicals to the wall surface of the confinement. An experimental investigation was carried out to investigate the relative significance of these two causes of quenching of a premixed flame. A premixed jet burner with a rectangular cross section at the exit was built. At the burner exit, the flame stands between two walls with adjustable distance. The gap between the two walls at which quenching occurs was measured at different wall surface conditions. The results were analyzed to estimate the relative significance of heat loss to the wall and the removal of radicals at the surface. The measurements indicated that the quenching distance was independent of the wall surface characteristics such as oxygen vacancy, grain boundary, or impurities at low temperature. At high temperature, however, the surface characteristics strongly affect the quenching distance, implying that radical removal at the wall plays a significant role in the quenching process.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.5
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• pp.343-348
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• 2009

The present study has experimentally investigated the effects of $CO_2$ diluted oxygen on the structure of swirl-stabilized flame in a lab-scale combustor. The methane fuel and oxidant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for various amount of carbon dioxide addition to the methane fuel and various swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the hot combustion zone increases at the upstream reaction zone because of an increase in the recirculation flow for an increase in swirl intensity. The hot combustion zone is also increased at the downstream zone by recirculation flow because of an increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensities of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of diluted gas in the reaction zone.

• Journal of the Korean Society of Combustion
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• v.21 no.2
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• pp.22-28
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• 2016

High efficient and environment friendly combustion technologies are used to be operated an extreme condition, which results in unintended flame instability such as extinction and oscillation. The use of electromagnetic energy is one of methods to enhance the combustion stability and a microwave as electromagnetic wave is receiving increased attention recently because of its high performance and low-cost system. In this study, an experiment was performed with jet diffusion flames induced by microwave. Micro jet was introduced to simulate the high velocity of industrial combustor. The results show that micro jet flames had three different modes with increasing oxidizer velocity; attached yellow flame, lifted flame, and lifted partially premixed flame. As a microwave was induced to flames, the overall flame stability and blowout limit were extended with the higher microwave power. Especially the interaction between a flame and a microwave was shown clearly in the partially premixed flame, in which the lift-off height decreased and NOx emission measured in post flame region increased with increasing microwave power. It might be attributed to increase of reactivity due to the abundance of radical pool and the enhanced absorption to thermal energy.

• Journal of ILASS-Korea
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• v.10 no.2
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• pp.1-9
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• 2005

An experimental study was carried out to obtain the fundamental data about the effects of radical ignition on premixture combustion. A CVC(constant volume combustor) divided into the sub-chamber and the main chamber was used. Numerous narrow passage holes are arranged between the main chamber and the sub-chamber. The products including radicals generated by spark ignition in tile sub-chamber derives the simultaneous multi-point ignition in the main chamber. We have examined the effects of the sub-chamber volume, the diameter and number of passage holes, and the equivalence $ratio({\Phi})$ on the combustion characteristics by means of burning pressure measurement and flame visualization. In a CVC, the overall burning time including the ignition delay became very short and the maximum burning pressure was slightly increased by the radical ignition(RI) method in comparison with those by the conventional spark ignition(SI) method. Combustible lean limit by RI method is extended by ${\Phi}=0.25$ compared with that by SI method. Also, In cases of charging the number and the diameter for the fixed total cross section of the passage holes, combustion period increased significantly at a sub-chamber with a single hole, but those of the other conditions had almost a similar tendency in the sub-chamber with 4 or more holes. regardless of equivalence ratio. Therefore, it was Proved that a critical cross section exists with the number of passage holes.

• Journal of the Korean Society of Combustion
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• v.19 no.1
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• pp.17-28
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• 2014

In this study, the laminar burning velocity of syngas fuel($H_2/CO$) and flame structure with various hydrogen contents were studied using both experimental measurements and detailed kinetic analysis. The laminar burning velocities were measured by the angle method of Bunsen flame configuration and the numerical calculations including chemical kinetic analysis were made using CHEMKIN Package with USC-Mech II. A wide range of syngas mixture compositions such as $H_2$ : CO = 10 : 90, 25 : 75, 50 : 50, 75:25 and equivalence ratios from lean condition of 0.5 to rich condition of 5.0 have been considered. The experimental results of burning velocity were in good agreement with previous other research data and numerical simulation. Also, it was shown that the experimental measurements of laminar burning velocity linearly increased with the increment of $H_2$ content although the burning velocity of hydrogen is faster than the carbon monoxide above 10 times. This phenomenon is attributed to the rapid production of hydrogen related radicals such as H radical at the early stage of combustion, which is confirmed the linear increase of radical concentrations on kinetic analysis. Particular concerns in this study are the characteristics of burning velocity and flame structure different from lean condition for rich condition. The decrease of OH radicals and double peaks are observed with $H_2$ content in rich condition once $H_2$ fraction exceeds over threshold.

• International Journal of Automotive Technology
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• v.8 no.3
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• pp.269-274
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• 2007

A prior fundamental study was executed using a constant volume chamber (CVC) to improve the burning characteristics of lean pre-mixture by the injection of active radicals generated in the sub-chamber of the CVC. The Radical ignition (RI) technique shows remarkable progress in the burning velocity and combustible lean limit compared with the results of the spark ignition (SI) technique. The optimum design value of the sub-chamber geometry is near $0.11cm^{-1}$ for the ratio of the total area of the holes to the sub-chamber volume $(A_h/V_s)$. In this study, based on the former experimental results, the additional works have been performed to examine the effects of the geometry change in the number $(N_h)$, the total section area $(A_h)$, and diameter $(D_h)$ of the passage holes on the combustion characteristics in the CVC. Also ambient conditions such as the initial temperature and the initial pressure of the mixture were selected as experimental parameters and the effects of residual gas at the chamber on the combustion characteristics were investigated. As a result, the correlation between the passage hole number and overall passage hole area was grasped. The effects of the initial temperature were significant, but on the other hand, those of the initial pressure were weak. A more detailed analysis on the residual gas is required in the future.