• Bulletin of the Korean Chemical Society
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• 제22권1호
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• pp.37-42
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• 2001

Ridge regression is compared with multiple linear regression (MLR) for determination of Research Octane Number (RON) when the baseline and signal-to-noise ratio are varied. MLR analysis of near-infrared (NIR) spectroscopic data usually encounters a collinearity problem, which adversely affects long-term prediction performance. The collinearity problem can be eliminated or greatly improved by using ridge regression, which is a biased estimation method. To evaluate the robustness of each calibration, the calibration models developed by both calibration methods were used to predict RONs of gasoline spectra in which the baseline and signal-to-noise ratio were varied. The prediction results of a ridge calibration model showed more stable prediction performance as compared to that of MLR, especially when the spectral baselines were varied. . In conclusion, ridge regression is shown to be a viable method for calibration of RON with the NIR data when only a few wavelengths are available such as hand-carry device using a few diodes.

• 공업화학
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• 제4권4호
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• pp.753-759
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• 1993

리서취법과 모터법(RON과 MON)에 의한 가솔린 옥탄가는 가솔린의 연료로서의 성능에 관한 품질의 동력학적 측정값이다. 가솔린 옥탄가(RON과 MON)를 측정하기 위한 방법으로는 ASTM 표준엔진 시험방법(RON:ASTM D-2699, MON:ASTM D-2700)이 사용되고 있다. 그러나 이 방법은 재현성, 반복성 등이 매우 낮아서 오래 전부터 비판되어지고 있다. 또한 이 방법에 의한 측정시 그에 따른 비용 및 가동시간 등으로 인하여 비엔진 측정방법(기체 크로마토그래피법, 핵자기공명 분광법 등)에 대한 연구가 진행되어왔다. 본 연구에서는 $^{13}C-NMR$ 분광법을 이용하여 가솔린의 탄소 유형별 구조적 조성을 결정한 후 높은 정확도로 옥탄가(RON과 MON)를 예측하였다 그리고 옥탄가에 대한 가솔린의 분자구조적 조성의 영향에 관하여 고찰하였다.

• International Journal of Automotive Technology
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• 제8권1호
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• pp.1-7
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• 2007

The effect of the di-tertiary butyl peroxide (DTBP) additive on the heat release rate and emissions of a homogeneous charge compression ignition (HCCI) engine fueled with high Research Octane Number (RON) fuels were investigated. The experiments were performed using 0%, 1%, 2%, 3%, and 4% (by volume) DTBP-RON90 blends. The RON90 Fuel was obtained by blending 90% iso-octane with 10% n-heptane. The experimental results show that the operation range was remarkably expanded to lower temperature and lower engine load with the DTBP additive in RON90 fuel. The first ignition phase of HCCI combustion was observed at 850 K and ended at 950 K while the hot ignition occurred at 1125 K for all fuels at different engine working conditions. The chemical reaction scale time decreases with the DTBP addition. As a result, the ignition timing advances, the combustion duration shortens, and heat release rates were increased at overall engine loads. Meanwhile, the unburned hydrocarbon (UHC) and CO emissions decrease sharply with the DTBP addition while the NOx emissions maintain at a lower level.

• 오토저널
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• 제14권5호
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• pp.61-68
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• 1992

Knock phenomenon is an abnormal combustion originated from autoignition of unburned gas in the end-gas region during the later stage of combustion process and it accompanys a high pitched metallic noise. Engine Knock is accompanied with a vibration of engine cylinder and when it is severe, it can cause major engine demage. Engine Knock is characterized in terms of knock crank angle, knock pressure, pressure jump and knock intensity. In this study, a 4-cylinder spark ignition engine was used for experiment and eighty consecutive cycles were analyzed statistically. The purpose of this study is to characterize spark ignition engine knock as a function of ignition timing and fuel research octane number. The result of this study can be summerized as follows. Knock occurrence angle approached TDC as ignition timing is advanced. Pressure and knock intensity gradually increased as spark timing is advanced. Mean knock occurence angle gradually approached TDC as fuel research octane number is decreased for identical spark timing. Knock intensity increased linearly as RON is decreased.

• 한국분무공학회지
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• 제16권4호
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• pp.167-175
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• 2011

The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

• 한국자동차공학회논문집
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• 제6권4호
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• pp.178-185
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• 1998

To reduce the particulate matter and nitrogen oxides from diesel engine, many studies are proceeding and being accomplished practically. In this situation CNG engine has important meaning both as a clean fuel and an alternative energy. In order to present the direction and application of CNG, we simulated various operating conditions, that is, spark timing, compression ratio and fuel composition etc. Thus we try to understand how those affect performance and exhaust characteristics. The simulation program results found that the optimum combustion start angle was 21$^{\circ}$ at 1800rpm and fuel composition affects performance and emissions, also we could understand the formation of emission as crank angle is changed.

• 에너지공학
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• 제25권4호
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• pp.159-169
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• 2016

본 연구에서는 함산소기재 중 MTBE를 휘발유에 첨가하여 산소함량(0, 1.0, 2.3 및 2.7 wt %)의 변화에 따라 MPI 및 GDi 차량에서 배출되는 유해한 배출가스와 연비를 분석하였다. 국내 및 미국의 연비시험방법인 FTP-75 mode와 HWFET mode를 적용하였다. CO, NMHC, NOx 배출량은 산소함량의 변화에 따라 미미한 차이는 있었지만 상관관계는 없었다. FTP-75 mode에서 CO2 배출량은 산소함량의 변화에 따라 증감의 경향성은 없었다. 하지만 차량이 예열된 상태이고 고속 운전영역이 포함된 FTP-75 mode의 phase-3와 HWFET mode에서는 산소를 함유한 연료의 CO2 배출량이 적었다. 입자개수 배출량은 산소함량과 음의 상관관계를 보였으며 산소함량 2.3 wt %에서 가장 적었다. 카본발란스법에 의해 계산된 연비는 산소를 함유한 연료가 높았으며 2.3 wt %에서 가장 높았다.