• 제목/요약/키워드: Quenching rate

검색결과 242건 처리시간 0.02초

Correlative Changes between Photosynthetic Activities and Chlorophyll Fluorescence in Wheat Chloroplasts Exposed to High Temperature

  • Young-Nam Hong
    • Journal of Plant Biology
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    • 제37권1호
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    • pp.37-42
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    • 1994
  • Correlative changes between photosynthetic O2 exchange rates and room temperature Chl fluorescence were investigated in wheat (Triticum aestivum L.) chloroplasts treated with high temperature for 5 min. With increasing treatment temperature, photosynthetic O2 evolution rate mediated by PSII was decreased, showing 50% inhibition at 38$^{\circ}C$ (I50). But PSI activity measured by O2 uptake rates was stimulated as a function of increasing temperature. Dark level fluorescence (Fo)-temperature (T) analysis showed that fluorescence rising temperature (Tr), critical temperature (Tc), and peak temperature (Tp) was 38, 43, and 52$^{\circ}C$, respectively. Quenching analysis of Chl fluorescence showed that both the oxidized fraction of plastoquinone (qQ) and degree of thylakoid membrane energization (qNP) increased up to 4$0^{\circ}C$ and then declined dramatically. These results suggest that Tr is correlated with temperature showing a 50% of inhibition of photosynthesis and under mild high temperature stress, qNP is worth regarding as indicator for heat-induced damage of photosynthesis.

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대향류 예혼합 난류 연소 유동에서의 Coherent Flamelet Model 적용 및 검증에 관한 연구 (A Study on Application and Validation of the Coherent Flamelet Model in Counterflow Turbulent Premixed Combustion)

  • 최창렬;허강열
    • 한국연소학회지
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    • 제1권2호
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    • pp.51-58
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    • 1996
  • The coherent flamelet model(CFM) is applied to symmetric counterflow turbulent premixed flames. The flame source term is set proportional to the turbulence intensity to reproduce the experimental correlation of Abdel-Gayed et al. for the turbulent burning velocity. Flame quenching by the turbulent rate of strain is modeled by an additional multiplication factor to the flame source term. A modified form of CFM is employed to consider coexistence of burned and unburned premixture with ambient air. The predicted flame position and turbulent flow field coincide well with the experimental data of Kostiuk et al., although there is some discrepancy in the radial rms velocity component and integral length scale near the symmetric plane.

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배기 Hydrocarbon의 생성과정에 과한 실험적 연구 (An experimental study on the mechanism of hydrocarbon emissions)

  • 심현성;박찬준;이대운
    • 오토저널
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    • 제13권3호
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    • pp.25-31
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    • 1991
  • The formation process of hydrocarbon emissions was investigated in SI engine. The time- resolved concentrations of hydrocarbon emissions were measured using a high gas sampling valve and a gas chromatography. The gas was sampled at exhaust port, or the position of spark plug, or the wall of combustion chamber. The experiments were conducted using the Alpha engine of Hyundai Motor Company. The fuel used was methanol or propane. It was found that the effect of the quenching layer of combustion chamber wall on hydrocarbon emissions was not significant. The increasing rate of hydrocarbon concentration at combustion chamber wall near crevice and oil layer after flame was reached was much higher than that at the position of spark plug. The hydrocarbon concentrations at exhaust port had two peak values just after opening exhaust valve and just before closing it.

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Transient Absorption Spectra of Phenothiazine Derivative in the Vesicle System Containing Ru$^{2+}$ Complex as a Sensitizer

  • Park, Yong-Tae;Kim, Young-Doo;Burkhart, Richard D.;Caldwell, Norris J.
    • Bulletin of the Korean Chemical Society
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    • 제9권2호
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    • pp.84-87
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    • 1988
  • The Photophysical and photochemical properties of Ruthenium bipyridine with two long hydrocarbon chains, $[Ru(bipy)_2(dhbipy)]^{2+}$ and transient phenothiazine derivative cation radical $(PTD^+)$ in the cationic vesicle were studied. Transient absorption spectra of cation radical of phenothiazine derivative in the vesicle system containing the $Ru^{2+}$ complex, $[Ru(bipy)_2(dhbipy)]^{2+}$, (1) as sensitizer and phenothiazine derivative as electron donor was observed by XeCl excimer laser photolysis system. Thus the excited ruthenium complex would be quenched by phenothiazine derivative(PTD) reductively in the vesicle system. The quenching rate constant($K_Q$) of $Ru^{2+}$ with two long hydrocarbon chains in the vesicle by PTD was $9.6{\times}10^8M^{-1}S^{-1}$. The absorption decay kinetics showed that lifetime of phenothiazine derivative cation radical is a value in the 4-8m sec range.

고탄소강 열연판재의 미세조직과 냉간압하율에 따른 구상화 속도 및 기계적 특성 (Effect of Microstructure and Cold Reduction Ratio on Spheroidization Rate and Mechanical Properties of High Carbon Steel)

  • 이규동;이수연;하태권;정효태
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.382-385
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    • 2008
  • In the present study, the effect of cold reduction ratio on the spheroidization rate of SK85 high carbon steel sheet was investigated. High carbon steel sheet fabricated by POSCO was soaked at $850^{\circ}C$ for 2 hr in a box furnace and then treated at $570^{\circ}C$ and $670^{\circ}C$ for 10 min in a salt bath furnace followed by water quenching to obtain a fine pearlite structure and coarse pearlite structure. Cold rolling was conducted on the sheets by reduction ratios of 20, 30, and 40 % and heat treatment for spheroidization was carried out at $720^{\circ}C$ for the various time intervals from 1 to 32 hrs. Area fraction of spheroidized cementite was measured with an image analyzer as a function of cold reduction ratios and duration times.

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연소용 공기중 $N_2$$CO_2$대체에 대한 연소특성 해석 (A Study on the Characteristics of Combustion for Substituting $CO_2\;for\;N_2$ in Combustion Air)

  • 김한석;안국영;김호근;이윤원;이창언
    • 한국연소학회지
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    • 제7권4호
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    • pp.29-35
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    • 2002
  • [$CO_2$] is a well-known greenhouse gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. The central method of low $CO_2$ emission is Oxygen/CxHy combustion. Theoretically Oxygen/CxHy combustion only produces $CO_2\;and\;H_2O$ and allows convenient recovery of $CO_2$. The combustion characteristics, flame stability, composition in the flame zone and temperature profile were studied experimentally for various compositions of oxidant by substituting $CO_2\;for\;N_2$ with the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was quenched and broadened, as the ratio of $CO_2\;to\;N_2$ was increased. The emission of NOx in flue gas decreased due to the decreased temperature of the reaction zone. As the conversion ratio of $CO_2\;to\;N_2$ was increased, the emission of CO and the higher temperature zone increased due to decrease of reaction rate by the a quenching effect.

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Prediction and Measurement of Residual Stresses in Injection Molded Parts

  • Kwon, Young-Il;Kang, Tae-Jin;Chung, Kwansoo;Youn, Jae Ryoun
    • Fibers and Polymers
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    • 제2권4호
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    • pp.203-211
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    • 2001
  • Residual stresses were predicted by a flow analysis in the mold cavity and residual stress distribution in the injection molded product was measured. Flow field was analyzed by the hybrid FEM/FDM method, using the Hele Shaw approximation. The Modified Cross model was used to determine the dependence of the viscosity on the temperature and the shear rate. The specific volume of the polymer melt which varies with the pressure and temperature fields was calculated by the Tait\`s state equation. Flow analysis results such as pressure, temperature, and the location of the liquid-solid interface were used as the input of the stress analysis. In order to calculate more accurate gap-wise temperature field, a coordinate transformation technique was used. The residual stress distribution in the gap-wise temperature field, a coordinate transformation technique was used. The residual stress distribution in the gap-wise direction was predicted in two cases, the free quenching, under the assumption that the shrinkage of the injection molded product occurs within the mold cavity and that the solid polymer is elastic. Effects of the initial flow rate, packing pressure, and mold temperature on the residual stress distribution was discussed. Experimental results were also obtained by the layer removal method for molded polypropylene.

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산소부화연소에서 Co2 첨가에 대한 연소 특성 (Characteristics for Effects of Co2 Addition to Oxygen-Enriched Combustion)

  • 김한석;김호근;안국영;김용모
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.9-15
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    • 2004
  • $CO_2$ is a well-known green house gas as well as the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. Because its adiabatic flame temperature is relatively too high, existing facilities must be changed or the flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were investigated experimentally for the various oxygen-enriched ratios(OER) by the addition of $CO_2$, under constant $O_2$ flow rate. Results showed that the reaction zone was quenched and broadened as the addition of $CO_2$ was increased. The emission of NOx in flue gas was decreased as decreasing temperature in reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone was increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0%, but the composition of CO was decreased by quenching effect at OER=50% and 100%.

면방전형 Xe 플라즈마 평판 램프의 방전 및 발광 특성 (Discharge and Luminous Characteristics of Coplanar Type Xe Plasma Flat Lamp)

  • 김혁환;이원종
    • 한국재료학회지
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    • 제21권10호
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    • pp.532-541
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    • 2011
  • The Xe plasma flat lamp, considered to be a new eco-friendly LCD backlight, requires a further improvement of its luminance and luminous efficiency. To improve the performance of this type of lamp, it is necessary to understand the effects of the discharge variables on the luminous characteristics of the lamp. In this study, the luminous characteristics of a coplanartype Xe plasma flat lamp with a teeth-type electrode pattern were analyzed while varying the gas composition, gas pressure and input voltage. The effects of the phosphor layer on the discharge and the luminous characteristics of the lamp were also studied. The luminous efficiency of the coplanar-type Xe plasma flat lamp improved as the Xe input ratio and gas pressure increased. Higher luminous efficiency was also obtained when helium (He) was used as a buffer gas and when a phosphor layer was fabricated on the electrode region. In contrast, the luminous efficiency was reduced with increasing the input voltage. It was found that the infrared emissions from the lamp were affected by the Xe excitation rate in the plasma, the Xe gas density, the collisional quenching of excited Xe species by gas molecules, and the recombination rate between the Xe ions and electrons.

Radioactivity analysis for EPS waste using organic solvents

  • Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • 제53권11호
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    • pp.3717-3722
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    • 2021
  • In this study, the recovery rates of the dissolution method for radioactivity analysis of expandable polystyrene (EPS) with a liquid scintillation counter (LSC) using tetrahydrofuran (THF), toluene, and acetone as solvents were estimated. The detection efficiency calibration curve for each solvent was derived. Two methods-the volumetric ratio method and the quenching agent method-were used to prepare quench source sets, and calibration curves were derived by linking the data from the two quench source sets. The R2 value of the calibration curve for THF was found to be 0.984. The relationship between the mass of dissolved EPS and the quench level was estimated: the quench level increased as the mass of dissolved EPS increased. Premix and postmix dissolution methods were tested. The recovery rates using THF with the premix method were 84.9 ± 0.9% and 96.5 ± 1.5% for 3H and 14C, respectively. Furthermore, the stability of the recovery rate over time when using THF was evaluated. The dissolution method with the premixed solution exhibited a more stable recovery rate over time. The dissolution methods were found to be applicable for analysis using LSC, and THF was found to be the most suitable solvent for the proposed method.