• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
• /
• pp.243.1-243.1
• /
• 2016

Recently, many groups have attempted to fabricate 3-dimensional (3D) structures of GaN such as pyramids, rods, stripes and annulars. Since quantum structures on non-polar and semi-polar planes of 3D structures have less influence of internal electric filed, multi quantum wells (MQWs) formed on those planes have high quantum efficiency. Especially, pyramidal and annular structures consist of various crystal planes with different emission wavelength, providing a possibillity of phosphor-free white light emtting diodes (WLEDs).[1] However, it still has problem to obtain high color rendering index (CRI) number because of narrow-band emission and poor indium composition caused by the formation of few number of facets during metal-organic chemical vapor deposition growth.[2] If we can fabricate 3D structure having more various facets, we can make broad-band emittied WLEDs and improve CRI number. In this study, we suggest a simple method to fabricate 3D structures having various facet and containing high indium composition by means of a combination of metal-organic chemical vapor deposition and wet chemical etching techniques.

• 한국산학기술학회논문지
• /
• 제20권3호
• /
• pp.638-644
• /
• 2019

본 연구에서는 전산유체역학 해석을 이용하여 알루미늄 피라미드 트러스 심재 샌드위치의 열유동 특성을 분석하였다. 규칙적 다공질 금속인 피라미드 트러스 코어를 샌드위치 구조물에 채용할 경우 공기 매질이 자유롭게 유입, 유출될 수 있는 개방형 코어인 점을 고려하여 하중을 지지할 수 있는 구조성능과 함께 방열체로서 다기능성을 구현할 수 있는 구조가 된다. 따라서, 유입되는 공기의 속도변화, 설계변수인 트러스각에 따른 압력강하와 열전달 메카니즘을 확인하기 위해 ANSYS/Fluent를 이용하여 수치해석을 실시하였다. 해석모델에 사용된 샌드위치 패널은 알루미늄으로 이루어져 있으며, 샌드위치 패널의 위 면재와 아래 면재 사이에는 15개의 피라미드 트러스 유닛셀이 반복되고 있다. 폭 방향으로는 무한히 넓은 유닛셀을 모사하기 위해 대칭조건을 지정하였으며, 입구에는 균일한 속도분포를 경계조건으로 입력하였다. 해석결과 입구부와 첫 유닛셀까지의 구간에서 입구영향이 관찰되었으며, 입구영향을 배제하고 마찰계수와 누셀수를 분석하였다. 공기의 속도가 증가할수록 마찰계수는 감소하였으며, 누셀수는 증가하는 경향을 보인다. 한편, V=1m/s에서 5m/s에서의 마찰계수와 누셀수 변화가 확연하였으며, 이는 층류에서 난류로 유동패턴이 변하기 때문에 거시적으로 열전도보다 대류열전달의 비중이 커졌기 때문이다. 또한, 설계변수인 트러스각에 대해서는 의미가 있을 정도의 마찰계수와 누셀수의 변화는 관찰되지 않았다. 따라서, 트러스각이 강도, 강성 등 구조성능에 민감한 점을 감안하면 다기능성을 염두에 둔 알루미늄 피라미드트러스 심재 설계 시 설계변수의 변화는 구조성능에 더 민감할 것으로 판단된다.

• Animal cells and systems
• /
• 제2권1호
• /
• pp.71-80
• /
• 1998

Glutamate dehydrogenase (GDH) is one of the main enzymes involved in the formation and metabolism of the neurotransmitter glutamate. In the present study, we investigated the distribution of the GDH-immunoreactive cells in the rat brain using monoclonal antibodies against bovine brain GDH isoprotein. GDH-immunoreactive cell were distributed in the basal ganglia, thalamus and the nuclei belong to substantia innominata, and its connecting area, subthalamic nucleus, zona incerta, and substantia niqra. We could see GDH-immunoreactive cells in the hippocampus, septal nuclei associated with the limbic system, the anterior thalamic nuclei connecting between the hypothalamus and limbic system, and its associated structures, amygdaloid nuclear complex, the dorsal raphe and median raphe nuclei and the reticular formation of the midbrain. The GDH-immunoreactive cells were shown in the pyramidal neurons of the cerebral cortex, the Purkinie cells of the cerebella cortex, their associated structures, ventral thalamic nuclei and the reticular thalamic nuclei that seem to function as neural conduction in the thalamus.

• Bulletin of the Korean Chemical Society
• /
• 제32권8호
• /
• pp.2617-2622
• /
• 2011

Two new Zn(II) complexes, $[Zn_2(dpa)_2(phen)_2(H_2O)_2]{\cdot}H_2O$ (1) (dpa = dephenate, phen = 1,10-phenanthroline) and [$Zn_2(dpa)_2(bpy)_2(H_2O)_2$] (2) (bpy = 2,2'-bipyridine) have been synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The X-ray analysis reveals that the structures of 1 and 2 are dinuclear zinc(II) complexes bridged by dpa dianions, respectively. The zinc ions in 1 exhibit a distorted square pyramidal environments, while the zinc ions in 2 exhibit a trigonal bipyramid geometry. In each complex, the dpa ligand is coordinated to zinc ions as a bis-monodentate.

• International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
• /
• 제6권1호
• /
• pp.38-43
• /
• 2003

This paper presents the results of a post-tensioning test and analysis of a pyramidal unit structure that is basic element for space structures. The behavior characteristics was analyzed and compared with the numerical analysis and the mechanism in test model was confirmed with geometrical analysis. The results of this paper show that the behaviors of space structures can be predicted in multi-directional Mero joint system. And the authors suggest the possibility of erection and shaping formation with comparatively small post-tensioning, and space structure with the mechanism should consider the nonlinear behavior due to large deformation.

• The Korean Journal of Physiology and Pharmacology
• /
• 제24권6호
• /
• pp.517-527
• /
• 2020

Layer 2/3 pyramidal neurons (L2/3 PyNs) of the cortex extend their basal dendrites near the soma and as apical dendritic tufts in layer 1, which mainly receive feedforward and feedback inputs, respectively. It is suggested that neuromodulators such as serotonin and acetylcholine may regulate the information flow between brain structures depending on the brain state. However, little is known about the dendritic compartment-specific induction of synaptic transmission in single PyNs. Here, we studied layer-specific serotonergic and cholinergic induction of long-term synaptic plasticity in L2/3 PyNs of the agranular insular cortex, a lateral component of the orbitofrontal cortex. Using FM1-43 dye unloading, we verified that local electrical stimulation to layers 1 (L1) and 3 (L3) activated axon terminals mostly located in L1 and perisomatic area (L2/3). Independent and AMPA receptor-mediated excitatory postsynaptic potential was evoked by local electrical stimulation of either L1 or L3. Application of serotonin (5-HT, 10 μM) induced activity-dependent longterm depression (LTD) in L2/3 but not in L1 inputs. LTD induced by 5-HT was blocked by the 5-HT₂ receptor antagonist ketanserin, an NMDA receptor antagonist and by intracellular Ca²⁺ chelation. The 5-HT₂ receptor agonist α-me-5-HT mimicked the LTD induced by 5-HT. However, the application of carbachol induced muscarinic receptor-dependent LTD in both inputs. The differential layer-specific induction of LTD by neuromodulators might play an important role in information processing mechanism of the prefrontal cortex.

• Bulletin of the Korean Chemical Society
• /
• 제22권12호
• /
• pp.1316-1322
• /
• 2001

Transition metal complexes of novel mono- and di-ferrocene-substituted porphyrins have been synthesized and characterized by structural and electrochemical methods. The X-ray structures of Mn(FPTTP)Cl and Mn(DFTTP)Cl showed the distorted square pyramidal coordination geometry with syn configuration of chloride and ferrocenyl substituents. The electrochemistry of ferrocene-substituted porphyrins and their metal complexes has been determined to elucidate the ${\pi}-conjugation$ effect of the porphyrin ring. The ferrocenyl group of H2FPTTP underwent a reversible one-electron transfer process at 0.30 V, indicating the good electron donating effect of the phorphyrin ring to the ferrocene substituent. The redox potential of the ferrocenyl subunit and porphyrin ring was affected by the central metal ions of the metalloporphyrins, that is, Zn(II) and Ni(II) made the oxidation of ferrocene much easier and Mn(III) made it harder. The ferrocene subunits of H2DFTTP interacted electrochemically with each other with peak splitting of 0.21 V. The strength of the electrochemical interactions between the two ferrocenyl substituents can be controlled by central metal ions of metalloporphyrins.

• 한국농촌건축학회논문집
• /
• 제16권1호
• /
• pp.111-117
• /
• 2014

The aim of this study is to find out the pattern of Ger form, inner spatial composition of Mongolian Ger house, and to take a dig at the structural or symbolic elements of nomadic architecture of Ger. To the point of view of corresponding to living and space of housing, remarkable characteristics of Ger Architecture is able to pull down and recombine the structures of nomadic house. Even though urbanization of Mongolia has spreading rapidly in a whole nation, most of people preserves traditional housing pattern within Ger. The ways of survey are to study of traditional home of Mongolia, and then field work at residence or mountain area in Ulan Bator and Gorkhi Terelj National Park area. This survey contains the form, size, structure, spatial composition of living space, structure, and materials. There are three results as follows: First, the form of Ger house is like a pyramidal or crown roof style to approximate to the round shape of it. Usually they had lived in nomadic way of life, so the Ger had a movable and flexible structure. Second, the Ger is easy to build up and deconstruct to move or find a new pasture. Third, the Mongolian Ger structure is composed by mainly five elements that are Khana, Khaalga, Toono, Bagana, and Uni. It has a hierarchy of internal spaces which are classified to gender, orientation, and property.

• Bulletin of the Korean Chemical Society
• /
• 제33권1호
• /
• pp.95-99
• /
• 2012

Two novel copper(II) complexes, [Cu(dmamhp)$(H_2O)_2(SO_4)]_n$ (1) and [Cu(dmamhp)$(NO_3)_2(H_2O)]{\cdot}H_2O$ (2) [dmamhp = 2-dimethylaminomethyl-3-hydroxypyridine] have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. Compound 1 displays a double one-dimensional chains structure, in which each chain is constituted with the distorted octahedral copper(II) complex bridged through bidentate sulfate ligands resulting in a coordination polymer. The bifurcated hydrogen bonds and $\pi-\pi$ interactions play important roles in the formation of the double chains structure. On the other hand, compound 2 adopts a distorted square pyramidal geometry around copper(II) ion and exists as a discrete monomer. There are intermolecular bifurcated hydrogen bonds and $\pi-\pi$ stacking interactions between the monomeric units. The magnetic properties revealed that the paramagnetic behaviors are dominantly manifested and there are no intermolecular magnetic interactions in both compound 1 and 2.

• 대한화학회지
• /
• 제62권2호
• /
• pp.106-112
• /
• 2018

Ice-binding proteins have an affinity for ice. They create a gap between the melting and freezing points by inhibiting the growth of ice, known as thermal hysteresis (TH). Interestingly, moderately active LeIBP and hyperactive FfIBP are almost identical in primary and tertiary structures, but differ in TH activity. The TH of FfIBP is tenfold higher than that of LeIBP, due to a subtle difference in their ice-binding motifs. To further evaluate the difference in TH, the interactions were investigated by ice-etching and molecular docking. Ice-etching showed that FfIBP binds to the primary and secondary prism, pyramidal, and basal planes; previously, LeIBP was found to bind to the basal and primary prism planes. Docking analysis using shape complementarity (Sc) showed that the hyperactive FfIBP had higher Sc values for all four ice planes than LeIBP, which is comparable with TH. Docking can be used to describe the hyperactivity of IBPs.