• 대한상한금궤의학회지
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• v.8 no.1
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• pp.53-65
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• 2016

Objective : The purpose of this paper is to report the improved contact dermatitis(CD) treated with the herbal medication based on Shanghanlun disease pattern identification diagnostic system. The level V steroid ointments were no use to the patient 3weeks before the treatment. Methods : In this case, the patient was diagnosed according to 'Disease Pattern Identification Diagnostic System based on Shanghanlun Provisions' and took Mahwang-tang for 36days since the final diagnosis was Taeyang-byung, number 46 provision. The photographs of patient's hands were taken to observe the process of the skin status and the discomfort from CD was measured with DLQI(Dermatologic Life Quality Index) and NRS(Numeric Rating Scale). Results : The DLQI score changed from 24 to 7 and NRS of itching changed form 8 to under 4. Conclusions : This case report shows that the herbal medication through the diagnostic system could be a remedy on CD, dealing with the skin status with no use of the level V steroid ointments. It is needed proving an alternative possibility of Korean Medicine, on other skin diseases, with later studies since there are many reports on the side-effects after some long-term steroid treatments.

• Journal of The Korean Astronomical Society
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• v.43 no.3
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• pp.65-74
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• 2010

We investigate ${\rho}$ Pup using the high resolution spectral observations taken from the VLT archive and observations at a 1.8m-Korean telescope with BOES spectrograph. The atmospheric parameters are determined using the iron-line abundance analysis. We derive an effective temperature value of $T_{eff}=6890{\pm}250K$, surface gravity of log g=$3.28{\pm}0.3$ dex, microturbulent velocity of ${\upsilon}_{micro}=4.1{\pm}0.4km\;s^{-1}$, and the iron abundance of log N=$7.82{\pm}0.15$. The projected rotational velocity of the star is close to ${\upsilon}$ sin i=3.5km $s^{-1}$. Asymmetric line profiles in the observed spectra and variation of this asymmetry with time show that both strong radial pulsation and weak non-radial pulsations are present in ${\rho}$ Pup.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.4
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• pp.1039-1049
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• 1994

The intermitternt and transient fuel spray have been investigated from the simultaneous measurement of droplet sizes and velocities by using Phase/Doppler Particle Analyzer(PDPA). Measurement have been done on the spray axis and at the edge of the spray near nozzle at various gas-to-liquid density ratios(.rho./sub g//.rho./sub l/) that ranges from those found in free atmospheric jets to conditions typical of diesel engines. Probability density distributions of the droplet size and velocity were obtained from raw data and mathematical probability density functions which can fit the experimental distribations were extracted using the principle of maximum likelihood. In the near nozzle region on the spray axis, droplet sizes ranged from the lower limit of the measurement system to the order of nozzle diameter for all (.rho./sub g/ /.rho./sub l/) and droplet sizes tended to be small on the spray edge. At the edge of spray, average droplet velocity peaked during needle opening and needle closing. The rms intensity is greatly incresed as the radial distance from the nozzle is increased. The probability density function which can best fit the physical breakage process such as breakup of fuel drops is exponecially decreasing log-hypebolic function with 4 parameters.

• Journal of the Korean Chemical Society
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• v.48 no.5
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• pp.461-466
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• 2004

Kinetics for the nucleophiles have been studied under high vacuum and high pressures in various temperatures. Pseudo-first order rate constants, second order rate constants, thermodynamic parameters and Hammett ${\rho}$-values are determined. The values of ${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq}\;and\;{\Delta}S^{\neq}$are all negative. The Hammett r-values are negative for the nucleophile (${\rho}$x) over the pressure range studied. The results of kinetic studies for pressure and nucleophilet show that these reactions proceed in typical $S_N2$ reaction mechanism and change of mechanism.

• Bulletin of the Korean Chemical Society
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• v.24 no.2
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• pp.193-196
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• 2003

Nucleophilic addition reactions of benzylamines $(XC_6H_4CH_2NH_2)$ to benzylidene Meldrum's acids (BMA; $YC_6H_4CH=C(COO)_2C(CH_3)_2$) have been investigated in acetonitrile at 20.0 ℃. The rates of addition are greatly enhanced due to the abnormally high acidity of Meldrum's acid. The magnitudes of the Hammett $({\rho}_X\;and\;{\rho}_Y)$ and Bronsted $({\rho}_X$)$ coefficients are rather small suggesting an early transition state. The sign and magnitude of the cross-interaction constant, ${\rho}_{XY}$ (= -0.33), and kinetic isotope effects $(k_H/k_D\;{\stackrel}{~}{=}\;1.5-1.7)$ involving deuterated benzylamine nucleophilies $(XC_6H_4CH_2ND_2)$ are indicative of hydrogen-bonded cyclic transition state. The activation parameters, ${\Delta}H^{\neq}\;{\stackrel}{~}{=}\;4\;kcal\;mol^{-1}\;and\;{\Delta}S^{\neq}\;{\stackrel}{~}{=}\;-37\;e.u.$, are also in line with the proposed mechanism.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2339-2344
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• 2011

Kinetic studies for the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-pyridines have been carried out in dimethyl sulfoxide at 85.0 $^{\circ}C$. The Hammett and Br$\"{o}$nsted plots for substituent X variations in the nucleophiles are biphasic concave upwards with a break point at X = H, while those for substituent Z variations in the leaving groups are linear. The negative sign of the cross-interaction constant (${\rho}_{XZ}$) implies that the reaction proceeds through a concerted mechanism for both the strongly and weakly basic pyridines. The magnitude of ${\rho}_{XZ}$ (= -0.35) for the strongly basic pyridines is greater than that (${\rho}_{XZ}$ = -0.15) for the weakly basic pyridines, indicating a change of the nucleophilic attacking direction from frontside for the strongly basic pyridines to backside for the weakly basic pyridines. The early transition state is proposed on the basis of the absence of positive deviations from both the Hammett and Br$\"{o}$nsted plots for the strong ${\pi}$-acceptor, X = 4-Ac, and small values of ${\rho}_{XZ}$ and ${\beta}_X$.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.11 no.3
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• pp.403-409
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• 2000

In this paper, we measured and analyzed cross polarization discrimination(XPD), signal correlation coefficient($\rho$) and received signal level decrease, for the application of polarization diversity scheme in the up-link of microcell environments. We experimented in a dense building area, a dense residence area, a market area, a school area and etc at 1.9 GHz. Cross polarization discrimination (XPD) is about 6~11 dB, signal correlation coefficient($\rho$) is below 0.7 and received signal level decrease is smaller than 3 dB. The results of comparing polarization diversity with space diversity show that polarization diversity gain is about 2~5 dB higher in the various area. As a results, polarization diversity scheme is more effective than space diversity scheme in microcell environments.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.11 no.3
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• pp.429-436
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• 2000

In this paper, the performance of a orthogonal noncoherent FH-BFSK communication system in the presence of partial band noise jamming is analyzed. Also bit error rate(BER) is studied when jamming bandwidth ratio to overall spread spectrum bandwidth,$\rho$, changes according to processing gain(PG). The performance is investigated by numerical analysis and computer simulation of SPW. Even if PG is high, required performance could not gain because error floor occurs when JSR is 10 dB and SNR is under 10 dB. PG can be obtained to acquire a required BER according to $\rho$ when SNR is above 12 dB.

• Journal of the Korean Mathematical Society
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• v.8 no.1
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• pp.25-30
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• 1971

Put ($$^*$$) $$G[x,y]={\sum}\limits^{p+q=n}_{p,q=0}[-n]_{p+q}c_{p,q}x^py^q$$, where $[{\lambda}]_m$ is the Pocbhammer symbol and the $c_{p,q}$ are arbitrary constants. Making use of the specialized forms of some of his earlier results (see [8] and [9] the author derives here bilateral generating functions of the type ($$^{**}$$) $${\sum}\limits^{\infty}_{n=0}{\frac{[\lambda]_n}{n!}}_2F_1[\array{{\rho}-n,\;{\alpha};\\{\lambda}+{\rho};}x]\;G[y,z]t^n$$ where ${\alpha}$, ${\rho}$ and ${\lambda}$ are arbitrary complex numbers. In particular, it is shown that when G[y, z] is a double hypergeometric polynomial, the right-band member of ($^{**}$) belongs to a class of general triple hypergeometric functions introduced by the author [7]. An interesting special case of ($^{**}$) when ${\rho}=-m,\;m$ being a nonnegative integer, yields a class of bilateral generating functions for the Jacobi polynomials $\{P_n{^{{\alpha},{\beta}}}(x)\}$ in the form ($$^{***}$$) $${\sum\limits^{\infty}_{n=0}}\(\array{m+n\\n}\)P{^{({\alpha}-n,{\beta}-n)}_{m+n}(x)\;G[y,z]{\frac{t^n}{n!}}$$, which provides a unification of several known results. Further extensions of ($^{**}$) and ($^{***}$) with G[y, z] replaced by an analogous multiple sum $H\[y_1,{\cdots},y_m\]$ are also discussed.

• Journal of the Korean Chemical Society
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• v.27 no.6
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• pp.391-398
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• 1983

The reaction for the hydrogen abstraction from substituted-toluenes by t-butoxyl and t-butyl radical have been studied MO theoretically using CNDO/2 method. The reaction for the abstraction from substituted-toluenes by t-butoxyl radical showed the negative ${\rho}$ values from Hammett equation, since t-butoxyl radial is electrophilic, relatively low energy SOMO, which can interact with HOMO energy of substituted-toluens. On the other hand, t-butyl radical is nucleophilic, relatively high energy SOMO, which can interact with LUMO energy of substituted-toluenes. And so the reaction of abstraction from substituted-toluenes by t-butyl radical exhibited positive ${\rho}$ values.