• Title/Summary/Keyword: RUBBER COMPOSITE

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Synthesis and Characterization of the Ag-doped TiO2

  • Lee, Eun Kyoung;Han, Sun Young
    • Elastomers and Composites
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    • v.57 no.1
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    • pp.1-8
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    • 2022
  • In this study, the photo-deposition method was used to introduce Ag onto the surface of TiO2 to synthesize an Ag-TiO2 composite. The effects of the varying amounts of AgNO3 precursor and annealing time periods on the Ag content in the composites, as well as their antibacterial characteristics under visible light conditions were studied. SEM analysis revealed the spherical morphology of the Ag-TiO2 composite. Compared with TiO2, the Ag particles were too small to be observed. An XPS analysis of the Ag-TiO2 surface confirmed the Ag content and showed the peak intensities for elements such as Ag, Ti, O, C, and Si. The highest Ag content was observed when 33.3 wt.% of AgNO3 and an annealing time of 6 h were employed; this was the optimum annealing time for Ti-Ag-O bonding, in that the lowest number of O bonds and the highest number of Ag bonds were confirmed by XPS analysis. Superior antibacterial properties against Bacillus and Escherichia coli, in addition to the widest inhibition zones were exhibited by the Ag-TiO2 composite with an increased Ag content in a disk diffusion test, the bacterial reduction rate against Staphylococcus aureus and Escherichia coli being 99.9%.

A Study on the Vulcanization Reaction of Modified NR Blends by In-Situ Electrical Property Measurement (전기적 특성의 in-situ 측정에 의한 개질된 NR 블랜드의 가황 반응에 관한 연구)

  • Ha, Ki-Ryong;Suh, Soong-Hyuck;Rho, Seung-Baik;Lee, Seung-Hyun;Ahn, Won-Sool
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.235-242
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    • 2003
  • A vulcanization reaction characteristics of an isoprene rubber (IR)-modified natural rubber/carbon black (NR/CB) composite was studied using in-situ electrical property measuring technique. Since the electrical conductivity of the sample composite would be changed continuously during the vulcanization reaction by rearranging of the carbon black particles within the sample, volume resistivity (${\rho}$) might be obtained as a function or reaction time. A stabilization time ($t_i$), maximum reaction speed time ($t_p$), and volume resistivity at that time(${\rho}_p$) were defined from the data for the Arrhenius analysis. Volume resistivity ${\rho}$ showed a comparatively high value of ${\sim}10^8$ order before the reaction started, and dramatically decreased to be stabilized within $1{\sim}2$ minutes as soon as the reaction started. As the more time elapsed, thereafter, ${\rho}$ decreased monotonously to a certain constant value through a peak, ${\rho}_p$ at time $t_p$, which was considered as the maximum reaction rate. As a result, while $t_i$ values were comparatively constant as $1{\sim}2$ minutes, $t_p$ values showed to become shorter and shorter as the reaction temperature.

A Study on Dynamic Properties of Short-fiber Reinforced Chloroprene Rubber (단섬유 강화 Chloroprene 고무의 동적특성 연구)

  • 이동주;류상렬
    • Composites Research
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    • v.17 no.3
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    • pp.45-50
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    • 2004
  • The dynamic properties of short-fiber reinforced chloroprene rubber with different interphase conditions and fiber contents have been studied as functions of frequency, amplitude and temperature. The loss factor(LF) slightly increased more than 1.33% of strain and the dynamic ratio(DR) rapidly decreased with increasing strain amplitude. The LF rapidly decreased with increasing frequency especially more than 50Hz. The DR showed the lower when it compared to virgin material with increasing frequency. The LF showed the maximum at $65^{\circ}$ and rapidly decreased after that temperature. The DR showed the lower when it compared with virgin rubber with increasing temperature. Generally, the better interphase condition showed the lower LF and DR at the same testing condition. Therefore, the short-fiber reinforced rubber could have the better isolation when the frequency ratio is more than $\sqrt{2}$ compared with frequency ratio less than $\sqrt{2}$.

An Analysis about the Behavior of the Wiper Blade Including Incompressibility (비압축성을 고려한 와이퍼 블레이드의 거동 해석)

  • Chung, Won-Sun;Song, Hyun-Seok;Park, Tae-Won;Jung, Sung-Pil;Kim, Wook-Hyeon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.2
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    • pp.83-90
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    • 2010
  • The windshield wiper consists of 4 parts: a blade, an arm, a linkage and a motor. The wiper blade makes contact with the windshield and is designed to be operated normally at an angle of 30~50 degrees to the front glass. If the contact pressure between the wiper blade and windshield surface is too high, noise and wear of the rubber will result. On the other hand, if the contact pressure is too low, the performance will do badly, since foreign substances such as dust and stains will not be removed well. The pressure and friction of the wiper blade has a great influence on its effectiveness in cleaning the front window. This is due to the contact of the rubber with the window. This paper presents the dynamic analysis method to estimate the performance of the flat type blade of the wiper system. The blade has a nonlinear characteristic since the rubber is an incompressible hyper-elastic and visco-elastic material. Thus, Structural dynamic analysis using a complex contact model for the blade is performed to find the characteristics of the blade. The flexible multi-body dynamic model is verified by the comparison between test and analysis result. Also, the optimization using the central composite design table is performed.

Damping Characteristics of Polyurethane Composites Incorporating Recycled Rubber Particles and Aggregates (폐타이어 고무분말과 골재를 혼입한 폴리우레탄 복합재료의 감쇠 특성)

  • Park, Se Eon;Choi, Jeong-Il;Hwang, Jae-Seung;Lee, Bang Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.263-268
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    • 2020
  • The purpose of this study is to investigate the damping properties of polyurethane composites incorporating waste tire rubber powder and preplaced coarse aggregates. Four types of polyurethane-based composites were manufactured, and longitudinal impact tests were performed. And vibration signals in the time domain and frequency domain were measured and values of damping ratio for each specimen were calculated. Test results showed that the damping ratios of polyurethane composites, in which the amount of polyurethane was reduced by 10.6% and 21.2% through incorporation of rubber particles, were 8.4% and 4.6% lower than that of pure polyurethane. The damping ratio of the polyurethane composite produced in a similar manner to the prepact concrete production method was found to be 22% lower than that of pure polyurethane, however, the amount of polyurethane was reduced by 50% and the stiffness was 25.7 times higher than that of pure polyurethane.

Modeling of heated concrete-filled steel tubes with steel fiber and tire rubber under axial compression

  • Sabetifar, Hassan;Nematzadeh, Mahdi;Gholampour, Aliakbar
    • Computers and Concrete
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    • v.29 no.1
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    • pp.15-29
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    • 2022
  • Concrete-filled steel tubes (CFSTs) are increasingly used as composite sections in structures owing to their excellent load bearing capacity. Therefore, predicting the mechanical behavior of CFST sections under axial compression loading is vital for design purposes. This paper presents the first study on the nonlinear analysis of heated CFSTs with high-strength concrete core containing steel fiber and waste tire rubber under axial compression loading. CFSTs had steel fibers with 0, 1, and 1.5% volume fractions and 0, 5, and 10% rubber particles as sand alternative material. They were subjected to 20, 250, 500, and 750℃ temperatures. Using flow rule and analytical analysis, a model is developed to predict the load bearing capacity of steel tube, and hoop strain-axial strain relationship, and axial stress-volumetric strain relationship of CFSTs. An elastic-plastic analysis method is applied to determine the axial and hoop stresses of the steel tube, considering elastic, yield, and strain hardening stages of steel in its stress-strain curve. The axial stress in the concrete core is determined as the difference between the total experimental axial stress and the axial stress of steel tube obtained from modeling. The results show that steel tube in CFSTs under 750℃ exhibits a higher load bearing contribution compared to those under 20, 250, and 500℃. It is also found that the ratio of load bearing capacity of steel tube at peak point to the load bearing capacity of CFST at peak load is noticeable such that this ratio is in the ranges of 0.21-0.33 and 0.31-0.38 for the CFST specimens with a steel tube thickness of 2 and 3.5 mm, respectively. In addition, after the steel tube yielding, the load bearing capacity of the tube decreases due to the reduction of its axial stiffness and the increase of hoop strain rate, which is in the range of about 20 to 40%.

Enhanced photon shielding efficiency of a flexible and lightweight rare earth/polymer composite: A Monte Carlo simulation study

  • Wang, Ying;Wang, Guangke;Hu, Tao;Wen, Shipeng;Hu, Shui;Liu, Li
    • Nuclear Engineering and Technology
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    • v.52 no.7
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    • pp.1565-1570
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    • 2020
  • Photons with the energy of 60 keV are regularly used for some kinds of bone density examination devices, like the single photon absorptiometry (SPA). This article reports a flexible and lightweight rare earth/polymer composite for enhancing shielding efficiency against photon radiation with the energy of 60 keV. Lead oxide (PbO) and several rare earth element oxides (La2O3, Ce2O3, Nd2O3) were dispersed into natural rubber (NR) and the photon radiation shielding performance of the composites were assessed using monte carlo simulation method. For 60 keV photons, the shielding efficiency of rare earthbased composites were found to be much higher than that of the traditional lead-based composite, which has bad absorbing ability for photons with energies between 40 keV and 88 keV. In comparison with the lead oxide based composite, Nd2O3-NR composite with the same protection standard (the lead equivalent is 0.25 mmPb, 0.35 mmPb and 0.5 mmPb, respectively), can reduce the thickness by 35.29%, 37.5% and 38.24%, and reduce the weight by 38.91%, 40.99% and 41.69%, respectively. Thus, a flexible, lightweight and lead-free rare earth/NR composite could be designed, offering efficient photon radiation protection for the users of the single photon absorptiometry (SPA) with certain energy of 60 keV.

Adhesion Properties of Polymer Composite Materials for Concrete Repair (콘크리트 보수용 폴리머 복합재료의 접착강도 특성)

  • 지경용;연규석;이윤수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.330-335
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    • 1998
  • This research was conducted to evaluate the adhesion in tension of the polymer mortars for cement concrete repair. Various polymer types, binder ratios, and wet/dry conditions of the surface were considered in this study. Styrene-butadiene rubber (SBR) and ethylen vinyl acetate (EVA) used for polymer cement mortars. Epoxy resin (EP), and unsaturated polyester resin (UP) were used for polymer mertars. Adhesion in tension for the dry condition of the substrate surface was higher than that for the wet condition of the substrate surface under the same binder ratio. Therefore, in repairing concrete, the dry surface condition was effective on adhesion.

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Fundamental properties of polymer composite materials for concrete repair (콘크리트 보수용 폴리머 복합재료의 기초적 성질)

  • 지경용;연규석;이윤수;전철수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.319-322
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    • 1999
  • The adhesion properties of polymer cement mortars for cement concrete repair were evaluated with respect to polymer-cement ratios and the surface conditions of cement concrete substrate. Styrene-butadiene rubber (SBR) was used as an additive for polymer cement mortars. The adhesion strength of cement mortar was smaller than that of polymer cement mortar. The adhesion strengths to the dry surfaces of substrate were larger than those to the wet surfaces, indicating that the dryness of substrate increased the adhesion strength in repairing concrete structures.

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Failure of Tire Belt Cord (타이어 Belt Cord 의 파단)

  • Kim, Seok-Nam;Takashi, Akasaka
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1394-1400
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    • 2003
  • Tire subjected to inflation pressure and the load of passenger car has a important roll to dynamic performance characteristics of radial tires such as cornering and braking. These performance characteristics are directly related to the belt cord durability of tires. In this paper, we analyze the mechanism of belt cord broken due to cord tension at braking theoretically.

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