• Title/Summary/Keyword: Quenching rate

검색결과 242건 처리시간 0.031초

Edge Flame : Why Is It So Hot in Combustion?

  • 김종수
    • 한국연소학회지
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    • 제5권2호
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    • pp.19-27
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    • 2000
  • A turbulent combustion model, based on edge flame dynamics, is discussed in order to predict global extinction of turbulent flames. The model is applicable to the broken flamelet regime of turbulent combustion, in which global extinction of turbulent flame is achieved by gradual expansion of flame holes. The edge flame dynamics is the key mechanism to describe the flame hole expansion or contraction. For flames with Lewis numbers near unity, there is a $Damk{\ddot{o}}hler$ number, namely the crossover $Damk{\ddot{o}}hler$ number, at which edge flame changes its direction of propagation. The parametric region between the quasi-steady extinction condition and the edge-flame crossover condition is a metastable region, in that flames without edge can stay in their burning states while flames with edge have to retract to expand quenching holes. Using the above properties of edge flame, Hartley and Dold proposed a Lagrangian hole dynamics, which allows us to simulate transient variation of quenching holes. In their model, each stoichiometric surface is subjected to a random sequence of scalar dissipation rate compatible to the equilibrium turbulence. Then, each stoichiometric surface will evolve, according to the combustion map, dependent on the scalar dissipation rate and existence of flame edge, If all the burning surfaces are annihilated, the event can be declared as a global extinction. The consequence obtained from the above model also can be used as a subgrid model to determine local extinction occurring in a calculation grid.

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핫스탬핑 공정조건에 따른 기계적 특성 (The Effect of Hot Stamping Operation Condition on the Mechanical Properties)

  • 김훈동;문만빈;이승하;윤경원;유지홍
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.317-320
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    • 2008
  • The Hot Stamping process, which is the hot pressing of steel parts using cold dies. can utilize both case of shaping and high strength due to the hardening effect of rapid quenching during the pressing. We carried out experiments of quenching rate and tempering treatments at temperatures of $200^{\circ}C$ and $300^{\circ}C$ and different soaking times. Tn this study, the mechanical properties and microstructure of micro boron alloyed steels after heat treatments are compared.

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Stabilization of Bioluminescence of Immobilized Photobacterium phosphoreum and Monitoring of Environmental Pollutants

  • Britz, Margaret L.;Nina Simonov;Chun, Uck-Han
    • Journal of Microbiology and Biotechnology
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    • 제7권4호
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    • pp.242-249
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    • 1997
  • Stability of bioluminescence was investigated with Photobacterium phosphoreum immobilized on the strontium alginate in order to develope continuous real time monitoring of pollutants. The stability of bioluminescence emission was improved by prolonged aging time. The aging time of ${\geq}40$ min and the cell concentration of ${\leq}0.6\;of\;OD_660$ were selected for the immobilization of P. phosphoreum to give linearity between cell concentrations and bioluminescence intensity. In sensitivity tests using phenol, it was found that this compound quenched bioluminescence proportional to the concentration without lowering of cell growth. The lower value for maximum quenching ($q_s$) and higher dissociation constant ($K_s$) were observed with strontium-alginate immobilized cells compared to free cells. The response of bioluminescence to toxicants was evaluated with the immobilized luminescent bacteria. The sensitivity of the immobilized cells was found to be good in response to toxicants, 4-nitrophenol, salicylate and cadmium, when evaluated with a specific rate of bioluminescence quenching.

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음향방출을 이용한 극저온 환경하에서의 초전도 계자코일의 ?칭탐지에 관한 연구 (Application of AE Technique for On-line monitoring of Quencl in superconducting coil at Cryogenic Environment)

  • 이준현;이민래;권영길;류강식
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 1999년도 제1회 학술대회논문집(KIASC 1st conference 99)
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    • pp.34-38
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    • 1999
  • An acoustic emission(AE) technique has been used to monitor and diagnose quenching phenomenon in racetrack shaped superconducting magnets at cryogenic environment of 4.2K. The ultimate goal is to ensure the safety and reliability of large superconducting magnet systems by being able to identity and locate the sources of quench in superconducting magnets. The characteristics of AE parameters have been analyzed by correlating with quench number, winding tension of superconducting coil and charge rate by transport current. It was found in this study stat there was good correlation between quench current and AE parameters. The source location of quenching in superconducting magnet was also discussed on the correlation between magnet voltage and AE energy.

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A FULLY EMPIRICAL APPROACH TO GALAXY EVOLUTION

  • Renzini, Alvio
    • 천문학논총
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    • 제25권3호
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    • pp.65-69
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    • 2010
  • Observations of large samples of galaxies from low to high redshifts are composing a picture of remarkable simplicity: (1) The star formation rate (SFR) of starforming galaxies scales almost linearly with mass, strongly decline with cosmic time, and exhibits very small scatter around the average relation. (2) Due to the high observed SFRs the mass of galaxies at high redshifts must increase very rapidly, and yet the mass function of star forming galaxies evolves only very slightly with redshift. (3) At all redshifts the fraction of quenched (passively evolving) galaxies increases with galactic stellar mass and with local overdensity, with the remarkable property that the relative efficiency of "mass quenching" is independent of environment, and that of "environment quenching" is independent of mass. In a recent paper by the zCOSMOS collaboration, Peng et al. (2010) demonstrate that these three empirical facts suffice to account for the observed evolution of the galaxy mass function and naturally generate the "double-Schechter" mass function for quenched galaxies.

Spectrofluorometric Study of the Interaction of Coumarin Derivatives with Bovine Serum Albumin

  • Kamat, B.P.;Seetharamappa, J.;Kovala-Demertzi, D.
    • Journal of Photoscience
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    • 제11권2호
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    • pp.65-69
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    • 2004
  • The mechanism of interaction of four coumarin derivatives (CDS) with bovine serum albumin (BSA) was studied using spectrofluorometric technique. It was found that the coumarin ring common to all CDS makes major contribution to interaction. Binding affinities could be related to parachor values of CDS. Stem-Volmer plots indicated the presence of static component in the quenching mechanism. Results also showed that both tryptophan residues of protein are accessible to CDS. The high magnitude of rate constant of quenching indicated that the process of energy transfer occurs by intermolecular interaction forces and thus CDS binding site is in close proximity to tryptophan residues of BSA. Binding studies in the presence of the hydrophobic probe, 8-anilino-l-naphthalein-sulfonic acid showed that there is hydrophobic interaction between CDS and the probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of CDS to BSA involve hydrophobic bonds predominantly. The effects of various metal ions on the binding of CDS with BSA were also investigated.

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Fluorimetric Determination of Phosphate in Sea Water by Flow Injection Analysis

  • Motomizu, Shoji;Oshima, Mitsuko;Katsumura, Naoya
    • 분석과학
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    • 제8권4호
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    • pp.843-848
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    • 1995
  • A sensitive method for the determination of trace amounts of phosphate by fluorescence-quenching detection / FIA is proposed. The fluorescence of Rhodamine B(RB) was quenched with the formation of the ion associate of molybdophosphate with RB;${\lambda}_{ex}$ and ${\lambda}_{em}$ were 560nm and 580nm, respectively. A calibration graph was linear over the ranges from $10^{-8}$ to $3{\times}10^{-6}M$ of phosphate (~0.3~93ppb of phosphorus). The relative standard deviation was 1.2% with $8{\times}10^{-7}M$ phosphate solution and sampling rate was 15 samples / h. The proposed method was applied to the determination of phosphate in sea and river water samples.

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Spectroscopic Studies on the Interaction of N-alkyl Phenothiazines with Bovine Serum Albumin

  • Seetharamappa, J.;Shaikh, S.M.T;Kamat, B.P.
    • Journal of Photoscience
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    • 제12권1호
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    • pp.25-32
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    • 2005
  • Binding of N-Alkyl phenothiazines (NAP) to bovine serum albumin (BSA) was studied by spectroscopic methods.It was found that the phenothiazine ring common to all drugs makes major contribution to interaction. However, the nature of alkylamino group at position 10 influences the protein binding significantly. Stern-Volmer plots indicated the presence of static component in the quenching mechanism. The high magnitude of rate constant of quenching indicated that the process of energy transfer occurs by intermolecular interaction and thus the drug-binding site is in close proximity to tryptophan residues of BSA. Binding studies in presence of hydrophobic probe, 8-anilino-1-naphthalein-sulphonic acid showed that there is hydrophobic interaction between drug and the probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of NAP to BSA predominantly involve hydrophobic forces. The effects of some cations and anions common ions were investigated on NAP-BSA interactions. The CD spectrum of BSA in presence of drug showedthat binding of drug leads to change in the helicity of the protein.

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열플라즈마에 의한 CFC의 분해공정 (Decomposition Process of CFC by Thermal Plasma)

  • 차우병;최경수;박동화
    • 공업화학
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    • 제9권6호
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    • pp.829-834
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    • 1998
  • 환경문제와 관련하여 오존층 파괴의 주요 원인으로 알려진 CFC를 열플라즈마를 이용하여 완전하게 분해하였다. CFC113($C_2Cl_3F_3$)을 선정하여 열플라즈마 분해에서의 적절한 공정 조건을 검토하였다. 실험에 앞서, 상압에서 300 K~5000 K범위에서 CFC113, $H_2$, $O_2$간의 열역학적 화학평형조성을 고찰함으로써 CFC113의 분해 생성의 경향을 알 수 있었다. 실험은 상압, 상온에서 CFC113과 $H_2$, $O_2$혼합가스의 주입량, 그리고 냉각관 직경의 변화에 따른 분해생성물을 조사하였고 이를 기체크로마토그래피로 분석하였다. 그 결과, 각각 99.99%이상의 분해율을 보였다. CFC113/$H_2$=1/3에서 $O_2$비가 증가할수록 CO로의 전화율은 감소하였다. CFC113/$O_2$=1/1, 1/1.5, 1/2에서 $H_2$비가 3이상 증가될수록 CO로의 전화율이 증가하였다. 그 이유는 $H_2$첨가가 증가할수록 환원분위기에서 $H_2O$가 생성되고 $CO_2$생성량이 감소하기 때문이다. DC power가 증가하여도 CO로의 전화율 변화는 차이가 없었으며, 총유량이 증가할 경우 CO전화율이 약간 감소하는 경향을 보였다. 냉각관의 직경을 8 mm에서 4 mm로 작게 할 경우 빠른 냉각속도로 인하여 CO로의 전화율이 증가하였다.

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인지질 모델막에서의 지방산 이동에 관한 연구 방법 (Research Method of Fatty Acids Transfer between Phospholipid Model Membranes)

  • 임병순;김혜경;김을상
    • 한국식품영양과학회지
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    • 제26권4호
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    • pp.743-750
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    • 1997
  • 세포막에서의 지방산 이동은 매우 빠르게 일어나므로 방사성 원소를 사용해서는 여러가지 단점이 있고, 정확한 이동속도 측정에도 어려움이 많았다 최근에 개발된 FRET assay는 형광성 물질과 형광성 물질을 상쇄시키는 quencher를 사용한 실험방법 이다. 이는 공명 에너지 이동의 원리를 이용한 것으로 형광광도계, stopped-flow장치를 사용하여 소수성 물질 이동을 직접 컴퓨터 모니터로 측정하는 방법으로 기존방법의 단점을 보완하였다. Donor막에는 형광성 표지를 붙인 지방산이 들어 있고 acceptor막에는 형광을 흡수하는 물질이 들어 있어서 형광성 지방산이 donor에서 acceptor로 이동하면 형광도가 감소하며, 시간에 따른 형광도 감소를 측정하여 지방산 이동속도를 측정하는 방법이다. 형광성 표지를 이용하여 소수성 물질 이동에 사용되는 또 다른 방법은 self-Quenching assay이다. 형광 물질의 농도가 높아지면 서로 형광을 흡수하는 성질을 이용한 방법으로 주로 micelle에서의 물질 이동에 많이 쓰인다. Donor micelle에는 높은 농도의 형광성 지방산이 들어 있고 acceptor micelle에는 형광성 지방산이 들어 있지 않을 때 형광성 지방산이 donor에서 acceptor로 이동하면 형광도가 증가하게 되고 시간에 따른 형광도 증가를 측정하는 방법이다.

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