• Journal of the Korean Society for Heat Treatment
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• v.13 no.5
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• pp.330-336
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• 2000

This study deals with the characteristic of refrigerant for heat-treatment deformation control of SM45C steel. The control of heat-treatment deformation must need the progress of production parts for a landing gear. Most of the deformation is occurred on unequal cooling. The unequal cooling is occurred by a property of quenching refrigeration. When a heated metal is deposited in the refrigeration, the cooling speed is so slow in early period of cooling because of occurring a steam-curtain. After more cooling, the steam-curtain is destroyed. In this progress, the cooling speed is very fast. The object of this study is to control the deformation of heat-treatment for landing gear by improving the conditions of quenching. The cooling curves and cooling rates of water, oil and polymer solution are obtained and illustrated. From the characteristics of the quenching refrigerant, the effects of heat-treatments on thermal deformation and fatigue strength are also investigated.

• Transactions of Materials Processing
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• v.31 no.1
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• pp.17-22
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• 2022

Hot stamping is widely used to manufacture structural parts to satisfy requirements of eco-friendly vehicles. Recently, hot forming technology using uncoated steel sheet is being studied to reduce cost and solve patent problems. In particular, research is focused on process technology capable of suppressing the generation of an oxide layer. To evaluate the oxide layer in the hot stamping process, Gleeble testing machine can be used to evaluate the oxide layer by controlling the temperature history and the atmosphere condition. At this time, since cooling by gas injection is impossible to protect the oxide layer on the surface of a specimen, research on a method for securing a quenching speed through natural cooling is required. This paper proposes a specimen shape design method to secure a target quenching speed through natural cooling when evaluating the oxide layer of an un-coated boron steel sheet by Gleeble test. For the evaluation of the oxide layer of the un-coated steel sheet through the Gleeble test, dog-bone and rectangular type specimens were used. In consideration of the hot stamping process, the temperature control conditions for the Gleeble test were set and the quenching speed according to the specimen shape design was measured. Finally, the quenching speed sensitivity according to shape parameter was analyzed through regression analysis. A quenching speed prediction equation was then constructed according to the shape of the specimen. The constructed quenching speed prediction equation can be used as a specimen design guideline to secure a target quenching speed when evaluating the oxide layer of an un-coated boron steel sheet by the Gleeble test.

• Korean Journal of Materials Research
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• v.22 no.10
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• pp.513-518
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• 2012

Recently, automobile parts have been required to have high strength and toughness to allow for weight lightening or improved stability. But, traditional micro-alloyed steel cannot be applied in automobile parts. In this study, we considered the influence of quenching temperature and cooling rate for specimens fabricated by vacuum induction furnace. Directly quenched micro-alloyed steel for hot forging can be controlled according to its micro structure and the heat-treatment process. Low carbon steel, as well as alloying elements for improvement of strength and toughness, was used to obtain optimized conditions. After hot forging at $1,200^{\circ}C$, the ideal mechanical properties (tensile strength ${\geq}$ 1,000 MPa, Charpy impact value ${\geq}\;100\;J/cm^2$) can be achieved by using optimized conditions (quenching temperature : 925 to $1,050^{\circ}C$, cooling rate : ${\geq}\;5^{\circ}C/sec$). The difference of impact value according to cooling rate can be influenced by the microstructure. A fine lath martensite micro structure is formed at a cooling rate of over $5^{\circ}C/sec$. On the other hand, the second phase of the M-A constituent microstructure is the cause of crack initiation under the cooling rate of $5^{\circ}C/sec$.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.1
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• pp.77-87
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• 2003

The residual stress and birefringence in injection-molded plastic parts can be divided into the flow-induced residual stress and birefringence produced in flowing stage, the thermally-induced residual stress and birefringence produced in cooling stage. However, the physics involved in the generation of the thermally-induced residual stress and birefringence still remains to be understood. Because polymer experiences viscoelastic history near the glass-transition temperature it is hard to model the entire process. Volume relaxation phenomenon was included to predict the final thermally-induced residual stress and birefringence in quenched plastic parts more accurately. The present study focused on comparing the predicted values far thermally-induced residual stress and birefringence with and without volume relaxation behavior (or free volume theory) under free and constrained quenching conditions. As a result, tile residual stress remained as a tensile stress at the center and as a compressible stress near the surface for the free quenching cases. In contract the residual stress remained as a compressible stress at the center and as a tensile stress near the surface fur the constrained quenching cases. The residual birefringence remained as minus values at the center and as plus values near the surface for the free quenching cases. Interestingly the residual birefringence showed minus values in entire zone for the constrained quenching cases. In the prediction of birefringence only the case including free volume theory showed the correct result for the distribution of birefringence in thickness direction.

• Journal of Soil and Groundwater Environment
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• v.12 no.6
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• pp.53-59
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• 2007

Optimal quenching curves have been studied for the accurate analysis of $^{14}C$ in groundwater polluted by reducing efficiency of volatile organic compounds (VOCs) in liquid scintillation counter (LSC). The quenching parameters (SQP(E)) were measured for ten VOCs such as benzene, toluene, ethylbenzene, o-(m-,p-)xylene, trichloroethylene (TCE), tetrachloroethylene(PCE), carbon tetrachloride and chloroform. The quenching curves were plotted using $^{14}C$ standard solution and chloroform as a quenching agent. Optimal plotting conditions were determined for standard solution, LSC measuring time and the concentration of chloroform. The quenching effects of chlorinated organic compounds such as TCE, PCE, carbon tetrachloride and chloroform were greater than those of BTEX (benzene, toluene, ethylbenzene and xylene). Optimum measuring time was 100 minutes far 7,000 dpm/mL standard solution. A few mL of chloroform should be added for good quenching curves. These quenching curves have good correlation coefficients (> 0.99) and the curves could be applied to accurate analysis of $^{14}C$ in groundwater and tap water.

• Bulletin of the Korean Chemical Society
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• v.6 no.3
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• pp.164-168
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• 1985

The fluorescence emission of polystyrene-acrylic acid copolymers containing $Eu^{3+}$ in tetrahydrofuran solution was investigated by spectrofluorimetry. The excimer emission increased linearly with the polymer concentration up to approximately $5{\times}10^{-3}$M. Benzene and toluene collisionally quenched the excimer fluorescence and thier rate constants of quenching were determined. Quenching efficiencies decreased in the order: naphthalene > toluene > benzene. Analyses of Rayleigh scattering and europium emission showed no measurable structural changes observed under the experimental conditions.

• Transactions of Materials Processing
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• v.26 no.2
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• pp.101-107
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• 2017

Aluminum alloys are widely used in automotive industry because of their high strength-to-density ratio and excellent corrosion resistance. However, conventional cold stamping of aluminum alloys leads to low formability and excessive spring-back. To overcome these problems, Hot Forming Quenching (HFQ) is applied to manufacture automotive part using aluminum alloy. The purpose of this study is to investigate effect of forming temperature on spring-back in HFQ of T6 heat treated AA6061 sheet. In this study, hat shape forming test was adopted to evaluate spring-back characteristics according to various forming temperatures. In additions, the test was also performed with warm forming conditions in comparison with dimensional accuracy of HFQed part. The experimental results showed that dimensional accuracy of HFQed part was superior to warm formed part and amount of spring-back was decreased as forming temperature rise.

• Design & Manufacturing
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• v.8 no.2
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• pp.23-29
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• 2014

Salt bath heat treatment is usually used but recently vacuum heat treatment is increased for the heat treatment of hot work die steels. The differences in two heat treatment processes were compared by testing the mechanical properties of heat treated products. With two different features of processes, mechanical properties such as hardness, tensile strength and impact strength of products show very different results. In this study salt bath heat treated products showed higher tensile strength and impact strength than vacuum heat treated products but hardness was not much different. These lower mechanical properties of vacuum heat treated products are due to differences in heating and quenching process.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2727-2731
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• 2011

A new method for the determination of josamycin has been developed based on quenching of the fluorescence of 3-mercaptopropionic acid-capped CdTe quantum dots (MPA-CdTe QDs) by josamycin in ethanol. Reaction time, interfering substances on the fluorescence quenching, and mechanism of the interaction of CdTe QDs with josamycin were investigated. Under optimum conditions, the relative fluorescence intensity was linearly proportional to the concentration of josamycin between 12.0 and 120.0 ${\mu}g\;mL^{-1}$ with a correlation coefficient of 0.9956 and a detection limit of 2.5 ${\mu}g\;mL^{-1}$. The proposed method was successfully applied to commercial tablets, and the results were satisfactory, i.e. consistent with those of high-performance liquid chromatography (HPLC).

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.519-523
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• 2011

We studied the detection of the Hg(II) concentration in an aqueous solution using rhodamine dyes on citrate-reduced Au nanoparticles (NPs). The quenching effect from Au NPs was found to decrease as the Hg(II) concentration increased under our experimental conditions. As the fluorescence signals intensified, the surface-enhanced Raman scattering (SERS) intensities reduced on the contrary due to less rhodamine dyes on Au NPs as the Hg(II) concentration increased. The rhodamine 6G (Rh6G) and rhodamine 123 (Rh123) dyes were examined via fluorescence and SERS measurements depending on Hg(II) concentrations. Fast and easy fluorescence detection of an Hg (II) concentration as low as a few ppm could be achieved by naked eye using citrate-reduced Au NPs.