A Study on the Characteristics of Combustion for Substituting $CO_2\;for\;N_2$ in Combustion Air

연소용 공기중 $N_2$$CO_2$대체에 대한 연소특성 해석

  • 김한석 (한국기계연구원 환경기계연구부) ;
  • 안국영 (한국기계연구원 환경기계연구부) ;
  • 김호근 (한양대학교 대학원) ;
  • 이윤원 (인하대학교 대학원) ;
  • 이창언 (인하대학교 기계공학부)
  • Published : 2002.12.31

Abstract

[$CO_2$] is a well-known greenhouse gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. The central method of low $CO_2$ emission is Oxygen/CxHy combustion. Theoretically Oxygen/CxHy combustion only produces $CO_2\;and\;H_2O$ and allows convenient recovery of $CO_2$. The combustion characteristics, flame stability, composition in the flame zone and temperature profile were studied experimentally for various compositions of oxidant by substituting $CO_2\;for\;N_2$ with the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was quenched and broadened, as the ratio of $CO_2\;to\;N_2$ was increased. The emission of NOx in flue gas decreased due to the decreased temperature of the reaction zone. As the conversion ratio of $CO_2\;to\;N_2$ was increased, the emission of CO and the higher temperature zone increased due to decrease of reaction rate by the a quenching effect.

Keywords