• Title/Summary/Keyword: QCM

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Sensing and Degradation Properties in the QCM Gas Sensor Coated with the PVC and GC Blended Liquid (PVC 및 GC물질의 혼합액을 코팅한 QCM가스센서의 센싱 및 열화특성)

  • 장경욱;김명호;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.483-486
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    • 2000
  • In the recognition of the gases using the quartz crystal rnicrobalance (QCM) coated with the film materials, it is important to obtain the recognition ability of gases, and the stability of film coated above the QCM. Especially, the thickness of film coated above the QCM is decreased according with the using circumstance and time of QCM gas sensor. Therefore, the sensing chararcteristics of film is changed with these. In this paper, we coated the lipid GC materials varing with the blended amount of PVC(Po1y Vinyl Chloride) and solution (Tetra Hydrofan:THF) above QCM to obtain the stability of lipid PC film. QCM gas sensors coated with film materials were measured the frequency change in the chamber of stationary gas sensing system injected 1-hexane, ethyl acetate, ethanol and benzene of 20.4 respectively. Also, we measured the degradation characteristics of QCM gas sensor to show the properties of stability.

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Sensing and Degradation Characteristics in the QCM Gas Sensor Coated with the PVC and PC (PVC 및 PC 혼합액을 코팅한 QCM 가스센서의 센싱 및 열화 특성)

  • Jang, Kyung-Uk;Kim, Myung-Ho;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.176-179
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    • 2000
  • In the recognition of the gases using the quartz crystal microbalance (QCM) coated with the film materials, it is important to obtain the recognition ability of gases, and the stability of film coated above the QCM. Especially, the thickness of film coated above the QCM is decreased according with the using circumstance and time of QCM gas sensor. Therefore, the sensing chararcteristics of film is changed with these. In this paper, we coated the lipid PC (Phosphatidyl Choline) materials varing with the blended amount of PVC(Poly Vinyl Chloride) and solution (Tetra Hydrofan:THF) above QCM to obtain the stability of lipid PC film. QCM gas sensors coated with film materials were measured the frequency change in the chamber of stationary gas sensing system injected 1-hexane, ethyl acetate, ethanol and benzene of $20{\mu}{\ell}$, respectively. We obtained the principal component analysis (PCA) from the frequency change due to the absorption of gas. Also, we measured the degradation characteristics of QCM gas sensor to show the properties of stability.

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Degradation Properties in the QCM Gas Sensors Coated with the PEG Materials (PEG 물질을 도포한 QCM 가스센서의 열화특성)

  • Jang, Kyung-Uk;Kim, Myung-Ho;Lee, Won-Jae;Kim, Sang-Keol;Jung, Dong-Hoe;Lee, Joon-Ung;Lee, Ho-Sik;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.218-222
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    • 2002
  • In the recognition of the gases using the quartz crystal microbalance (QCM) coated with the PEG film materials, it is important to obtain the recognition ability of gases, and the stability of PEG film coated above the QCM. Especially, the thickness of PEG film coated above the QCM is decreased according with the using circumstance and time of QCM gas sensor. Therefore, the sensing characteristics of PEG film is changed with these. In this paper, we coated the PEG materials varing with the blended amount of PVC(Poly Vinyl Chloride) and chloroform above QCM to obtain the sensitive and the stability of PEG film. We measured the degradation characteristics of QCM gas sensor in the ethyle acetate 50[%] concentration to show the properties of stability.

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Study on the control methods of compositional ratios in co-evaporation system for SmBCO coated conductor (동시 증발 증착법을 이용한 SmBCO 초전도층 증착에서 조성비 제어 방법에 관한 연구)

  • Kim, H.S.;Ha, H.S.;Oh, S.S.;Ko, R.K.;Song, K.J.;Ha, D.W.;Kim, T.H.;Youm, D.J.;Lee, N.J.;Moon, S.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.294-294
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    • 2008
  • 동시 증발 증착법 화합물의 구성원자를 독립적으로 증발시켜서 기판에 증착하는 방법이다. 각 물질은 온도에 따른 증기압을 가지는데 각 물질의 온도를 조절하여 증착률을 조절한다. 보트에서 떠난 원자가 기판에 도달할 확률은 챔버의 진공도, 보토와 기판과의 거리 등에 의하여 영향을 받는다. 진공도가 나쁠수록, 보트와 기판과의 거리가 멀수록 기판에 도달할 확률이 떨어진다. 동시증발 증착법을 이용한 SmBCO 초전도층 증착에서 각 물질의 기판에 도달하는 원자비를 조절하기 위하여 QCM(증착률 측정장치), QCM 가이드를 사용하였다. QCM sensor 입구에 튜브형태의 QCM 가이드를 설치하고 QCM 가이드가 특정한 물질의 증발보트를 향하도록 배치하였다. 따라서 각 보트에서 떠난 원자들은 특정한 QCM sensor에 도달하게 되고 결국 3원소(Sm, Ba, Cu)의 증착률의 비를 조절함으로써 조성비를 조절할 수 있게 된다. QCM 증착률의 비와 실제 조성비는 여러 가지 변수에 의하여 영향을 받는 다. 대표적인 변수는 챔버의 진공도, QCM 가이드의 직경 및 길이, QCM 센서와 보트와의 거리 등이 있다. 진공도가 높을수록 특정 보트에서 떠난 원자들이 QCM 가이드 입구에 도달할 확률이 낮아지고, QCM 가이드의 직경이 좁을수록 가이드 내벽에 흡착될 확률이 높아진다. 또한 QCM센서와 보트와의 거리가 멀수록 챔버내 잔류가스의 원자들과 충돌확률이 높아지므로 도달확률이 줄어들게 된다. 동시 증발 증확법에서 조성비의 재현성을 높이기 위해서는 매회 증착실험에서 진공도가 일정해야 하며, QCM 가이드와 보트와의 거리를 되도록 최소화 하고, QCM 직경을 크게 하는 것이 유리하다.

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The Theory and Application or Piezoelectric Quartz Crystal Microbalance[PZ QCM] for Biosensor (압전 수정 결정 미량 천평[PZ QCM] 바이오센서의 원리와 응용)

  • 김의락
    • KSBB Journal
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    • v.18 no.2
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    • pp.79-89
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    • 2003
  • This article contains an overview of acoustic wave devices, the theory and application of piezoelectric quartz crystal microbalances(PZ QCM), clinical analysis, gas phase detection, DNA biosensors, drug analysis, food microbial analysis and environmental analysis.

Quartz Crystal Microbalance Modified by a Novel Vapor Diffused Molecular Assembly Technique and Measurement of Chiral Mandelic Acid (기상확산 자기조립화법에 QCM수식과 Madelic Acid 키랄물질 측정)

  • Kim, JongMin;Kim, SeungJin;Woo, SunYoung;Jang, SukHee;Kim, Woo-Sik;Chang, SangMok
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.574-582
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    • 2010
  • In this study, the possibility of a quartz crystal micro-balance(QCM) modification of crystallization of L-Penicillamine and D-Penicillamine with a Vapor Diffused Molecular Assembly Technique and its application to the R-(-)-Mandelic acid and S-(+)- Mandelic acid measurement was investigated. The 3-dimensional structures of L-Penicillamine and D-Penicillamine on the surface of QCM were verified to be different from each other through QCM and AFM analyses. The D-Penicillamine modified QCM had specific recognition to the R-(-)-Mandelic acid, but L-Penicillamine modified QCM had no specificity to the R-(-)-Mandelic acid and S-(+)- Mandelic acid. From these results, it was known that the QCM could be modified with various selective meterials via VDMA, and the chiral isomer such as a Mandelic acid isomer could be detected by using a modified QCM.

Fabrication of TiO2/polyelectrolyte thin film for a methyl mercaptan gas sensor (메칠멜캅탄 가스센서용 TiO2/전해질폴리머 박막 제조)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lee, Mi-Jai;Kim, Sei-Ki;Lim, Tae-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.5
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    • pp.221-226
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    • 2010
  • Quartz crystal microbalance (QCM) gas sensor to detect methyl mercaptan ($CH_3SH$) gas was fabricated by depositing $TiO_2$ nanoparticles and polyelectrolyte on the electrode of QCM. The $TiO_2$/poly(sodium 4-styrenesulfonate) (PSS) thin film fabricated by a layer-by-layer self-assembly (LBL-SA) method showed a high surface area and increased the sensitivity of gas sensor. When the QCM sensors coated with triethanolamine (TEA) or ($TiO_2$/PSS) were exposed to methyl mercaptan gas (1.0 ppm), the frequency shifts of QCM with TEA casting film and $TiO_2$/PSS thin film were ca. 9 Hz and ca. 24 Hz, respectively. As the bilayer number of ($TiO_2$/PSS) increased, the frequency shift of QCM sensor with ($TiO_2$/PSS) thin film was gradually increased. In addition, the frequency shift of QCM sensor was gradually increased as the concentration of methyl mercaptan gas increased from 0.5 ppm to 2.0 ppm. In this study, the surface morphology and sensor property of QCM sensor coated with ($TiO_2$/PSS) thin film were measured.

Adsorption of Aromatic Compounds on a QCM System Coated with Polymer Films (고분자 필름이 코팅된 QCM 시스템에 의한 방향족 화합물의 흡착)

  • Hwang, Min-Jin;Shim, Wang-Geun;Moon, Hee
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.233-239
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    • 2013
  • A quartz crystal microbalance (QCM) system coated with poly (isobutylene), polystyrene, and poly (methyl methacrylate) has been prepared to measure the adsorption amounts of benzene, toluene, and p-xylene at very low pressures. The resonant frequency shift of the QCM system is proportional to the increase in pressure in all experiments. The Henry's constants for all adsorbates on the polymer films are obtained from experimental data and compared with the minimum adsorption potential energies between adsorbates and the polymer films. In general, there is an explicit correlation between adsorption amount and the minimum adsorption potential energy.

Sensing and Degradation Properties in the Quartz Crystal Microbalance Coated with the PVC and the Lipid Blended Materials (지질과 PVC의 혼합액을 감응막으로 도포한 수정진동자 가스센서의 센싱 및 열화특성)

  • Jang, Kyung-Uk;Kim, Myung-Ho;Choi, Myung-Kyu
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.44-47
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    • 2000
  • In the recognition of the gases using the quartz crystal microbalance (QCM) coated with the film materials, it is important to obtain the recognition ability of gases, and the stability of film coated above the QCM. Especially, the thickness of film coated above the QCM is decreased according with the using circumstance and time of QCM gas sensor. Therefore, the sensing characteristics of film is changed with these. In this paper, we coated the lipid PC (Phosphatidyl Choline) materials varing with the blended amount of PVC(Poly Vinyl Chloride) and solution (Tetra Hydrofan:THF) above QCM to obtain the sensitive and the stability of lipid PC film. QCM gas sensors coated with film materials were measured the frequency change in the chamber of stationary gas sensing system injected 1-hexane, ethyl acetate, ethanol and benzene of $20{\mu}{\ell}$, respectively. We also measured the degradation characteristics of QCM gas sensor to show the properties of stability.

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Replaceable battery electric car's battery location coordinates image processing techniques for obtaining verification (배터리 교체형 전기자동차의 배터리 위치좌표 획득을 위한 영상처리기술 검증)

  • Kim, Eung-Pil;Jung, Won-Jae;Kim, Jeoung-Youn;Park, Jun-Seok;Kim, Tae-Hee
    • Journal of The Institute of Information and Telecommunication Facilities Engineering
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    • v.11 no.2
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    • pp.52-57
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    • 2012
  • In this paper describe configuration about QCM system for image processing device. It presents that QCM's image processing board video from the camera recognized by the PLC's battery removable exact location coordinates to the robot image processing technology to deliver. In addition, QCM video image processing technology for improved data reliability is described. In this paper define the landmarks of battery for obtaining the location coordinates and verify battery the location coordinates acquisition process from field tests of the QCM/QTPE-BUS Battery Exchange System.

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