• Title/Summary/Keyword: Quarternary

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Late Quaternary Stratigraphy and the Heavy Minerals from Deep Cored Sediments along the Coastal Deposits, Songji Lagoon, Eastern Coast, Korea (강원도 동해안(송지호) 해안퇴적층의 제4기 후기 층서와 중광물)

  • 박용안;박영후
    • The Korean Journal of Quaternary Research
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    • v.15 no.2
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    • pp.111-117
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    • 2001
  • The deep cored sediments of the beach spit deposit in the inlet of the Songji lagoon(lake) have been studied in terms of the late Quarternary stratigraphy and relationship of the Holocene sea-level curve. Furthermore, the total content of heavy mineral sands from the established stratigraphic units(Unit I, II and III) varies due to the changes of depositional environments from continental to marine condition.

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Isolation and Quantitative Determination of Berberine and Coptisine from Tubers of Corydalis ternata (들현호색으로부터 Berberine과 Coptisine의 분리 및 함량분석)

  • Lee, Hyang-Yi;Kim, Chong-Won
    • Korean Journal of Pharmacognosy
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    • v.30 no.3
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    • pp.332-334
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    • 1999
  • Corydalis Tuber has been used in traditional medicine for an analgesic, antispasmodic and gastric ulcers. For the quality control on this drug, isolation and quantitative determination of berberine and coptisine from Corydalis ternata Nakai (Papaveraceae) has been conducted by using HPLC method. Berberine and coptisine in quarternary alkaloidal fraction from the crude drug were separated on silicagel column using a $CHCl_3:MeOH\;(85:15)$ and $CHCl_3:MeOH:H_2O\;(70:30:4)$ as an eluent, and the average contents were about 0.93 and 0.36%.

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Influence of Suspending Agents on the Bactericidal Action of Cationic Surfactants and Amphoteric Surfactants -Influence on the Bactericidal Action of Codecyl Diaminoethyl Glycine and Benzalkonium Chloride- (분산안정제가 cationic surfactant와 amphoteric surfactant의 살균력에 미치는 영향 Dedecyl Diaminoethyl Glycine 및 Benzalkonium Chloride의 살균력에 미치는 영향)

  • 이진환
    • YAKHAK HOEJI
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    • v.11 no.3_4
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    • pp.17-21
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    • 1967
  • At present, quarternary ammonium salts(cationic surfactant) and Tego compounds (amphoteric surfactant) are used as germicidal agent. In this paper, it was investigated whether their germicidal activities are influenced or not by some suspending agents which are added to them 0.005% benzalkonium chloride aq. solution and 0.05% dodecyl diaminoethyl glycine aq. solution sterilized respectively against Staphylococcus aureus and Escherichia coli within a minute. The solutions aded acacia, carboxymethyl cellulose, sodium alginate solutions to make to 0.005% to above surfactants solution decreased the germicidal activity, not being sterilized bacteria for more than 2 hours however, the solutions decreased the germicidal activity by addition of suspending agents such as acacia, carboxymethyl cellose, sodium alginate and bacteria were survival for more than 2 hrs, 0.05% of benzalkonium chloride and 0.1% dodecyl diaminoethyl glycine respectively would be sterilized within 10 minutes, when added to 5% suspending agents. This result show that bactericidal action of dodecyl diaminoethyl glycine is affected by suspending agents less than that of benzalkonium chloride.

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An Analysis of the Phase Diagram fo the Crystal Growth of InGaAsP/GaAs in the Visible Region (가시광 InGaAsP/GaAs 결정성장을 위한 상평형도 해석)

  • Hong, Tchang-Hee;Cho, Ho-Sung;Oh, Jong-Hwan;Yea, Beyong-Deok;Hwang, Sang-Ku;Bea, Jung-Chul
    • Journal of the Korean Institute of Navigation
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    • v.15 no.3
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    • pp.99-106
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    • 1991
  • In order to grow InGaAsP epitaxial layer on GaAs by LPE, an accurate phase diagram for In-Ga-As-P quarternary compounds is required. But the short wavelength InGaAsP/GaAs phase diagram for full wavelength range was not yet reported. In this study, therefore, a theoretical calculation has been carried out by using thermodynamic's equation for InGaAsP/GaAs in order to get the relation between the mole fraction of the sloute and solid phase compounds. And the calculation being compared with the dta of Kawanishi et. al, the result has been shown that his phase diagram obtained by the calculation can apply to growing InGaAsP/GaAs by LPE.

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Gravity and Magnetic Surverys for Volcanic Rocks in Yeoncheon Area, kyonggi-do (경기도 인천지역 분포하는 화산암류에 대한 중력 및 자력 탐사 연구)

  • 박혁진
    • Economic and Environmental Geology
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    • v.32 no.6
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    • pp.645-651
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    • 1999
  • The gravity and magnetic measurements have been obtained from 34 stations with 50m intervals along the survey line positioned between Jangtanri and sindapri for studying subsurface geology and structures of the volcanic rocks in Yeoncheon area. The Bouguer gravity and magnetic anomaly values were evaluated from the reduction of the field observation, and then interpreted by Nettleton's method and maximum-pepth rules, are approximately 160m based on magnetic data and 135m based on gravity data. High Bouguer gravity anomaly zone between 0m in Jangtanri and 900m along the survery line, is caused by thick and high density, older dasalt which is positioned beneath jijangbong tuff breccia, and this result corresponds to the interpretation result based on magnetic anomly. Lower gravity and magnetic anomaly zones ariund 900m are caused by between 1300m and 1550m are caused by high density of Quarternary basalt exposed in the surface, and lower gravity and magnetic anomalies at 200m and 1250m are caused by faults.

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Studies on the Constituents of Berberis amurensis Ruprecht (매발톱나무의 성분에 관한 연구)

  • Lee, Hyang-Yi;Kim, Chong-Won
    • Korean Journal of Pharmacognosy
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    • v.28 no.4
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    • pp.257-263
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    • 1997
  • Berberis amurensis Ruprecht(Berberidaceae) is a medicinal plant indigenous to the middle and northern part of Korean peninsula. The woody parts of this plant have been used for the ocular, peptic and intestinal disorders. The stems of this plants were extracted with MeOH and the MeOH extract was partitioned between organic phases and water layer, successively to fractionated quarternary alkaloids. The acetone-soluble part of guarternary alkaloidal fraction had antibacterial activities and it contained four protoberberine alkaloids such as palmatine(I), Berberine(II), Jatrorrhizine(III) and coptisine(IV), and one aporphine alkaloid, magnoflorine(V). Although the isolations of the compounds I, II, IIII, IV and V from different sources were reported, this is the first report that Berberis amurensis contained the compounds. When the contents of compound I(palmatine) and II(berberine) were quantified and compared with those of other plant parts, cortex contained higher palmatine and berberine than any other part of the plant.

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The Development of Fertical type LPE System for Single Crystal Growth (단결정 성장을 위한 수직형 LPE 장치의 제작)

  • 오종환
    • Proceedings of the Optical Society of Korea Conference
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    • 1989.02a
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    • pp.201-205
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    • 1989
  • In this study, the vertical type LPE system has been developed by fully hand-made. The temperature fluctuation and minimum cooling rate of this LPE system are within $\pm$0.05$^{\circ}C$ and 0.15$^{\circ}C$/min, respectively. It is considered that these properties are enough to grow III-V semiconductor compounds single crystals by liquid phase epitaxy method. Futhermore in this study. 1.3${\mu}{\textrm}{m}$ GaInAsP/InP single crystal growing has been carried out by this system. It has been obtained that the growing rate was about 0.72${\mu}{\textrm}{m}$/min for InP binary layer and 0.36${\mu}{\textrm}{m}$/min for GaInAsP quarternary layer under 0.6$^{\circ}C$/min cooling rate condition.

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Synthesis and Reaction of Biheterocyclic Thiazolo[3,2-a]pyrimidinium-betaines

  • Yoo, Kyung-Ho;Park ,Sang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.272-276
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    • 1985
  • Various new kinds of biheterocyclic betaines were prepared by the reaction of 3-substituted-6,7-dihydro-5H-thiazolo[3,2-a]pyrimidine with electrophiles such as isothioyanates, isocyanates in aprotic solvents, respectively. The biheterocyclic betaines containing methyl group at 3-position of thiazole ring were obtained particularly in good yields at room temperature. These betaines were also reacted with alkyl halide to give quarternary ammonium salts. It was found that these betaines are dissociated in polar organic solvents depending on temperature. And new biheterocyclic compounds via ring transformation were prepared by the reaction of 8-phenyl (thiocarbamoyl)-3-phenyl-6,7-dihydro-5H-thiazolo[3 ,2-a]pyrimidinium-betaine with ${\alpha}$-halo kester ${\alpha}-halo$ ester and ${\gamma}-halo$ keto ester.

Reactivity of the Biheterocyclic Betaine with the para-Substituted Phenacyl Bromides for the Ring Transformation Reaction

  • Yoo, Kyung-Ho;Kim, Dong-Jin;Kim, You-Seung;Park, Sang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.164-166
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    • 1988
  • 7-Dithiocarboxy-3-phenyl-5,6-dihydro imidazo[2,1-b]thiazolium-betaine (2) was prepared by treatment of 3-phenyl-5,6-dihydro imidazo[2,1-b]thiazole (1) with carbon disulfide in acetone at room temperature. On the reaction of 2 with para-substituted phenacyl bromides (4) having the electron withdrawing property by virtue of (+) resonance (R) < (-) inductive (I) or (-) resonance (R), (-) inductive (I) effect, ring transformation product p-substituted-2-[2-[7-(p-substituted benzoyl)-5-thioxo-2,3-dihydro-1H-imidazo[1,2-c] thiazol-1-yl]-2-phenylvinylthio] acetophenone (6) was obtained; however, when R is electron donating grops with (+) resonance (R) > (-) inductive (I) effect the quarternary ammonium salt 7-(p-substituted phenyl) carbonyl methyl-3-phenyl-5,6-dihydro imidazo [2,1-b] thiazolium bromide (8) is formed. The reaction of 2 with unsubstituted-phenacyl bromide (R = H), on the other hand, gives 6a and 8a to the similar ratio, respectively.

Studies of Refractive Index and Hardness from the structures in Quarternary Li2O-B2O3-Al2O3-SiO2 Glasses (4성분 Li2O-B2O3-Al2O3-SiO2 유리들의 구조로부터 굴절률과 경도 연구)

  • Moon, Seong-Jun
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.27-31
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    • 2002
  • Quarternary $Li_2O-B_2O_3-Al_2O_3-SiO_2$ glasses were fabricated by the function of $R({\equiv}Li_2Omole%/B_2O_3mole%)$ and $K({\equiv}(Al_2O_3mole%+SiO_2mole%/B_2O_3mole%)$. The structures of these glasses were investigated through refractive index and Vicker's hardness. The refractive index increased as the increase of the polarizability in the glass network. In the region of low $Li_2O$ content, the refractive index increased due to the increase of the polarizability in the glass network but, in the region of high $Li_2O$ content, the rate of increase of the refractive index decreased due to the increase of the molar volume caused by the formation of $BO_3{^-}$ units with relatively high molar volume. And, the refractive index decreased as the increase of $Al_2O_3+SiO_2$ content with the molar volume in the glass network. The increase and decrease of vicker's hardness values for those glasses depended on the fraction of tetrahedral $BO_4$ units and it of triangle $BO_3{^-}$ units with non-bridging oxygen, respectively.

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