• 제목/요약/키워드: Quenching Phenomenon

검색결과 43건 처리시간 0.027초

Exchange Coupling in Massively Produced Nd2Fe14B+Fe3B Nanocomposite Powders

  • Yang, Choong Jin;Park, Eon Byung;Han, Jong Soo;Kim, Eung Chan
    • Journal of Magnetics
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    • 제9권2호
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    • pp.27-33
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    • 2004
  • Magnetic properties of $Nd_4Fe_{77.5}B_{18.5}$ compound in term of exchange coupling between $Nd_2Fe_{14}B$ and $Fe_3B$ magnetic nano crystals in melt spun powders were characterized by varying the quenching speed in mass production line. The exchange coupled phenomenon was characterized as functions of nano crystal size and volume fraction of each magnetic phase which was possible by employing Henkel plot (${\delta}M$) and refined Mossbauer spectroscopy. The optimized magnetic properties obtained from the present volume production line were: $B_r= 11.73 kG,{_i}H_c/ = 3.082 kOe$, and $(BH)_{max} = 12.28 MGOe.$ The volume fraction of each magnetic phase for those conditions giving the grain size of 10 nm were ${\alpha}-Fe; 4.2%, Fe_3B; 60.1 %$, and $Nd_2Fe_{14}B; 35.7%$. The superior magnetic properties in the $Nd_2Fe_{14}Fe_3B$ based nanocomposites were confirmed to be dependant on the volume fraction of $Fe_3B$.

직분식 가솔린 엔진에서 피스톤 캐비티 반경에 따른 연료 거동 분석 (A Study on the Fuel Behaivor with Cavity Diameter in a Gasoline Direct Injection Engine)

  • 김태안;강정중;김덕줄
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.472-477
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    • 2003
  • This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.

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수열합성에 의해 제조된 YVO4:Eu3+ 형광체의 발광특성 (Luminescent Properties of YVO4:Eu3+ Phosphor by Using Hydrothermal Synthesis)

  • 문영민;최성호;정하균;임상호
    • 한국재료학회지
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    • 제18권10호
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    • pp.511-514
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    • 2008
  • We have synthesized $Eu^{3+}$-doped $YVO_4$ phosphors by using a hydrothermal method and investigated their luminescent properties. Aqueous solutions of $Y_2O_3,\;V_2O_5,\;Eu_2O_3$, and nitric acid with various pH values were used as the precursors. The crystallinity, surface condition, and emission characteristics were examined using XRD, FT-IR, and photo-excited spectrometer. $Eu^{3+}$ incorporation followed by the efficient red emission strongly depends on the acidity of solution media. The emission intensity becomes stronger as the pH values increase to 7 and then gradually decreases. This phenomenon might be related to the hydroxyl quenching effect, which is induced by surface bound OH-groups.

Effect of SiO2/B2O3 ratio on Li ion conductivity of a Li2O-B2O3-SiO2 glass electrolyte

  • Kim, Young Han;Yoon, Mi Young;Lee, Eun Jung;Hwang, Hae Jin
    • Journal of Ceramic Processing Research
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    • 제13권spc1호
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    • pp.37-41
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    • 2012
  • A lithium ion conducting borosilicate glass was fabricated by a conventional melt quenching technique from a mixture of Li2CO3, B2O3 and SiO2 powders. The Li ion conductivity of the lithium borosilicate glasses was evaluated in terms of the SiO2/B2O3 ratio. In the Li2O-B2O3-SiO2 ternary glass, the glass forming region decreases with an increasing Li2O content. At the same Li2O, the crystallization tendency of the glass samples increases with the SiO2/B2O3 ratio, resulting in a reduced glass forming region in the Li2O-B2O3-SiO2 ternary glass. The electrical conductivity moderately depends on the SiO2/B2O3 ratio in the Li2O-B2O3-SiO2 ternary glass. The conductivity of the glasses slightly increases with the SiO2/B2O3 ratio. The observed phenomenon can be explained by the modification of the glass structure as a function of the SiO2 content.

Effects of Shading on the Growth and Chlorophyll Fluorescence under Agrivoltaic System Conditions

  • Hoejeong Jeong;Myeong-Gue Choi;Woon-Ha Hwang
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2022년도 추계학술대회
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    • pp.120-120
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    • 2022
  • Agrivoltaic System (AVS) was introduced with the concept that it could generate electricity by using the extra light remain after crops use for photosynthesis in farm, which can earn additional income. However, crop yield was declined under the AVS condition due to the decrease in light energy. In the past, many researchers have been studied about crop states under shading conditions. However, the phenomenon of partial shading such as under the AVS is not well studied. In this study, to figure out the response of crop under the different light conditions, the electron transport rate (ETR) and non-photochemical quenching (NPQ) of rice was investigated using the chlorophyll fluorescence measurement. Also, physiological changes of crops under the shading conditions were investigated. The growth experiment under partial shading under AVS and overall shading which made of 35% shade cloth was conducted to understand the eco-physiological responses of rice to light in terms of the photosynthesis. Under the shading conditions, SPAD value and chlorophyll contents were higher, but the leaf thickness was lower than control. The overall shading condition show lower ETR than others during the growing season. In contrast, NPQ was higher than other treatments. This means the available light energy cannot contribute to photosynthesis under the shading condition.

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n-Alkanols가 소의 대뇌피질 Synaptosomal Plasma Membrane Vesicles로부터 추출 제제한 총지질 인공세포막 이중층간에 형성된 비대칭적 유동성에 미치는 비대칭적 영향 (Transbilayer Effects of n-Alkanols on the Fluidity of Model Membranes of Total Lipids Extracted from Synaptosomal Plasma Membrane Vesicles)

  • 윤일;강정숙
    • 대한약리학회지
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    • 제28권2호
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    • pp.191-199
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    • 1992
  • 한국산 2년생 소의 대뇌피질로부터 synaptosomal plasma membrane vesicles(SPMV)를 분리한 후 이 SPMV로부터 추출한 총지질로서 인공세포막(SPMVTL)을 제제하였다. SPMVTL의 outer monolayer에 trinitrophenyl group을 공유결합시킴으로써 SPMVTL이중층에 분포된 형광 probe 1,6-diphenyl-1,3,5-hexatriene(DPH)중 outer monolayer에 분포된 DPH형광만을 소광케 하였다. 형광분석기를 통하여 SPMVTL의 inner monolayer에 비하여 outer monolayer의 유동성이 크다는 것을 확인하였다. n-Alkanols는 SPMVTL지질 이중층(inner+outer monolayers)의 회전확산운동을 증가시키되 탄소수 두개가 증가될 때마다 그 효력이 약10배 가량 증가된다는 것을 알았다. 그러나 1-decanol의 경우에는 1-nonanol에 비하여 그 효력이 낮아지는 소위 cut-off현상이 나타났다. 뿐만 아니라 n-alkanols는 SPMVTL의 inner monolayer에 비하여 outer monolayer의 회전확산운동을 주로 증가시켰다. 하지만 n-alkanols의 탄소수가 증가됨에 따라 outer monolayer에 대한 선택적인 작용이 감소된다는 것도 확인되었다.

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극저온 환경에서의 피로균열 선단의 온도상승에 관한 연구 (A Study on Temperature Rising near Fatigue Crack Tip at Cryogenic Temperature)

  • 이준현
    • 대한기계학회논문집
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    • 제19권1호
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    • pp.79-86
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    • 1995
  • The structural materials for cryogenic technology have been recently developed to support the many modern large-scale application from superconducting magnets for nuclear fusion reactor, magnetic levitation railway to LNG tankers. However it is pointed out that quenching phenomenon is one of the serious problems for the integrity of these applications, which is mainly attributed to the rapid temperature rising in the material due to some extrinsic factors of structures. From the viewpoint of fracture mechanics, it is therefore very important to clarify the mechanism of temperature rising of structural material due to cyclic loading at cryogenic temperature. From this purpose, fatigue test was carried out for high manganese steel at liquid helium temperature(4.2K) using triangular stress waveform to identify both the mechanism of temperature rising near crack tip and the effect of loading stress waveform on temperature rising near crack tip and the effect of loading stress waveforms on temperature rising. As the results, two types of temperature rising, that is, regular and burst types were observed. And a periodical temperature rising corresponding to the stress waveforms was also found. The peaks of the temperature rising were recorded near both the maximum and the minimum values of the applied stress. The sudden temperature rises, which indicated the higher values than those of periodical temperature rises under the repetition of stress, were observed at the final region of crack growth. It was shown that the peak values of the temperature rising increased with stress intensity factor range.

차세대 원전 대형 압력용기용 고강도 SA508 Gr.4N Ni-Cr-Mo계 저합금강 개발 (High Strength SA508 Gr.4N Ni-Cr-Mo Low Alloy Steels for Larger Pressure Vessels of the Advanced Nuclear Power Plant)

  • 김민철;박상규;이기형;이봉상
    • 한국압력기기공학회 논문집
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    • 제10권1호
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    • pp.100-106
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    • 2014
  • There is a growing need to introduce advanced pressure vessel steels with higher strength and toughness for the optimizatiooCn of the design and construction of longer life and larger capacity nuclear power plants. SA508 Gr.4N Ni-Cr-Mo low alloy steels have superior strength and fracture toughness, compared to SA508 Gr.3 Mn-Mo-Ni low alloy steel. Therefore, the application of SA508 Gr.4N low alloy steel could be considered to satisfy the strength and toughness required in advanced nuclear power plants. The purpose of this study is to characterize the microstructure and mechanical properties of SA508 Gr.4N low alloy steels. 1 ton ingot of SA508 Gr.4N model alloy was fabricated by vacuum induction melting followed by forging, quenching, and tempering. The predominant microstructure of the SA508 Gr.4N model alloy is tempered martensite having small packet and fine Cr-rich carbides. The yield strength at room temperature was 540MPa, and it was decreased with an increase of test temperature while DSA phenomenon occurred at around $288^{\circ}C$. Overall transition property of SA508 Gr.4N model alloy was much better than SA508 Gr.3 low alloy steel. The index temperature, $T_{41J}$, of SA508 Gr.4N model alloy was $-132^{\circ}C$ in Charpy impact tests, and reference nil-ductility transition temperature, $RT_{NDT}$ of $-105^{\circ}C$ was obtained from drop weight tests. From the fracture toughness tests performed in accordance with the ASTM standard E1921 Master curve method, the reference temperature, $T_0$ was $-147^{\circ}C$, which was improved more than $60^{\circ}C$ compared to SA508 Gr.3 low alloy steels.

니켈기 초내열합금 분말의 고용화 열처리 후 냉각속도에 따른 크리프특성 분석 (Analyses of Creep Properties of Ni-base Superalloy Powders as Cooling Rate after Solid Solution Heat Treatment)

  • 전찬;이영선;배병범;김홍규;홍성석;김동훈;윤존도;윤은유
    • 한국분말재료학회지
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    • 제23권3호
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    • pp.247-253
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    • 2016
  • In this study, solid solution heat treatment of consolidated nickel-based superalloy powders is carried out by hot isotactic pressing. The effects of the cooling rate of salt quenching, and air cooling on the microstructures and the mechanical properties of the specimens are analyzed. The specimen that is air cooled shows the formation of serrated grain boundaries due to their obstruction by the carbide particles. Moreover, the specimen that is salt quenched shows higher strength than the one that is air cooled due to the presence of fine and close-packed tertiary gamma prime phase. The tensile elongation at high temperatures improves due to the presence of grain boundary serrations in the specimen that is air cooled. On the contrary, the specimen that is salt quenched and consists of unserrated grain boundaries shows better creep properties than the air cooled specimen with the serrated grain boundaries, due to the negative creep phenomenon.

SnO2-(1-x)P2O5-xB2O3 유리의 열적, 구조적 특성 (Structure and Thermal Properties of SnO2-(1-x)P2O5-xB2O3 Glasses)

  • 안용태;최병현;지미정;장우석;배현;황해진
    • 한국세라믹학회지
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    • 제47권2호
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    • pp.117-121
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    • 2010
  • $SnO_2-(1-x)P_2O_5-xB_2O_3$ glass system were prepared by melt-quenching technique in the compositional series containing 50, 55 and 60 mol% of $SnO_2$. Local structure of the glasses was investigated by Raman and FT-IR measurements. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5~25 mol% of $B_2O_3$. According as content of $B_2O_3$ increases, theraml expansion coefficient of glass decreased but transition temperature and softening temperature increased. Because these phenomenon changed local structure of glass. According as content of $B_2O_3$ increases, quantity of bridging oxygen increased. Also, according as content of $SnO_2$ increases, confirmed that quantity of non-bridging oxygen increases.