• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.704-710
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• 2017

Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.5
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• pp.431-439
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• 2013

A cooling system is adopted to control the thermal load from the avionic equipments in an aircraft for stable operation. In this study, an avionic cooling system was designed and manufactured by adopting a vapor compression cycle with a closed-loop air-circulation system to investigate the operating characteristics of an alternative refrigerant. The performance characteristics of a cooling system adopting R236fa as an alternative refrigerant were experimentally determined by varying the refrigerant charging amount, expansion valve opening, and compressor rotation speed. The experimental results were analyzed and compared with those of a cooling system adopting R124 as a refrigerant. The possibility of the adoption of R236fa as an alternative refrigerant was verified, and design solutions were suggested to improve the system efficiency.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.4
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• pp.282-287
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• 2016

Recently in order to protect the ocean environment and to reduce energy consumption, shipbuilders have been developing highly economized ships. This research analyzed the possibility of adopting the onshore absorption refrigerator to offshore ships having a cooling system with refrigerant by using the waiste heat of the engine jacket cooling water instead of compression refrigerators. The results showed that R236fa could be a suitable medium for absorbing the heat of the absorber and condenser in an absorption refrigerator. The cooling system using R236fa achieved a high COP of 0.798, which is 15% and 5% higher than an air cooling system with a cooling tower and a water cooling system with a heat exchanger, respectively. The cooling system with R236fa achieved high efficiency with a 25% reduction in flow rate of LiBr solution and only 15.7% flow rate of cooling medium as compared to the water cooling system. The heating of sea water by the engine jacket water flowing out from the generator can prevent the crystallization of LiBr solution due to the low temperature of sea water.

• Journal of Power System Engineering
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• v.18 no.6
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• pp.120-125
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• 2014

In this paper, suitable working fluid of 1MW Organic Rankine Cycle(ORC) with liquid-vapor ejector using effluent from power plant is selected. The results of comparison performance of 5 refrigerants are as follows; R600a, R134a, R1270, R236fa, R235fa. The operating parameters considered in this study include the condensation capacity evaporation capacity and efficiency. As a result of comparison of basic ORC system and with liquid-vapor ejector, with ORC system presents the higher system efficiency since the ejector makes the turbine outlet pressure lower than condensation pressure through its pressure recovery. Also, this ejector ORC system is advantageous in miniaturizing the size of components owing to decrease of evaporation capacity and condensation capacity.

• The KSFM Journal of Fluid Machinery
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• v.18 no.4
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• pp.5-12
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• 2015

Several working fluids for Organic Rankine Cycle(ORC) were recommended by many researchers. However, the recommended optimal working fluids were not exactly same because the operating conditions of ORC and application were different. The major parameter to select the working fluid for ORC was the temperature of available thermal energy. In this study, low-grade thermal energy was used for the heat source for ORC and the appropriate working fluids were searched among 26 candidate working fluids. The requirements to be a working fluid for ORC were reviewed and the cycle analysis for simple cycle was conducted with $75^{\circ}C$ and $35^{\circ}C$ at the turbine inlet and exit, respectively. R600, R601, toluene were best candidates if the system could work without leaking the working fluid. Next, R236ea, R245ca, R245fa were recommended because they are not inflammable working fluids as well as better efficiency.