• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.449-455
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• 2021

Composite materials are substances that are configured to have excellent physical properties by combining the properties of a single substance, and are in the limelight as materials that exceed the performance of metals and polymers. However, it has the disadvantages of long cycle time and high unit price, and much research is being performed to overcome these disadvantages. In this study, we developed an epoxy resin curing agent that can shorten the time required for mass production of composite materials, and tried to expand the applicability of objections by imparting flame retardancy. The epoxy resin used as a basic substance utilized two types of bisphenol F and resorcinol structure, which was further modified using 9,10-dihydro-9-oxa-10-phosphaphenantrene-10-oxide (DOPO) to impart flame retardancy. Triethylphosphate (TEP) and bis [(5-ethyl-2-methyl-1,3,2-dioxaphosphorinan-5-yl)methyl] methyl phosphonate P,P'-dioxide (FR-001) were used as additives, seven kinds of compositions were blended, thermal characteristics (gelation time, glass transition temperature) and flame retardant performance were evaluated. We successfully developed an epoxy matrix that can be applied to high pressure resin transfer molding (HP-RTM) process.

• The Korean Journal of Rheology
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• v.11 no.1
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• pp.34-43
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• 1999

Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.111-115
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• 2005

Recently, natural fibers draw much interests in composite industry due to low cost, light weight, and environment-friendly characteristics compared with glass fibers. In this study, mechanical properties were evaluated for two extreme cases of jute fiber orientations, i.e. the unidirectional yarn composites and the felt fabric composites. Samples of jute fiber composites were fabricated by RTM process using epoxy resin, and tensile, compression, and shear tests were conducted. As can be expected, unidirectional fiber specimens in longitudinal direction showed the highest strength and modulus. Compared with glass/epoxy composites of the similar fabric architecture and fiber volume fraction, the tensile strength and modulus of jute felt/epoxy composites reached only 40% and 50% levels. However, the specific tensile strength and modulus increased to 80% and 90% of the glass/epoxy composites. The main reason for the poor mechanical properties of jute composites is associated with the weak interfacial bonding between fiber and matrix. The effect of surface treatment of jute fibers on the interfacial bonding will be examined in the future work.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.87-90
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• 2003

In Resin transfer molding (RTM), composite parts are produced by impregnation of a dry reinforcement with liquid matrix resin. Permeability is a key issue in this process. For thin parts, the resin flow in the thickness direction can be neglected. Therefore thin parts are considered as two-dimensional composites. However the resin flow through the thickness is important to thicker parts and we have to consider out-of-plane permeability. This work discusses a method to measure out-of-plane permeability. The flow rate and pressure drop across the porous media were measured. Also one dimensional form of Darcy's law is applied to calculate the out-of-plane permeability of various preforms. The flow is injected uniformly into layers of the preform. And a circular fiber mat with 6cm diameter was cut and flattened from cylindrical mandrel.

• Composites Research
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• v.15 no.6
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• pp.30-37
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• 2002

A stiffness model has been proposed to predict elastic constants of twisted yam composites. The model is based upon the unit cell structure, the coordinate transformation, and the volume averaging of compliance constants for constituent materials. For the correlation of analytic results with experiments, composite samples of various yam twist angles were tested, and strength and Young's modulus under tensile, compressive, and shear loading have been obtained. The sample was fabricated by the RTM process using glass yarns and epoxy resin. The correlations of elastic constants showed relatively good agreements. The model provides the predictions of the three-dimensional engineering constants, which are valuable input data for the analytic characterization of textile composites made of twisted yam.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.121-122
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• 2015

The demand on free-form buildings is gradually increasing, but there are several problems such as increased cost and construction duration, and decreased constructability at the construction phase upon construction of a building owing to the difficulty of member production-installation. To solve these problems, a technology to produce FCP using a CNC machine was developed. Basically, it delivers the information on a free-form building designed to the CNC machine, the shapes of RTM and PCM are created using the information delivered and FCP are produced with the RTM and PCM which act as forms. Since the construction duration and project cost are limited on site, the efficiency of FCP production-installation is significant for application of the technology. For it is almost impossible to change the production-installation layout and process once they are set in the construction phase, they should be carefully determined. Before the production-installation layout are established, it is necessary to analyze the factors that influence the duration. Thus, the study intends to analyze influence factors in PCM mold on estimation of the production-installation duration for FCP. According to the analysis of influence factors, a simulation model for estimation of the duration that changes depending on the constraint conditions can be built.

• Composites Research
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• v.17 no.3
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• pp.1-7
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• 2004

In the vacuum assisted RTM (VARTM) process that has become the center of attention for manufacturing massive composite structures, a good evacuation of air in the fiber preform is recognized as the prime factor. The microvoids, or the dry spots, are formed as a result of improper gate/vent locations and the mold geometry. The non-uniform resin velocity at the flow front leads to the formation of microvoids in the fibers, whereas the air in the microvoids can migrate along with the resin flow during mold filling. The residual air in the internal voids of a composite structure may cause a degradation of the mechanical properties as well as the structural failure. In this study, a unified macro- and micro analysis methods were developed to investigate the formation and transport of air in resin during VARTM process. A numerical simulation program was developed to analyze the three-dimensional flow pattern as well as the macro- and microscopic distribution of air in a composite part fabricated by VARTM process.

• Composites Research
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• v.22 no.2
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• pp.30-36
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• 2009

In this paper, we propose the design method for the composite torque link of a landing gear for a helicopter. The composite torque link has to be light weighted and very stiff to keep the shock absorber in the landing gear of helicopter. The configuration and structural shape has to be designed in consideration of the RTM (Resin Transfer Molding) manufacturing process which is adopted to minimize the manufacturing cost. The mechanical properties are obtained through the coupon tests with the specimens made by the same manufacturing process for the composite structure. The optimal design process was performed through iterative modifications of the models which were verified by stress analysis using FEM. The composite torque link has lug-shaped parts and is very thick, so 3D Layered solid elements of ABAQUS were used to get the stress field including the stress components in thickness direction and non-linear static analysis using contact B.C. of rigid-deform condition was used to get the optimal design.

• International conference on construction engineering and project management
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• 2015.10a
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• pp.401-404
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• 2015

Demand on free-form buildings is gradually increasing, yet owing to the difficulty of production-installation work, several problems occur in the construction phase upon construction of a building, including the increased cost and construction duration, and reduced constructibility. To solve these problems, a techonology to produce FCP using a CNC(Computerized Numeric Control) machine is developed. The technology is that the information of designed free-form buildings to the CNC machine is transferred, and the transferred information is used for RTM(Rod-Type Mold, the mold shaped by back-up rods) and PCM(Phase Change Material) shaping, and the shaped RTM and PCM have the role of molds to produce FCP. Construction duration and project cost are limited in building sites, so the efficiency of processes like production-installation of FCP for application of the technology is significant. Since it is almost impossible to change the production-installation process at the construction phase when they are established, process should be deliberately decided. Therefore, the purpose of the study is to propose a production-installation simulation model of free-form concrete panels, in aspect of PCM. This paper is establishing the process for production-installation of FCP, estimating time required by each construction type and proposing a time simulation model that changes according to various constraints based on the analyses. With the time simulation model, it will be possible to build a cost model and to review the optimal construction duration and project cost.

• Advanced Composite Materials
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• v.16 no.3
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• pp.207-221
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• 2007

The filling process of resin injection/compression molding (I/CM) can be divided into injection and compression phases. During the resin injection the mold is kept only partially closed and thus a gap is present between the reinforcements and the upper mold. The gap results in preferential flow path. After the gap is filled with the resin, the compression action initiates and forces the resin to penetrate into the fiber preform. In the present study, the resin flow in the gap is simplified by using the Stokes approximation, while Darcy's law is used to calculate the flow field in the fiber mats. Results show that most of the injected resins enter into the gap during the injection phase. The resin injection time is extremely short so the duration of the filling process is determined by the final closing action of the mold cavity. Compared with resin transfer molding (RTM), I/CM process can reduce the mold filling time or injection pressure significantly.