• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.1
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• pp.42-53
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• 2004

An experimental study on the refrigerant-side pressure drop of slit fin-tube heat exchanger has been carried out. A comparison was made between the predictions of previously proposed empirical correlations and experimental data for the pressure drop on design conditions of condenser in micro-fin tube for R22 and its alternatives, R407C (R32/125/134a, 23/25/52 wt.％) and R410A (R32/125, 50/50 wt.％). Experiments were carried out under the conditions of inlet refrigerant temperature of 6$0^{\circ}C$ and mass fluxes varying from 150 to 250 kg/$m^2$s for R22, R407C and R410A. The inlet air conditions are dry bulb temperature of 35$^{\circ}C$, relative humidity of 40% and air velocity varying from 0.68 to 1.43 m/s. Experiments show that pressure drop for R410A and R407C were 17.8∼20.2％ and 5∼6.8％ lower than those of R22 respectively for the degree of subcooling of 5$^{\circ}C$. For the mass fluxes of 200∼250 kg/$m^2$s, the deviation between the experimental and predicted values for the pressure drop was less than $\pm$20％ for R22, R407C and R410A.

• Journal of Life Science
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• v.14 no.1
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• pp.91-97
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• 2004

As a part of our study on the improvement of anticonvulsant, here we report the synthesis of N-acyl-$\alpha$-aminosuc-cinimides 1 and N-acyl-$\alpha$-aminoglutarimides 2. (R)-Benzoic acid 4-benzyloxycarbonylamino-2-oxo-pyrrolidin-1-ylester 6a, (R)-4-nifro-benzoic acid 4-benzyloxycarbonylamino-2- oxo-pyrrolidin-1-yl ester 6b, (R) -4-nitro-benzoic acid 4-benzyloxycarbonylamino-2-oxo-pyrrolidin-1-yl ester 6c, and (R)-propionic acid 4-benzyloxycarbonylamino-2-oxo-pyrrolidin-1-yl ester 6d were synthesized from (R)-2-benzyloxy carbonylamino-succinic acid 3 as a starting meterial. (R)-(3- Benzyloxycarbonylamino-2,6-dioxo-piperidin-1-yloxy)-acetic acid methyl ester 10a, (R)-(3-benzyloxycarbonylamino-2,6-dioxo-piperidin-1-yloxy)-acetic acid ethy1 ester 10b, an d (R)-2-(3-benzyloxycarbonylamino-2,6- diox o-piperidin-1-yl oxy)-propionic acid methyl ester l0c were synthesized from (R)- 3-carbobenzyloxy-amino-glutarmic acid 7 as a starting meterial. The yield, mp, IR, $^1H-NMR,\; and^{13}C$- NMR spectra of the products 6a, 6b, 6c, 6d, 10a, l0b, l0c are summarized in footnote. The biological studies of these compounds are in progress and will be reported in future.

• Journal of the Korean Mathematical Society
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• v.44 no.3
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• pp.683-695
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• 2007

A tournament is an orientation of a complete graph, and in general a multipartite or c-partite tournament is an orientation of a complete c-partite graph. In a recent article, the authors proved that a regular c-partite tournament with $r{\geq}2$ vertices in each partite set contains a cycle with exactly r-1 vertices from each partite set, with exception of the case that c=4 and r=2. Here we will examine the existence of cycles with r-2 vertices from each partite set in regular multipartite tournaments where the r-2 vertices are chosen arbitrarily. Let D be a regular c-partite tournament and let $X{\subseteq}V(D)$ be an arbitrary set with exactly 2 vertices of each partite set. For all $c{\geq}4$ we will determine the minimal value g(c) such that D-X is Hamiltonian for every regular multipartite tournament with $r{\geq}g(c)$.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.2
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• pp.210-218
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• 1998

Experimental results for forced convection condensationof Refrigerant-22 and ternary Refrigerant-407c(HFC-32/125/134a 23/25/52 wt%) considered as a substitute R-22 inside horizontal micor-fin tubes are presented. The test section was horizontal double-tubed counterflow condenser with a length 4000 mm micro-fin tube having 9.53 mm OD., 0.2 mm fin height and 60 fins. The refrigerants R-22 and R-407c were cooled by a coolant circulated in a surrounding annulus. The range of parameters of mass velocity was varied from 102.1 to 301.0kg/($\textrm{m}^{2}.s$) with inlet quality 1.0. Both refrigerant R-22 and its alternative refrigerant R-407c were tested within the same range of parameters. At the given experimental conditions for R-22 and R-407c the pressure drops for R-407c were considerably higher than those for R-22 at micro-fin tubes. Over the mass velocity range tested the PF(penalty factor)was lower than the increasing ratio of heat transfer area by fins. Based on the data correlation was proposed for predicting the frictional pressure drops for R-22 and R-407c for a duration of condensation inside a horizontal micro-fin tube.

• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.113-117
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• 1993

Good yield synthetic routes for the production of new B-alkyl-dithiaborane clusters are reported. The syntheses of the B-alkyl-dithiaboranes are based on the use of Fischer-type carbene reagents to activate the B-H bonds of dithiaborane for alkyl-addition reactions and are the first examples of transition-mediated reactions of dithiaborane to be reported. Thus, reactions employing arachno-$S_2B_7H_8$- and $(CO)_5M{C(R_1)R_2}$ (M = Cr, W; $R_1 = CH_3,\;C_6H_5;\; R_2 = OCH_3,\;SC_6H_5)$ were found to yield the intermidiate anions I, $[(CO)_5M{C(R_1)R_2S_2B_7H_8}]^-$, which upon protonation gave the corresponding neutral, air-sensitive cluster arachno-4-$RCH_2-6,8-S_2B_7H_8(R=CH_3,\;IIa;\;C_6H_5,\;IIb)$ range from 30 to 35% yield. Complexes IIa and IIb are isoelectronic with arachno-6,8-$S_2B_7H_9$ and, on the basis of the spectroscopic data, are proposed to adopt a similar arachno cage geometry in which an $RCH_2$ units are substituted to 4 position boron atom of the arachno-6,8-$S_2B_7H_9$.

• Journal of the Mineralogical Society of Korea
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• v.16 no.3
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• pp.223-232
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• 2003

The co-precipitation method is applied to synthesize the cathode material Li[L $i_{x}$M $n_{1-x-y}$C $r_{y}$ ] $O_2$ for lithium rechargeable batteries at $650^{\circ}C$ (CR650) and 8$50^{\circ}C$ (CR850), respectively. Rietveld indices indicate that $R_{wp}$ with respect to $R_{exp}$ ( $R_{wp}$/ $R_{exp}$) are 9.2%/10.1% for CR650 and 15.9%/9.76% for CR850, respectively. $R_{B}$ and S (GofF) shows 10.9%, 8.54% and 1.9, 1.6, respectively. Rietveld structure refinement reveals that layer structure of LiMn $O_2$ (R3m) coexists with lower symmetry of Li[L $i_{1}$3/M $n_{2}$3/] $O_2$ (C2/c) due to superlattice ordering of Li and Mn in metal-transition containing layers. Unit-cell parameters are calculated as a=2.8520(2)$\AA$, c=14.248(2)$\AA$, V=100.40(l)$\AA^3$ for CR650, and a=2.8504(1)$\AA$, c=14.2371(7)$\AA$, V=100.179(8)$\AA^3$ for CR850. Final chemistry is obtained as Li[L $i_{0.35}$M $n_{0.56}$C $r_{0.09}$] $O_2$ (CR650) and Li[L $i_{0.27}$M $n_{0.61}$C $r_{0.13}$] $O_2$ (CR850), respectively.y...y..vely.y...y..

• Journal of Powder Materials
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• v.8 no.2
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• pp.124-130
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• 2001

A centrifugally atomized 2024A1/SiC/sub p/ composites were extruded to study effect of clusters on mechanical properties, and a model was proposed that the strength of MMCs would be estimated from the load transfer model approach that taken into consideration of the clusters. This model has been successfully utilized to predict the strength and fracture toughness of MMCs. The experimental and calculated results show coincidence and that the fracture toughness decreases with increasing the volume fraction of particles. On the basis of experimental observations, we suggest that the strength and fracture toughness of particle reinforced MMCs may be calculated from; σ/sub y/=σ/sub m/V/sub m/+σ/sub r/(V/sub r/-V/sub c)-σ/sub r/V/sub c/, K/sub IQ/=σ/sub Y/((3πt)((r/sub r//V/sub r/)(r/sub c//V/sub c/))/sup 1/2/)/sup 1/2/, respectively.

• Journal of the Korean Ceramic Society
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• v.37 no.4
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• pp.359-367
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• 2000

Particulate composites of Al2O3/SiC, Al2O3/ZrO2 and Al2O3/ZrO2/SiC have been fabricated to investigate their R-curve behaviors and toughening mechanisms. Al2O3 containing 30 vol% SiC particles of 3${\mu}{\textrm}{m}$ showed rising R-curve behavior owing to the strong crack bridging by SiC particles. The fracture toughness reached 9.1 MPa {{{{ SQRT {m} }} at the crack length of 1000${\mu}{\textrm}{m}$. On the other hand, ZrO2-toughened Al2O3 had a high flat R-curve since it rose steeply in the short crack region due to the well known transformation toughening. For Al2O3/ZrO2/SiC composites, the R-curve behavior was similar to that of Al2O3/SiC but with slightly higher toughness. The SiC particles in this composite decreased the amount of transformable tetragonal phase to reduce the effect of transformation toughening by 50%. It was also found that the fracture toughness of this composite with two different toughening mechanisms was markedly lower than that estimated by the simple addition of two contributions.

• Journal of the Korean Chemical Society
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• v.41 no.3
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• pp.150-156
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• 1997

A precursor of bulgecinine, (4S,5R)-1-acetyl-2-formyl-5-benzyloxymethyl-4-pyrrolidinol (15) has been synthesized from diacetone-D-glucose. Barton deoxygenation, conversion to an L-sugar and displacement with $N_3^-$ at C-5, and one-pot reductive cyclization at C-2 produced (6R)-6-Ο-benzyloxymethyl-(3R)-3-methoxy-2-oxa-5-azabicyclo-[2,2,1]heptane(13), a key intermediate for bulgecinine. N-Acetylation and acid hydrolysis of 13 furnished a precursor of bulgecinine, (2S,4S,5R)-pyrrolidinol derivative 15 and its (2R,4S,5R)-diastereomer.

• Geomechanics and Engineering
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• v.23 no.2
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• pp.115-125
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• 2020

This study aims to explore practical and useful equations for rapid evaluation of uniaxial compressive strength of concrete (UCS-C) during the preliminary design stage of aggregate selection. For this purpose, aggregates which were produced from eight different intact rocks were used in the production of concretes. Laboratory experiments involved the tests for uniaxial compressive strength (UCS-R), point load index (PLI-R), P wave velocity (UPV-R), apparent porosity (n-R), unit weight (UW-R) and aggregate impact value (AIV-R) of the rock samples. UCS-C, point load index (PLI-C) and P wave velocity (UPV-C) of concrete samples were also determined. Relationships between UCS-R-rock parameters and UCS-C-concrete parameters were developed by regression analyses. In the simple regression analyses, PLI-C, UPV-C, UCS-R, PLI-R, and UPV-R were found to be statistically significant independent variables to estimate the UCS-C. However, higher coefficients of determination (R²=0.97-1.0) were obtained by multiple regression analyses. The results of simple regression analysis were also compared to the limited number of previous studies. The strength conversion factor (k) values were found to be 14.3 and 14.7 for concrete and rock samples, respectively. It is concluded that the UCS-C can roughly be estimated from derived equations only for the specified rock types.