• Korean journal of food and cookery science
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• v.10 no.2
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• pp.121-125
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• 1994

The antioxidant activity of gingerol according to temperature on soybean oil were examined by measuring peroxide value(POV). The induction period(IP) of soybean oil was 45; 276.0, 65; 17.0 and 105$^{\circ}C$ : 4.7 hours respectively by-measuring POV. The relative antioxidant effectiveness(RAE) of ginge-rol group were 45; 191, 65; 200, 65: 150, 85: 132 and 105$^{\circ}C$;106%. 'The activation energies(Ea) and temperature coefficients(Q10) for Arrhenius equations at 45∼105$^{\circ}C$, was estimated in order to find out the influence of temperature on the oxidation of soybean oil contai-ning various antioxidants. The soybean oil was more unstable at 45∼65$^{\circ}C$ than at 65∼105$^{\circ}C$ in the Ea and Q10. The soybean oils containing gingerol were more stable than the control group at 45∼105$^{\circ}C$, however, BHT group was unstable compared to gingerol group at 85∼105$^{\circ}C$.

• Korean Journal of Food Science and Technology
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• v.26 no.3
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• pp.331-335
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• 1994

The shelf-life of instant noodle stored at $35{\sim}65^{\circ}C$ under dark condition was estimated from the change of hexanal content, which was linearly increased as the storage time increased. The rate constants of hexanal production at various storage temperatures followed Arrhenius relationship. The activation energy and $Q_{10}$ calculated were 12.7 kcal/mole and 1.92, respectively. The rancid flavor was organoleptically detected after 6 days at $65^{\circ}C$ and 13 days $50^{\circ}C$, at which the content of hexanal was 3.5 ppm. The shelf-life of instant noddle at $21^{\circ}C$ based on $Q_{10}$ value of hexanal production was about 110 days. The changes of acid value and peroxide value of instant noodle during storage followed similar pattern to those of hexanal. The activation energy and $Q_{10}$ for both acid value and peroxide value were 16.0 kcal/mole and 2.55, respectively. The hexanal content showed a high positive correlation with acid value as well as peroxide value at all storage temperatures.

• Journal of Chest Surgery
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• v.31 no.1
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• pp.7-12
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• 1998

The study in detection of perioperative myocardial infarction by serial ECGs and the analysis of risk factors involved was carried out from January 1994 to July 1996 on 87 consecutive patients undergoing coronary artery bypass grafting. There were significant differences in the mean CK-MB peaks and frequencies of flipping in LDH1/LDH2 among the 3 groups(group I: new Q-wave, group II: S-T change, group III: no ECG change). The ECG was considered positive for postoperative myocardial infarction if the new Q-waves appeared in the postoperative period or if S-T segment changes persisted for more than 48 hours. The hospital mortality rate was 3.3% and the perioperative infarction rate was 17.2%. The following risk factors of the perioperative MI were found: endarterectomy, decreased ejection fraction($\leq$40%) and prolonged aortic cross clamping time. Left main disease, triple vessel disease, 3 or more graft, unstable angina and hypertension did not correlate with myocardial infarction. This study suggests that serial ECGs could be used as means of detecting the perioperative myocardial infarction after coronary artery bypass grafting.

• Bulletin of the Society of Naval Architects of Korea
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• v.11 no.2
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• pp.15-22
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• 1974

As for the added mass moment of inertia of ships in torsional vibration, it seems that the works by T. Kumai[1,2] are the only systematic one available currently. The work[1] is for the calculation of the two dimensional correction factors with finitely-long elliptic cylinders as the mathematic model. In this work the authors recalculated the above factors, $J_{\tau}$, with the same mathematic model and the same problem formulation, and presented the numerical results in Fig. 1. The reason why the reinvestigation was done was that in Kumai's work he obtained the solutions of the Mathieu equations, which was derived from the problem formulation for the velocity potential, under the assumption that the dummy constant q involved in the equations was always far less than unity, whereas in fact it takes values within the region of $0<q{\leq}{\infty}$ in sequence. As a result the authors found two remarkable differences in general features of $J_{\tau}$(refer to Fg.3); one that the authors' numerical results are considerably higher than the results given in [2], and the other that for a given number of node those have properties of decreasing monotonically with increase of the beam-draft ratio while these rapidly decrease from a maximum value of near at B/T=2.00 with B/T becoming greater or less than ratio. It seems that the latter trend was resulted from the fact that the assumption of $q{\ll}1$ employed in [2] was more closely satisfied in the vicinity of B/T=2.00.

• Journal of the Korean Geotechnical Society
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• v.25 no.8
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• pp.77-93
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• 2009

The load distribution and deformation of rock socketed drilled shafts subjected to axial loads were evaluated by a load transfer approach. The emphasis was laid on quantifying the end bearing load transfer characteristics of rock socketed drilled shafts based on 3D Finite Difference (FD) analysis performed under varying rock strength and rock mass conditions. From the results of FD analysis, it was found that the ultimate unit toe resistance ($q_{max}$) was influenced by both rock strength and rock mass conditions, while the initial tangent of end bearing load transfer curve ($G_{ini}$) was only dependent on rock strength. End bearing load transfer function of drilled shafts socketed in rock was proposed based on the FD analysis and the field loading tests which were performed on weathered rock in South Korea. Through the comparison with the results of the field loading tests, it is found that the load transfer curve by the present study is in good agreement with the general trend observed by field loading tests, and thus represents a significant improvement in the prediction of load transfer behavior of drilled shaft.

• Journal of the Korean Geotechnical Society
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• v.24 no.11
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• pp.133-141
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• 2008

In this study, a new method for estimating the undrained shear strength $s_u$ of saturated clays using piezocone penetration test (CPTu) result is proposed. This is to develop more effective CPTu-based $s_u$ estimation method at lower cost with less uncertainty. For this purpose, a marine clay deposit is selected and tested through extensive experimental testing program including both in-situ and fundamental laboratory tests. The proposed method is based on a correlation between the undrained shear strength $s_u$ and the cone resistance $q_t$, without introduction of the total overburden stress into the $s_u-q_t$ correlation. As a result, no additional testing procedure for collecting undisturbed soils samples is required, which can reduce overall testing cost. To verify the proposed method, 4 test sites, which consist of a variety of soil conditions, are selected and used for comparison between measured and predicted undrained shear strength. From comparison, it is seen that predicted values of $s_u$ using the proposed method match well those from measured results.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.34-34
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• 2021

본 연구에서는 격자기반 분포형 수문모델링을 통해 하천갈수량을 추정하고자 한다. 분포형 수문모형은 단방향흐름 알고리즘에 의한 토양 물수지식을 기반으로 개발되었으며 운동파(kinematic wave) 이론을 적용하여 지표 및 지표하 유출을 모의한다. 또한, 격자별로 수문학적 물수지요소인 차단량, 증발산량, 침투 및 침루량, 지하수충전량 등을 계산하며, 댐·보 방류량을 해당 지점 격자의 물수지에 적용할 수 있도록 개발하였다. 본 모형은 2개의 다목적댐과 3개의 다기능보가 위치한 금강유역(9,645.5 km²)에 적용하였으며, 유역 면적과 하천 유속을 고려하여 1 km × 1 km 격자를 구성하고 10분 간격으로 2013년부터 2020년까지 수문모의를 진행하였다. 모형의 입력자료로 유역 인근의 12개 기상관측소로부터 시단위 기상자료를 구축하였으며, 모형의 검보정은 일단위 관측유량(Q), 플럭스 타워 증발산량, 실측 토양수분 및 지하수위 자료를 구축하여 활용하였다. 댐 및 보 지점에 대해 Q와 1/Q로 검보정을 수행한 결과, 평균 결정계수(R²)는 댐 지점에서 0.53~0.65, 보 지점에서 0.46~0.69의 값을 나타냈으며, Nash-Shtcliffe efficiency(NSE)는 댐 지점에서 0.46~0.55, 보 지점에서 0.31~0.65의 값을 나타냈다. 공간 보정을 위해 증발산량, 토양수분, 지하수위에 대한 검보정을 수행할 예정이며, 유황곡선을 활용하여 하천차수, 토양속성 및 토지이용에 따른 하천갈수량을 분석할 예정이다.

• Analytical Science and Technology
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• v.6 no.1
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• pp.29-37
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• 1993

Some new podands containing phenyl(B), benzyl(Bz), pyridine(Py), quinoline(Q) and naphthalene(Np) as end-groups, and oxygen(O) and sulfur(S) in ether chains as donor atoms have been synthesized. The univalent cation binding characteristics of these podands have been studied by NMR titration and solvent extraction. By NMR titration we have found that the most of podands form 1:1 complexes with $Ag^+$ ion. Especially, the substituted sulfur atoms in ether chains show the effects to enhance the stabilities. We also carried out the extractions of univalent cation picrates including alkaline metal, $Ag^+$, $Tl^+$ and $NH_4{^-}$ ions from aqueous to chloroform layer by using these podands. We found that the extractabilities of $Ag^+$ ion with the quinoline-containing podands such as, $Q_2O_4$, $Q_2O_5$ and $BQO_5$ were 86.8, 86.6 and 48.0% respectively, but the naphthalene-containing podands such as, $Np_2O_4$ and $Np_2O_5$ extracted quite small amount. Otherwise, in cases of $Bz_2O_3S_2$(89.4%), $B_2O_2S_2$(96.8%), $B_2O_3S_2$(58.9%), $Py_2O_2S_2$(58.8%), $Py_2O_3S_2$(42.1%), and $B_2O_4S$(15.0%), interestingly, $Bz_2O_3S_2$ which have sulfur atoms and benzyl groups showed the highest extraction selectivity for $Ag^+$ ion. This result seems due to not only the strong interaction of $Ag^+$ ion with sulfur donors according to the HSAB theory, but also the effective ${\pi}-{\pi}$ stacking interaction between two aromatic end-groups which is enhanced by the flexible methylene spacing group in benzyl groups instead of phenyl groups. The extraction coefficients gave the similar tendency as the extractabilities and the stabilities. From these results, it could be concluded that the predominant factor affected to extraction coefficients is the stabilities, which are strongly influenced by the structures of podands.

• Journal of the Korean Chemical Society
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• v.66 no.2
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• pp.78-85
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• 2022

Natural white clay was treated with 6 M of H₂SO₄ and heated at 80℃ for 6 h under mechanical stirring and the resulting acid active clay was used as an adsorbent for the removal of Cs⁺ in water. The physicochemical changes of natural white clay and acid active clay were observed by X-ray Fluorescence Spectrometry (XRF), BET Surface Area Analyser and Energy Dispersive X-line Spectrometer (EDX). While activating natural white clay with acid, the part of Al₂O₃, CaO, MgO, SO₃ and Fe₂O₃ was dissolved firstly from the crystal lattice, which bring about the increase in the specific surface area and the pore volume as well as active sites. The specific surface area and the pore volume of acid active clay were roughly twice as high compared with natural white clay. The adsorption of Cs⁺ on acid active clay was increased rapidly within 1 min and reached equilibrium at 60 min. At 25 mg L^- of Cs⁺ concentration, 96.88% of adsorption capacity was accomplished by acid active clay. The adsorption data of Cs⁺ were fitted to the adsorption isotherm and kinetic models. It was found that Langmuir isotherm was described well to the adsorption behavior of Cs⁺ on acid active clay rather than Freundlich isotherm. For adsorption Cs⁺ on acid active clay, the Langmuir isotherm coefficients, Q, was found to be 10.52 mg g^-1. In acid active clay/water system, the pseudo-second-order kinetic model was more suitable for adsorption of Cs⁺ than the pseudo-first-order kinetic model owing to the higher correlation coefficient R² and the more proximity value of the experimental value q_e,exp and the calculated value q_e,cal. The overall results of study showed that acid active clay could be used as an efficient adsorbent for the removal of Cs⁺ from water.

• Journal of the Korean Chemical Society
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• v.65 no.3
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• pp.197-202
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• 2021

In this study, activated clay treated with H₂SO₄ (20% by weight) and heat at 90 ℃ for 8 h for acid white soil was used as an adsorbent for the removal of PO₄^3--P in water. Prior to the adsorption experiment, the characteristics of activated clay was examined by X-ray Fluorescence Spectrometry (XRF) and BET surface area analyser. The adsorption of PO₄^3--P on activated clay was steeply increased within 0.25 h and reached equilibrium at 4 h. At 5 mg/L of low PO₄^3--P concentration, roughly 98% of adsorption efficiency was accomplished by activated clay. The adsorption data of PO₄^3--P were introduced to the adsorption isotherm and kinetic models. It was seen that both Freundlich and Langmuir isotherms were applied well to describe the adsorption behavior of PO₄^3--P on activated clay. For adsorption PO₄^3--P on activated clay, the Freundlich and Langmuir isotherm coefficients, K_F and Q, were found to be 8.3 and 20.0 mg/g, respectively. The pseudo-second-order kinetics model was more suitable for adsorption of PO₄^3--P in water/activated clay system owing to the higher correlation coefficient R² and the more proximity value of the experimental value q_e,exp and the calculated value q_e,cal than the pseudo-first-order kinetics model. The results of study indicate that activated clay could be used as an efficient adsorbent for the removal of PO₄³-P from water.