• Title/Summary/Keyword: RSM(Response Surface Method)

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Optimization of Esterification of Jatropha Oil by Amberlyst-15 and Biodiesel Production (Amberlyst-15를 이용한 자트로파 오일의 에스테르화 반응 최적화 및 바이오디젤 생산)

  • Choi, Jong-Doo;Kim, Deog-Keun;Park, Ji-Yeon;Rhee, Young-Woo;Lee, Jin-Suk
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.194-199
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    • 2008
  • In this study, the effective method to esterify the free fatty acids in jatropha oil was examined. Compared to other plant oils, the acid value of jatropha oil was remarkably high, 11.5 mgKOH/g. So direct transesterification by a base catalyst was not suitable for the oil. After the free fatty acids were esterified with methanol, jatropha oil was transesterified. The activities of four solid acid catalysts were tested and Amberlyst-15 showed the best activity for the esterification. After constructing the experiment matrix based on RSM and analyzing the statistical data, the optimal esterification conditions were determined to be 6.79% of methanol and 17.14% of Amberlyst-15. After the pretreatment, jatropha biodiesel was produced by the transesterification using KOH in a pressurized batch reactor. Jatropha biodiesel produced could meet the major specifications of Korean biodiesel standards; 97.35% of FAME, 8.17 h of oxidation stability, 0.125% of total glycerol and $0^{\circ}C$ of CFPP.

Optimization of Antioxidant Extraction from Dandelion (Taraxacum officinale) Leaves Using BBD-RSM (BBD-RSM을 이용한 민들레로부터 항산화성분의 추출공정 최적화)

  • Han, Kyongho;Jang, Hyun Sik;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.408-414
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    • 2019
  • In this study, an antioxidant was extracted from dandelion leaves using traditional hot water and ultrasonic extraction methods. In order to optimize the extraction yield and total flavonoid, an antioxidant, Box-Behnken design (BBD) model among response surface analysis methods was used. In the case of hot water extraction, the extraction temperature and time as well as the ratio of alcohol/ultrapure water were set as variables, and for the ultrasonic extraction, the ultrasonic survey century and irradiation time and the ratio of alcohol/ultrapure water were variables. Optimum extraction conditions in the hot water extraction method were the extraction temperature and time of $45.76^{\circ}C$ and 1.75 h and the ratio of alcohol/ultrapure water of 41.92 vol.%. While for the ultrasonic extraction method the survey century of 512.63 W, the ratio of alcohol/ultrapure water of 56.97 vol.% and the extraction time of 20.79 min were optimum conditions. Expected reaction yield and flavonoid content values under the optimized condition were calculated as 22.09 wt.% and 28.98 mg QE/mL dw, respectively. In addition, the error value of less than 3% was obtained validating our optimization process.

Rapid Statistical Optimization of Cultural Conditions for Mass Production of Carboxymethylcellulase by a Newly Isolated Marine Bacterium, Bacillus velezensis A-68 from Rice Hulls (통계학적 방법을 사용한 해양미생물 Bacillus velezensis A-68균주의 섬유소 분해효소 생산 조건 최적화)

  • Kim, Bo-Kyung;Kim, Hye-Jin;Lee, Jin-Woo
    • Journal of Life Science
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    • v.23 no.6
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    • pp.757-769
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    • 2013
  • A microorganism producing carboxymethylcellulase (CMCase) was isolated from seawater, identified as Bacillus velezensis by analyses of 16S rDNA and partial sequences of the gyrA, and designated as B. velezensis A-68. The optimal conditions for production of CMCase by B. velezensis A-68 were established using response surface methodology (RSM). The optimal concentrations of rice hulls and yeast extract, and initial pH of the medium for cell growth were 60.2 g/l, 7.38 g/l, and 7.18, respectively, whereas those for production of CMCase were 50.0 g/l, 5.00 g/l, and 7.30. The analysis of variance (ANOVA) implied that the most significant factor for cell growth as well as production of CMCase was yeast extract. The optimal concentrations of $K_2HPO_4$, NaCl, $MgSO_4{\cdot}7H_2O$, and $(NH_4)_2SO_4$ in the medium for cell growth were 7.50, 1.00, 0.10, and 0.80 g/l, respectively, which were the same as those for production of CMCase. The optimal temperatures for cell growth and production of CMCase were 30 and $35^{\circ}C$, respectively. The maximal production of CMCase under optimized conditions was 83.8 U/ml, which was 3.3 times higher than that before optimization. In this study, rice hulls, agro-byproduct, were developed as a substrate for production of CMCase and time for production of CMCase was reduced to 3 days using a newly isolated marine bacterium.

A Study on the Structural Analysis & Design Optimization Using Automation System Integrated with CAD/CAE (통합된 CAD/CAE 자동화 System을 이용한 구조 강도 해석 및 설계 최적화에 관한 연구)

  • Won June-Ho;Kim Jong-Soo;choi Joo-Ho;Yoon Jong-Min
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2005.04a
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    • pp.55-62
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    • 2005
  • In this paper, a CAB/CAE integrated optimal design system is developed, in which design and analysis process is automated using CAD/CAE softwares, for a complicated model for which parametric modeling provided by CAD software is not possible. CAD modeling process is automated by using UG/OPEN API function and UG/Knowledge Fusion provided by Unigraphics. The generated model is transferred to the analysis code ANSYS in parasolid format. Visual DOC software is used for optimization. The system is developed for PLS(Plasma Lighting System), which is a next generation illumination system that is used to illuminate stadium or outdoor advertizing panel. The PLS system consists of more then 20 components, which requires a lot of human efforts in modeling and analysis. The analysis for PLS includes static load, wind load and impact load analysis. As a result of analysis, it is found that the most critical component is a tilt assembly, which links lower & upper body assembly. For more reliable analysis, experiment is conducted using MTS and compared with the Finite element analysis result. The objective in the optimization is to minimize the material volume under allowable stresses. The design variables are three parameters in the tilt assembly that are chosen to be the most sensitive in stress values of twelve parameters. Gradient based method and RSM(Response Surface Method) are used for the algorithm and the results are compared. As a result of optimization, the maximum stress is reduced by 57%.

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Development of Easily Chewable and Swallowable Pan-fried Flat Fish for Elderly (가자미 구이 저작·연하 용이 노인식 개발)

  • Kim, Soojeong;Joo, Nami
    • The Korean Journal of Food And Nutrition
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    • v.28 no.1
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    • pp.153-159
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    • 2015
  • This study was conducted to develop food for the elderly, which are well-shaped and easy to chew and swallow. The amounts of water and gelatin were adjusted to facilitate breaking down of the food with the tongue. In the aging society, it is necessary to support the development of a variety of products that can ease the intake functions of swallowing and chewing, while complementing with the essential nutrients supplements; such products can be actively commercialized in the elderly industry. Various types of food, for elderly with difficulties in chewing and swallowing, were used for sensory assessment. Sensory panel consisted of 10 dietitians (10 women) in nursing care facilities. The sensory optimal composite recipes were determined by central composite design (CCD). The sensory measurements were significantly different in the appearance (p<0.01), saltiness (p<0.01) and overall quality (p<0.01). The optimum formulation of pan fried flat fish, calculated by numerical and graphical method, was 8.54 g of salt and 6.34 g of olive oil. Moisture content, hardness, and adhesiveness of pan fried flat fish were 84.77%, 250, and -1.20, respectively. The result showed that easily chewable and swallowable pan fried flat fish for the elderly will have sufficient competitiveness, considering its safety, taste, and preference. This study may provide the basic materials for the development of easily chewable and swallowable foods for elderly.

Shape Optimum Design of Ship's Bellows Using Statistical Method (통계적 방법을 이용한 선박용 벨로우즈의 형상 최적 설계)

  • Kim, Hyun-Su;Kim, Hyo-Gyeum;Lee, Jae-Sub;Kim, Hyoung-Jun
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.55-60
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    • 2007
  • Bellows are mechanical components which prevent the damage of system by absorption of the vibration and the displacement of axle and radial direction. Thermal piping system is expanded by the fluid of the high temperature from the heat engine inside. At this time, bellows prevent the damage of the piping due to the thermal expansion. Recently, design of bellows is required to fit some other operational environments which are not suggested in the E.J.M.A code book. And it is difficult to produce and to maintain bellows of high temperature and high pressure bemuse of its complicated shape and this causes the manufacturing cost to rise. The objective of this study is to determine optimum shape of bellows which can endure in the high temperature and high pressure. The maximum stress has an effect on the fatigue life of bellows, therefore it needs to be minimized. This study attempts to find a shape which minimizes the stress occurring in the bellows by the design of experiment. The model used in this study is not presented in the E.J.M.A code book, therefore, from the result of design of experiment we find the factors which give effects on the characteristic value and we presents the recession model using the RSM, which can predict the characteristic values depending on the change of factor values.

Evolutionary Optimization of Pulp Digester Process Using D-optimal DOE and RSM

  • Chu, Young-Hwan;Chonghun Han
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.395-395
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    • 2000
  • Optimization of existing processes becomes more important than the past as environmental problems and concerns about energy savings stand out. When we can model a process mathematically, we can easily optimize it by using the model as constraints. However, modeling is very difficult for most chemical processes as they include numerous units together with their correlation and we can hardly obtain parameters. Therefore, optimization that is based on the process models is, in turn, hard to perform. Especially, f3r unknown processes, such as bioprocess or microelectronics materials process, optimization using mathematical model (first principle model) is nearly impossible, as we cannot understand the inside mechanism. Consequently, we propose a few optimization method using empirical model evolutionarily instead of mathematical model. In this method, firstly, designing experiments is executed fur removing unecessary experiments. D-optimal DOE is the most developed one among DOEs. It calculates design points so as to minimize the parameters variances of empirical model. Experiments must be performed in order to see the causation between input variables and output variables as only correlation structure can be detected in historical data. And then, using data generated by experiments, empirical model, i.e. response surface is built by PLS or MLR. Now, as process model is constructed, it is used as objective function for optimization. As the optimum point is a local one. above procedures are repeated while moving to a new experiment region fur finding the global optimum point. As a result of application to the pulp digester benchmark model, kappa number that is an indication fur impurity contents decreased to very low value, 3.0394 from 29.7091. From the result, we can see that the proposed methodology has sufficient good performance fur optimization, and is also applicable to real processes.

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Optimum Design Based on Sequential Design of Experiments and Artificial Neural Network for Enhancing Occupant Head Protection in B-Pillar Trim (센터 필라트림의 FMH 충격성능 향상을 위한 순차적 실험계획법과 인공신경망 기반의 최적설계)

  • Lee, Jung Hwan;Suh, Myung Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.11
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    • pp.1397-1405
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    • 2013
  • The optimal rib pattern design of B-pillar trim considering occupant head protection can be determined by two methods. One is the conventional approximate optimization method that uses the statistical design of experiments (DOE) and response surface method (RSM). Generally, approximated optimum results are obtained through the iterative process by trial-and-error. The quality of results strongly depends on the factors and levels assigned by a designer. The other is a methodology derived from previous work by the authors, called the sequential design of experiments (SDOE), to reduce the trial-and-error procedure and to find an appropriate condition for using artificial neural network (ANN) systematically. An appropriate condition is determined from the iterative process based on the analysis of means. With this new technique and ANN, it is possible to find an optimum design accurately and efficiently.

Isolation of Dibutyl Phthalate-Degrading Bacteria and Its Coculture with Citrobacter freundii CD-9 to Degrade Fenvalerate

  • Wu, Min;Tang, Jie;Zhou, Xuerui;Lei, Dan;Zeng, Chaoyi;Ye, Hong;Cai, Ting;Zhang, Qing
    • Journal of Microbiology and Biotechnology
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    • v.32 no.2
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    • pp.176-186
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    • 2022
  • Continued fenvalerate use has caused serious environmental pollution and requires large-scale remediation. Dibutyl phthalate (DBP) was discovered in fenvalerate metabolites degraded by Citrobacter freundii CD-9. Coculturing is an effective method for bioremediation, but few studies have analyzed the degradation pathways and potential mechanisms of cocultures. Here, a DBP-degrading strain (BDBP 071) was isolated from soil contaminated with pyrethroid pesticides (PPs) and identified as Stenotrophomonas acidaminiphila. The optimum conditions for DBP degradation were determined by response surface methodology (RSM) analysis to be 30.9 mg/l DBP concentration, pH 7.5, at a culture temperature of 37.2℃. Under the optimized conditions, approximately 88% of DBP was degraded within 48 h and five metabolites were detected. Coculturing C. freundii CD-9 and S. acidaminiphila BDBP 071 promoted fenvalerate degradation. When CD-9 was cultured for 16 h before adding BDBP 071, the strain inoculation ratio was 5:5 (v/v), fenvalerate concentration was 75.0 mg/l, fenvalerate was degraded to 84.37 ± 1.25%, and DBP level was reduced by 5.21 mg/l. In addition, 12 fenvalerate metabolites were identified and a pathway for fenvalerate degradation by the cocultured strains was proposed. These results provide theoretical data for further exploration of the mechanisms used by this coculture system to degrade fenvalerate and DBP, and also offer a promising method for effective bioremediation of PPs and their related metabolites in polluted environments.

Optimal Design of Stiffness of Torsion Spring Hinge Considering the Deployment Performance of Large Scale SAR Antenna (전개성능을 고려한 대형 전개형 SAR 안테나의 회전스프링 힌지의 강성 최적설계)

  • Kim, Dong-Yeon;Lim, Jae Hyuk;Jang, Tae-Seong;Cha, Won Ho;Lee, So-Jeong;Oh, Hyun-Ung;Kim, Kyung-Won
    • Journal of Aerospace System Engineering
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    • v.13 no.3
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    • pp.78-86
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    • 2019
  • This paper describes the stiffness optimization of the torsion spring hinge of the large SAR antenna considering the deployment performance. A large SAR antenna is folded in a launch environment and then unfolded when performing a mission in orbit. Under these conditions, it is very important to find the proper stiffness of the torsion spring hinge so that the antenna panels can be deployed with minimal impact in a given time. If the torsion spring stiffness is high, a large impact load at the time of full deployment damages the structure. If it is weak, it cannot guarantee full deployment due to the deployment resistance. A multi-body dynamics analysis model was developed to solve this problem using RecurDyn and the development performance were predicted in terms of: development time, latching force, and torque margin through deployment analysis. In order to find the optimum torsion spring stiffness, the deployment performance was approximated by the response surface method (RSM) and the optimal design was performed to derive the appropriate stiffness value of the rotating springs.