• Journal of Advanced Marine Engineering and Technology
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• 제33권4호
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• pp.533-538
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• 2009

The magnitude of constraint effect $A_2$ values on the non-linear elastic plastic fracture toughness was experimentally estimated by using displacement at various measuring positions near crack tip. Constraint effect $A_2$ value was dependent on specimen configuration and on the measured displacement near crack front. The crack tip opening displacement in the vicinity of the crack tip front should be estimated within plastic region when appropriately constraint effect was calculated. It was found that the magnitude of constrain effect |$A_2$| is below 8.0 at the crack tip. But an appropriate location to measure the effective constraint effects $A_2$ at the critical value of J that crack initiation is characterizable by is r = 2mm and ${\theta}=90^{\circ}$ away from original crack tip, and the constraint effect |$A_2$| estimated is 5.3.

• Archives of Pharmacal Research
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• 제25권3호
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• pp.275-279
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• 2002

The crystal structure of byakangelicin, one of furanocoumarin aldose reductase inhibitors, was determined by X-ray diffraction method. The crystal is triclinic, with a=8.114(1), b=10.194(1), $c=11.428(1)\AA,{\;}{\alpha}=111.50(1),{\}{\beta}=95.57(1),{\}{\gamma}=112.52(1)^{circ},{\;}D_x=1.41,{\;}D_m=1.39{\;}g/cm^3$, space group P1 and Z=2. The intensity data were collected by ${\omega}-2{\theta}$ scan method with $CuK_{a}$ radiations. The structure was solved by direct method and refined by full matrix least-squares procedure to the final R-value of 0.056. There are two molecules with different conformations in an asymmetric unit. The molecules are kept by two intermolecular O-HO type hydrogen bonds and van der Waal's forces in the crystal. The absolute configuration of the molecules was estimated to S-form by the 'Eta refinement' procedure.

• 대한조선학회논문집
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• 제48권2호
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• pp.141-146
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• 2011

This study numerically carried out the propeller open water test(POW) by solving Navier-Stokes equations governing the three-dimensional unsteady incompressible viscous flow with the turbulence closure model of the ${\kappa}-{\omega}$ SST model. Numerical simulations are performed at various range of advance ratios. Corresponding to Reynolds numbers of $5.89{\times}105{\sim}6.47{\times}105$ based on free stream velocity and the chord length at 0.7 propeller radius. The present results give a good agreement with those of the experiment. The propeller induced vortical structures have been analyzed by visualizing the resultant vorticity. As the advance ratio increases, the magnitude and length of the resultant vorticity decrease significantly. As the main focus of present study, the numerical model to present the ($r-{\theta}$) plane-averaged resultant vorticity along the streamwise direction for various advance ratios has been suggested.

• 한국주조공학회지
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• 제31권4호
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• pp.191-197
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• 2011

Transparent organic materials have been frequently used as an analog of the solidifying metallic materials, because their transparency permits an in-situ observation of the microstructural development during solidification through optical microscopy. Pivalic acid (PVA)-ethanol system showing an anisotropic property in solid-liquid interfacial energy and interface kinetics was adopted in the present experiment, and the detailed experiments performed are as follows: (1) variation of dendrite tip temperature with growth velocity, (2) correlation between primary dendrite arm spacing (${\lambda}_1$) and the growth orientation away from the heat flow direction (tilt angle: ${\theta}$), (3) variation of dendrite tip radius (R) with growth velocity (V), (4) dendrite tip stability parameter (${\sigma}^*$) and its dependence on the concentration. Concerning the correlation between the dendrite tip temperature and growth velocity the present result is well suited to Hunt-Lu equation. As the tilt angle increases, the average primary dendrite spacing tends to increase.

• Journal of Biosystems Engineering
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• 제14권3호
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• pp.196-206
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• 1989

와권(渦券) 노즐에 작용(作用)되는 힘은 분두(噴頭)의 도구(導溝) 및 와실(渦室)의 기능(機能)에 의하여 축방향력(軸方向力)과 반경방향력(半徑方向力)으로 분류(分類)되고, 이 두 개의 힘은 미립화(微粒化)의 과정(過程)에 각각(各各)의 특성(特性)을 주고 있다. 반경방향(半徑方向)의 힘은 분두(噴頭)에서 분사(噴射)되는 입자(粒子)에 전단력(剪斷力)으로서 작용(作用)하지만 이 힘의 크기는 물방울의 직경(直徑) $100{mu}m$을 기준(基準)하여 2.4m/s의 속도(速度) 이내(以內)의 범위(範圍)이었으며, 그 속도범위(速度範圍)는 다음 유도된 식(式)으로 산출(算出)할 수 있었다. $$V_{ot}=(\frac{8g{\sigma}}{d{\gamma}})^{1/2}$$ 축방향력(軸方向力)은 아래 유도된 식(式)과 같이 분사액류(噴射液流)의 굴절각에 매우 민감하게 영향을 미치었고, 그 크기는 반경방향력(半徑方向力)에 비교(比較)하여 큰 값을 나타내었다. $$V_{\ell}={\sigma}[\frac{1}{2}{\rho}_{a}sin2{\theta}_d-4({\mu}+{\eta})\frac{\ell}{r_o}]^{-1}$$.

• Bulletin of the Korean Chemical Society
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• 제4권2호
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• pp.79-83
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• 1983

The structure of thiamphenicol, one of the congeners of chloramphenicol which is a well-known antibiotic, has been determined by single crystal x-ray diffraction techniques. The crystal structure was determined using diffractometer data obtained by the $2{\theta}:{\omega}$ scan technique with $MoK{\alpha}$ radiation from a crystal having space group symmetry $P2_{1}2_{1}2_{1}$, and unit cell parameters a = 5.779, b = 15.292 and c = 17.322 ${\AA}$ . The structure was solved by direct methods and refined by least squares to an R = 0.070 for the 2116 reflections. The overall V-shaped conformation of thiamphenicol revealed in this study is consistent with those from the crystallographic studies and the proposed models from the theoretical and nmr studies of chloramphenicol. However there is no intramolecular hydrogen bond and the propanediol moiety is fully extended in the thiamphenicol molecule, while the crystal structures of chloramphenicol show the existence of the hydrogen bond between the two hydroxyl groups of the propanediol moiety forming an acyclic ring. All of the thiamphenicol molecules in the crystal are linked by a threedimensional hydrogen bonding network.

• Bulletin of the Korean Chemical Society
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• 제10권2호
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• pp.177-184
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• 1989

The structure of cholesteryl isobutyrate, $(CH_3)_2CHCOOC_{27}H_{45}$, was determined by single crystal X-ray diffraction methods. Cholesteryl isobutyrate crystallized monoclinic space group $P2_1$, with a = 15.115 (8)${\AA}$, b = 9.636 (5)${\AA}$, c = 20.224 (9)${\AA}$, ${\beta}$ = 93.15 (5)$^{\circ}$, z = 4, $D_c = 1.03 g/cm^3 $and Dm= 1.04 g/$cm^3$. The intensity data were measured for the 3417 reflections, within $sin{\theta}/{\lambda} = 0.59{\AA}^{-1}$, using an automatic four-circle diffractometer and graphite monochromated Mo-$K_{\alpha}$ radiation. The structure was solved by fragment search Patterson methods and direct methods and refined by full-matrix least-squares methods. The final R factor was 0.129 for 2984 observed reflections. The two symmetry-independent molecules (A) and (B) are almost fully extended. The molecules are in antiparallel array forming monolayers with thickness $d_{100}$ = 15.2${\AA}$, and molecular long axes are nearly parallel to the [$\bar{1}$01] directions. The two distinct molecules form separate stacks with almost the same orientations, but with differing degrees of steroid overlap. Thers is a close packing of cholesteryl groups within the monolayers. The packing type is similar to those of cholesteryl hexanoate and cholesteryl oleate.

• 한국전기전자재료학회논문지
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• 제28권5호
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• pp.306-313
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• 2015

In this study, the change of optical characteristics was studied according to the micro optical pattern provided by photo lithography followed by thermal reflow process. The shape and luminance variation with micro pattern was evaluated by SEM and spectrometers. Also, we analyzed the luminance characteristics using the 3D-optical simulation (Optis works) program. As a result, we found that the radius of curvature(R) in micro pattern is decreased up to 77%($150^{\circ}C$) compared to the radius of curvature at the condition $100^{\circ}C$, which is caused by efficient reflow of organic material without chemical changes. The highest enhancement of brightness with optimum micro pattern was obtained at the condition of $120^{\circ}C$ reflow process. The brightness gain with optical micro patterns is more than 15% at the condition of R=16.95 um, ${\Theta}=77.14^{\circ}$ compared to original optical source. The results of light simulation with various radius of curvature and side angle of pattern shows the similar result of experiment evaluation of light behavior on optical micro patterns. It is regarded that the more effect on light enhancement was contributed by side angle which is effective factor on light reflection, rather than the curvature of micro-patterns.

• 대한기계학회논문집
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• 제16권7호
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• pp.1373-1380
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• 1992

본 연구에서는 전보에서 실험역학적으로 도출한 .DELTA.A가 재료 및 하중크기에 의존하는 점에 착안하여, SNC631-A, SNC631-B, S45C, A12024-T3 및 A17075-T6 등 5종 류 재료를 응력비 R=0.1, 0.3, 0.5에서 피로크랙전파속도시험을 실시하고, 피로크랙팁 의 국소피로변형률장의 상태를 정량적으로 나타낼 수 있는 피로변형률확대계수 .DELTA.A(m, P)를 이용하여 크랙전파속도 da/dN을 통일적으로 평가하고, 그 결과의 유용성을 명백 히 하였다.

• International Journal of Ocean System Engineering
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• 제1권2호
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• pp.95-101
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• 2011

Perforated plates with cutouts (or holes) are widely used in structural members. These cutouts provide stress concentration in plates. Extensive studies have been carried out on stress concentration in perforated plates, which consider cutout shapes, boundary conditions, bluntness of cutouts, and more. This study presents stress concentration analyses of perforated plates with not only various cutouts and bluntness but also different cutout orientations. Especially, the effect of cutout orientation on stress concentration is emphasized since structural members have become more complicated recently. To obtain stress concentration patterns, a finite element program, ANSYS, is used. For the designated goal, three parameters are considered as follows: the shapes of polygonal cutouts (circle, triangle, and square), bluntness (a counter measure of radius ratio, r/R), and rotation of cutouts (${\theta}$). From the analyses, it is shown that, in general, as bluntness increases, the stress concentration increases, regardless of the shape and rotation. A more important finding is that the stress concentration increases as the cutouts become more oriented from the baseline, which is the positive horizontal axis (+x). This fact demonstrates that the orientation is also a relatively significant design factor to reduce stress concentration. In detail, in the case of the triangle cutout, orienting one side of the triangle cutout to be perpendicular to the applied tensile forces is preferable. Similarly, in the case of the square cutout, it is more advantageous to orient two sides of square cutout to be perpendicular to the applied tensile force. Therefore, at the design stage, determining the direction of a major tensile force is required. Then, by aligning those polygon cutouts properly, we can reduce stress concentration.