• Title/Summary/Keyword: R-DOC

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Comparison of Solidification Pre-treatment Methods for the Determination of δ13C of Dissolved Organic Carbon: Alkaline Persulfate Oxidation-Carbonate Precipitation vs. Freeze Drying (용존유기탄소의 δ13C : 분석시 고형화 전처리 방법 비교 알칼린 과황산칼륨산화 탄산침전과 동결건조)

  • Jeon, Byeong-Jun;Park, Hyun-Jin;Choi, Woo-Jung;Park, Yong-Se;Lee, Sang-Mo;Yoon, Kwang-Sik
    • Korean Journal of Environmental Agriculture
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    • v.36 no.2
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    • pp.113-118
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    • 2017
  • BACKGROUND: The carbon (C) isotope ratio (${\delta}^{13}C$) of dissolved organic C (DOC) is an indicator of water pollution source. In this study, the potential use of two pre-treatments for the ${\delta}^{13}C$ analysis, alkaline persulfate oxidation coupled with carbonate precipitation (precipitation) and freeze drying (drying), were compared to suggest a more feasible pre-treatment method. METHODS AND RESULTS: Two reference materials with different ${\delta}^{13}C$ values were used for the experiments; chemical grade glucose ($-12.0{\pm}0.02$‰) and pig manure compost extract ($-23.3{\pm}0.04$‰). In the precipitation method, the measured ${\delta}^{13}C$ values were consistently lower than the theoretically calculated values as dissolved $CO_2$ could not be removed due to the alkaline property of the reagents and the dissolution of air $CO_2$ into the alkaline solution. The drying method also resulted in more negative ${\delta}^{13}C$ than the calculated ${\delta}^{13}C$; however, the difference was systematic ($3.9{\pm}0.3$‰) and there was a strong correlation (${\delta}^{13}C_{calculated}=0.87{\times}{\delta}^{13}C_{measured}-0.624$, $r^2=0.98$) between the calculated and measured ${\delta}^{13}C$. Calibration of ${\delta}^{13}C$ using the relationship between the calculated and the measured ${\delta}^{13}C$ values produced reliable and accurate ${\delta}^{13}C$ values. CONCLUSION: Our results suggest that the drying method is more accurate pre-treatment method to minimize the influence of air $CO_2$ compared to the precipitation method for the determination of ${\delta}^{13}C$ of DOC.

Conversion of CODMn into TOC and Refractory Organic Matter Concentrations for Treated Sewage using Regression Equations (회귀식을 사용한 하수처리장 방류수 CODMn 농도의 총 유기탄소 및 난분해성 물질 농도 전환)

  • Lee, Tae-Hwan;Lee, Bomi;Hur, Jin;Jung, Myung-Sook;Kang, Tae-Gu
    • Journal of Korean Society on Water Environment
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    • v.26 no.6
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    • pp.969-975
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    • 2010
  • Estimating the organic matter loadings from individual treated sewage has become important for establishment of effective management strategies to control refractory organic matter (R-OM) in watersheds. For this study, regression equations were constructed using treated sewage data to convert the chemical oxygen demand (COD) concentrations, which are mostly available from open database, into total organic carbon (TOC) and R-OM concentrations. Effluent samples were collected from five major sewage treatment plants (STPs) located upstream of the lake Paldang. Variations in the OM concentrations were not associated with either the location of the STP or the sampling season. The effluent investigated were characterized by higher ratio of R-OM with respect to biodegradable organic matter (B-OM) and higher presence of dissolved organic matters (DOM) versus particulate organic matter (POM). Compared to $COD_{Mn}$, $COD_{Cr}$ exhibited higher oxidation efficiencies and greater variations in the concentrations. The concentrations of $COD_{Mn}$ were positively correlated with dissolved organic carbon (DOC), total organic carbon (TOC), and R-OM concentrations. There was nearly no seasonal and annual variation in the regression equations between $COD_{Mn}$ and TOC or R-OM concentrations. The constructed regression equations for TOC and R-OM were $0.650({\pm}0.071){\times}COD_{Mn}+1.426({\pm}0.575)$ and $0.340({\pm}0.083){\times}COD_{Mn}+2.054({\pm}0.670)$, respectively. The established equations are expected to contribute to estimating OM loadings from the STPs into the lake Paldang and also to compensating for the deficiency of the data for effluent OM concentrations in STP.

Estimation of Dissolved Organics Characteristics and THM Formation from Different Organics Sources Based on Molecular Weight Distribution

  • Jeong, Kyu-Yeon;Ko, Young-Song;Lee, Yoon-Jin
    • Journal of Environmental Health Sciences
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    • v.33 no.2 s.95
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    • pp.158-165
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    • 2007
  • 본 연구는 근원에 따른 용존 유기물의 특성을 평가하기 위해 하천수, 호소수, 하수 2차 처리 유출수의 자연수 및 Aldrich, Wako 사에서 공급된 휴믹산을 대상으로 분자량 분포에 따른 물리 화학적인 수질 특성, 생분해도, 소독, 부산물의 생성 등을 고찰하였다. SUVA를 이용해서 자연수의 생분해 가능성을 평가한 결과 호소수, 하수, 하천수 순으로 예측되었으며 이는, 실제 생분해도 실험 결과와 유사하였다 생분해 반응 중 저분자 영역대의 용존 유기물은 점차 감소하였고 반면에 고분자 영역대의 용존 유기물은 증가하였다. SMP는 전체 용존 유기물의 0.7-5.5%정도 관찰되었으며 고분자 물질을 많이 함유한 시료에서 높게 나타났다. THM 생성은 대체로 고분자 물질이 높을수록 증가하였으며 THMFP도 Wako 휴믹산을 제외한 샘플에서 이와 유사한 경향을 나타냈다.

Effect of Hysteretic Models on the Inelastic Design Spectra (비탄성 설계 스펙트럼에 의한 이력 모델의 효과)

  • 한상환;오영훈;이리형
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.214-224
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    • 1999
  • The design response spectrum has been widely used in seismic design to estimate force and deformation demands of structures imposed by Earthquake Ground Motion (EQGM). Inelastic Design Response Spectra (IDRS) to specify design yielding strength in seismic codes are obtained by reducing the ordinates of Linear Elastic Design Response Spectrum (LEDRS) by strength reduction factor (R). Since a building is designed using reduced design spectrum (IDRS) rather than LEDRS in current seismic design procedures it allows structures behave inelastically during design level EQGM. Inelastic Response Spectra (IRS) depend not only on the characteristics of the expected ground motion at a given site, but also on the dynamic properties and nonlinear characteristics of a structure. However, it has not been explicitly investigated the effect of different hysteretic models on IRS. In this study, the effect of hysteretic models on IRS is investigated.

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Dense Retrieval using Pretrained RoBERTa with Augmented Query (증강된 질문을 이용한 RoBERTa 기반 Dense Passage Retrieval)

  • Jun-Bum Park;Beomseok Hong;Wonseok Choi;Youngsub Han;Byoung-Ki Jeon;Seung-Hoon Na
    • Annual Conference on Human and Language Technology
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    • 2022.10a
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    • pp.141-145
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    • 2022
  • 다중 문서 기반 대화 시스템에서 응답 시스템은 올바른 답변을 생성하기 위해서 여러 개의 문서 중 질문과 가장 관련 있는 문서를 검색하는 것부터 시작해야 한다. DialDoc 2022 Shared Task[1]를 비롯한 최근의 연구들은 대화 시스템의 문서 검색 과정을 위해 Dense Passage Retrieval(DPR)[2] 모델을 사용하고 있으며 검색기의 성능 개선을 위해 Re-ranking과 Hard negative sampling 같은 방법들이 연구되고 있다. 본 논문에서는 문서에 기반하는 대화 데이터의 양이 적거나 제한될 경우, 주어진 데이터를 효율적으로 활용해 보고자 검색기를 생성 모델을 이용하여 문서의 엔티티를 기반으로 질문을 생성하고 기존 데이터에 증강하는 방법을 제시했으며 실험의 결과로 MRR metric의 경우 0.96 ~ 1.56의 성능 향상을, R@1 metric의 경우 1.2 ~ 1.57의 성능 향상을 확인하였다.

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Establishment and Application of a Comprehensive Business Model Framework : Focusing on Healthcare Business Models (포괄적 비즈니스 모델 프레임워크 구축 및 적용 : 헬스케어 비즈니스 모델을 중심으로)

  • Yeon, Younghee;Lee, Baekhee;Kim, Eunha;Park, Boyoung;You, Heecheon
    • Journal of Korean Institute of Industrial Engineers
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    • v.41 no.6
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    • pp.530-539
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    • 2015
  • A business model (BM) can be developed based on a business model framework (BMF) consisting of key components such as value proposition, customers, and resources. To systematically generate and analyze emerging BMs such as healthcare BM, an integration of diverse BMF components is needed. The present study is to establish a comprehensive BMF and evaluate its applicability to healthcare BMs. Based on a review of eight BMF studies, ten BMF components were identified and classified into five major components (value proposition, resources, organizing model, customers, and revenue model) and five minor components (technology, service platform, delivery, competitive strategy, and growth/exit) by analyses of frequency and functional importance. Lastly, the BMs of three emerging healthcare companies (WellDoc, Inc., CFW Shops, and Aravind Eye Care System) were analyzed and compared in terms of the proposed BMF components. The comprehensive BMF components presented in the study can be of help for developing new BMs and analyzing the strengths and weaknesses of BMs.

A Study on the Diatomaceous Earth Filtration of Settling Basin Effluent (정수장 침전지 유출수의 규조토 여과에 관한 연구)

  • Shin Dae-Yewn;Ji Sung-Nam;Moon Ok-Ran;Kim Ji-Yeong;Suh Dong-Woo;Cho Young-Kwan
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.410-416
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    • 2004
  • The objective of this investigation was to evaluate applicability of precoat filtration that can be substituted for rapid sand filter of conventional water treatment system(CWTS). Precoat filter used in this experiment are candle filter. Element disk of candle are pore size $10{\mu}m(R),\;20{\mu}m(B)$ And diatomaceous earth are cake pore size $3.5{\mu}m$(Standard Super- Cel; A), $7{\mu}m$(Hyflo Super-Cel; B) and $17{\mu}m$(Celite 545RV; C). $2kg/m^2$ diatomaceous earth is used for precoating, it coated candle in $5{\sim}6mm$ thickness. 1. Al adsorption dosages by diatomaceous earth used in experimental we Hyflo Super-Cel 0.843mg/g, Standard Super-Cel 0.782 mg/g and Celite 545RV 0.766 mg/g. 2. Filtrate of precoat filter during 60min are R-C combination 20.7($m^3/m^2$)>B-C 18.3($m^3/m^2$)>B-B 15.0($m^3/m^2$)> R-B 12.9($m^3/m^2$)> R-A 11,093($l/m^2$). 3. Water quality of precoat filter effluent are thus. $KMnO_4$ consumption are $1.10{\sim}2.20mg/l$, removal rate are $30.9{\sim}65.6\%$. They are R-A 1.10(mg/l)(removal rate $65.6\%$). R-C(2.20 mg/l)(removal rate $30.9\%$). 4. $Al^{3+}$ are not detected with all combination, removal rate $100\%$. 5. Considering water quality and flux, continued running time of R-A combination is 7 hr. Accumulated filtrate are $74.4 m^3/m^2$, average flux is $177.2 l/m^2{\cdot}min$. And filtrate per diatomaceous earth 1g are 37.2 l. 6. R-A effluent's water quality are $KMnO_4$ Consumption 1.10(mg/l), DOC 1.161 mg/1, Al 0.0 mg/1, $UV_{254}$ 0.016/cm, Turbidity 0.1(NTU). R-A combination is suitable to precoat filtration for the settling basin effluent treatment.

Factors Affecting the Formation of Iodo-Trihalomethanes during Chlorination in Drinking Water Treatment (정수처리에서 염소 처리시 요오드계 트리할로메탄류 생성에 영향을 미치는 인자들)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Kim, Kyung-A;Song, Mi-Jeong;Choi, Jin-Taek
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.542-548
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    • 2014
  • Effects of bromide ($Br^-$) and iodide ($I^-$) concentrations, chlorine ($Cl_2$) doses, pH, temperature, ammonia nitrogen concentrations, reaction times and water characteristics on formation of iodinated trihalomethanes (I-THMs) during oxidation of iodide containing water with chlorine were investigated in this study. Results showed that the yields of I-THMs increased with the high bromide and iodide level during chlorination. The elevated pH significantly increased the yields of I-THMs during chlorination. The formation of I-THMs was higher at $20^{\circ}C$ than $4^{\circ}C$, $10^{\circ}C$ and $30^{\circ}C$. In chloramination study, addition of ammonium chloride ($NH_4Cl$) markedly increased the formation of I-THMs. Among the water samples collected from seven water sources including wastewater treatment plant (WWTP) effluent water (EfOM water), prepared humic containing water (HA water) and algal organic matter (AOM) containing water (AOM water), EfOM water generated the highest yields of I-THMs ($12.31{\mu}g/mg$ DOC), followed by HA water ($4.96{\mu}g/mg$ DOC), while AOM water produced the lowest yields of I-THMs ($0.99{\mu}g/mg$ DOC). $SUVA_{254}$ values of EfOM water, HA water and AOM water were $1.38L/mg{\cdot}m$, $4.96L/mg{\cdot}m$ and $0.97L/mg{\cdot}m$, respectively. The I-THMs yields had a low correlation with $SUVA_{254}$ values ($r^2$ = 0.002).

Investigation on Bromate Formation and Removal of NOM during Ozonation in Super Ozone Mass Transfer Reactor (고효율 오존장치를 이용한 NOM 제거 및 Bromate 생성 특성)

  • Song, Ki-Ju;Choi, Il-Hwan;Baek, Kyoung-Hee;Lee, Sang-Tae
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1137-1143
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    • 2006
  • In this study we investigated the removal characteristics of NOM and bromate formation characteristics in SOMT reactor. The system was recently developed as a novel ozone reactor and installed in SJ pilot plant. DOC values were decreased within 3% after treatment of 0.5~2.0 mg/L ozone dosage in SOMT reactor while the $UV_{254}$ value was 69% decreased at 2.0 mg/L ozone dosage. The composition of NOM was analysed by LC-OCD (Organic Cabon Detector) after ozone treatment in SOMT reactor to elucidate the variation of NOM character. Polysaccharide (more than 20,000 g/mol) fraction of NOM was decomposed while building blocks (350~500 g/mol) and neutral (less than 350 g/mol) fraction increased. Spiked bromide reacted with 0.5~2.0 mg/L ozone dosage in the SOMT reactor. The bromate formation was proportional to the ozone dosage ($R^2=0.978$) but not proportional to reaction time. The maximum concentration of formated bromate was not exceeded to 10% of spiked bromide concentration.

Effect of Freezing on Proteins and Protein Profiles of Sperm Membrane Extracts and Seminal Plasma of Buffalo Bulls

  • Dhanju, C.K.;Cheema, R.S.;Kaur, S.P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.12
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    • pp.1678-1682
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    • 2001
  • The total proteins were estimated in both deoxycholate (DOC)-extract of sperm membrane and seminal plasma of chilled as well as frozen semen obtained from five Murrah buffalo bulls. Proteins were further characterized by polyacrylamide gel electrophoresis (PAGE) in three bulls. The protein content of sperm membrane extract (SME) and that of seminal plasma (SP) decreased gradually with increase in freezing period from 6 to 24 mo when compared with the values observed in freshly chilled semen in all bulls. The total decrease in protein content of SME and SP varied from 30-40% and 28-59% respectively during 6-24 mo of freezing. The number of glycoproteins/proteins (GP/P) in SME varied from 4-8 in freshly-chilled semen of all bulls and reduced to 2-4 after 24 mo of freezing. In SP, the number of proteins varied from 6-10 in freshly chilled semen of all bulls and reduced to 3-8 after 24 mo of freezing. Some of the proteins in SME and SP disappeared, others got altered and appeared with change in molecular weight after different freezing times. These studies reveal that alterations in the sperm membrane proteins may be responsible for damage to their membrane during freezing and thus lowering their fertilizability.