• Title/Summary/Keyword: Pure gas

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The Characteristics on Arc Pressure Distribution of TIG Welding with Shield Gas Mixing Ratio (TIG 용접에서의 실드 가스 혼합비에 따른 아크 압력분포 특성)

  • Oh Dong-Soo;Kim Yeong-Sik;Cho Sang-Myung
    • Journal of Welding and Joining
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    • v.23 no.1
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    • pp.41-47
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    • 2005
  • Arc pressure is one of important factors in understanding physical arc phenomena. Especially it affects on the penetration, size and shape of TIG welding. Some researches were reported on the effect of arc pressure in low and middle current region. But there are not any research in high current region. The purpose of this study is to investigate the arc pressure distribution with mixing ratio of shield gas such as Ar and He gases. A Cu block with water cooling was specifically designed and used as an anode electrode in order to measure the arc pressure in high current region. Then, the arc pressure distribution was measured with change in welding current and mixing ratio of shield gases. The arc force was obtained by numerically integrating the measured results. As the results, it was shown that the arc pressure was concentrated at the central part of the arc in middle and high current regions when a pure Ar gas was used. In case of Ar + He mixing gas, the arc pressure was much lower than that of pure Ar gas. In addition, it was widely distributed to radial direction.

Trimethylamine Sensing Characteristics of Molybdenum doped ZnO Hollow Nanofibers Prepared by Electrospinning (전기방사방법에 의해 합성된 ZnO 중공 나노섬유의 trimethylamine 가스 감응 특성)

  • Kim, Bo-Young;Yoon, Ji-Wook;Lee, Chul-Soon;Park, Joon-Shik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.24 no.6
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    • pp.419-422
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    • 2015
  • Pure and Mo-doped ZnO hollow nanofibers were prepared by single capillary electrospinning and their gas sensing characteristics toward 5 ppm ethanol, trimethylamine (TMA), CO and $H_2$ were investigated. The gas responses and responding kinetics were dependent upon sensing temperature and Mo doping. Mo-doped ZnO hollow nanofibers showed high response to 5 ppm TMA ($R_a/R_g=111.7$, $R_a$: resistance in air, $R_g$: resistance in gas) at $400^{\circ}C$, while the responses of pure ZnO hollow nanofibers was low ($R_a/R_g=47.1$). In addition, the doping of Mo enhanced selectivity toward TMA. The enhancement of gas response and selectivity to TMA by Mo doping to ZnO nanofibers was discussed in relation to the interaction between basic analyte gas and acidic additive materials.

An analysis of influence on chemical additives in gas hydrate formation (하이드레이트 제조시 다양한 화학물질 첨가에 의한 영향 분석)

  • Lee Young-Chul;Mo Yong-Gi;Cho Byoung-Hak;Baek Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.8 no.4 s.25
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    • pp.23-29
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    • 2004
  • This work carried out experiment to change characteristics of hydrate formation using various chemicals which are acetone, dimethylbutane, polyvinylalcohol, methanol and ethlyene glycol as additives in gas hydrate formation. Gas storage ability of formed hydrate with acetone, firnethylbuthane and polyvinylalcohol in gas hydrate formation increased higher than that obtained with pure water. Among them polyvinylalcohol showed best gas storage ability, so it is a more useful promoter Methanol and Ethylene gl?col in using additives showed the characteristics of inhibitor and methanol is lower gas storage ability than ethylene gl)rcol as a inhibitor in hydrate formation, so it is a more useful inhibitor. But, low concentration of methanol and ethylene glycol showed considerably higher gas storage ability of hydrate than that obtained with Pure water and showed the characteristics of promoter in gas hydrate formation.

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Development of a High Efficiency Polymer Electrolyte Membrane Fuel Cell Stack under Pressurized Operating Conditions (고효율 가압형 고분자전해질 연료전지 셀스택 개발)

  • Han, In-Su;Seo, Hakyu;Jung, Jeehoon;Kim, Minsung;Shin, Hyunkhil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.125.1-125.1
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    • 2010
  • A high efficiency polymer electrolyte membrane (PEM) fuel cell stack was developed for pressurized pure hydrogen and oxygen supplying conditions. The design objective for the cell stack was to maximize the electric efficiency and to minimize exhaust-gas emissions from it simultaneously. To achieve this objective, the cell stack was designed to use pure hydrogen and oxygen as fuel and oxidant, respectively, and to be operated under high gas inlet pressures and in a stage-wise dead-end operation mode. Major components constituting the cell stack, such as membrane electrode assembly, bipolar-plate, and gasket, have been developed to meet a target durability even in severe operating conditions: high gas inlet pressures and usage of pure oxygen. A high-power fuel cell stack was assembled using these components to verify the performance. The cell stack showed a good performance in terms of the efficiency and maximum power output.

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Characteristics of Pure Mg Powder Compacts Prepared by Spark Plasma Sintering Process (방전플라즈마 소결법으로 제작된 순 마그네슘 분말 소결체의 특성평가)

  • Hong, Ji-Min;Son, Hyeon-Taek;Chang, Se-Hun;Lee, Jae-Seoul;Cha, Yong-Hun;Oh, Ik-Hyun
    • Korean Journal of Materials Research
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    • v.17 no.6
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    • pp.331-336
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    • 2007
  • The pure Mg powder compacts were successfully fabricated using SPS process. The machined chip powder showed flake shaped morphology with coarse surfaces, while gas atomized powders were spherical in morphology with smooth surfaces. In this study, SPS process was used to consolidate the pure Mg powder because this process allows high density consolidation in a short time. The results showed that increased sintering temperature from $350^{\circ}C$ to $500^{\circ}C$ with pressure of 30MPa, the maximum values of the density was increased from 98.1% to 99.8% of theoretical density, respectively. However, density of the sintered chip powders was higher than that of gas-atomized powder due to larger contact areas between particles.

SIMULATION ON PURE OXYGEN COMBUSTION OF SMV FOR $CO_2$ REDUCTION (이산화탄소 저감을 위한 SMV의 순산소 연소 시뮬레이션)

  • Kim, H.Y.;Sohn, H.S.;Kim, C.M.
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.275-277
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    • 2011
  • KOGAS(Korea Gas Corporation) uses two-type vaporizers to send customers natural gas with imported LNG. In winter season, SMVs(SubMerged combustion Vaporizers) are mainly operated due to low seawater temperature. SMVs consume the natural gas of 1,520 $Nm^3/hr$ and emit a lot of $CO_2$ in winter time. If carbon taxes are activated on climate change, the tax burden will be severely heavy. Accordingly this work carried out numerical simulation with a commercail CFX code to investigate its possibility on the practical use of pure oxygen combustion of SMVs to reduce $CO_2$ and to improve its efficiency. First, a nozzle of a SMV's combustor is modelled. The combustion characteristics of Air/Fuel and Oxygen/Fuel are analyzed under folly insulated condition. Although we couldn't find the carbon reduction and the efficient elevation when the pure oxygen/fuel type was compared to the existing air/fuel one, we need a further study to investigate the effect of $CO_2$ recirculation.

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Pressure-Temperature Diagram of Critical Condition for Disproportionation of Nd-Fe-B Alloy in Hydrogen

  • Kwon, H.W.;Kim, D.H.;Yu, J.H.
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.155-158
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    • 2010
  • The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

Removal potential of dissolved gas in gas hydrate desalination process by reverse osmosis (역삼투막을 이용한 가스하이드레이트 해수담수화 공정 내 용존 가스의 제거 가능성 평가)

  • Ryu, Hyunwook;Kim, Minseok;Lim, Jun-Heok;Kim, Joung Ha;Lee, Ju Dong;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.635-643
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    • 2016
  • Gas hydrate (GH)-based desalination process have a potential as a novel unit desalination process. GHs are nonstoichiometric crystalline inclusion compounds formed at low temperature and a high pressure condition by water and a number of guest gas molecules. After formation, pure GHs are separated from the remaining concentrated seawater and they are dissociated into guest gas and pure water in a low temperature and a high pressure condition. The condition of GH formation is different depending on the type of guest gas. This is the reason why the guest gas is a key to success of GH desalination process. The salt rejection of GH based desalination process appeared 60.5-93%, post treatment process is needed to finally meet the product water quality. This study adopted reverse osmosis (RO) as a post treatment. However, the test about gas rejection by RO process have to be performed because the guest gas will be dissolved in a GH product (RO feed). In this research, removal potential of dissolved gas by RO process is performed using lab-scale RO system and GC/MS analysis. The relation between RO membrane characteristics and gas removal rate were analyzed based on the GC/MS measurement.

Thermophysical Properties of CO2 and CO2-Hydrate Mixture and In-Tube Heat Transfer Characteristics (CO2-Hydrate와 CO2 가스 혼합물의 전달물성과 관내측 열전달계수 및 압력강하 예측)

  • Yun, Rin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.5
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    • pp.233-239
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    • 2013
  • The Thermophysical properties of thermal conductivity, viscosity, and heat capacity for $CO_2$ slurry ($CO_2$ gas and $CO_2$-hydrate mixture) having a high gas phase volume fraction were predicted using the conventional mixture models and the TRAPP model under hydrate formation conditions. Based on the calculated thermophysical properties, the heat transfer coefficient and pressure drop of the $CO_2$ slurry in the tube were predicted. The thermal conductivity of $CO_2$ slurry ranged from 0.02 to 0.2 W/m-K, and the mixture viscosity was larger than that of pure $CO_2$ by 1.9~2.7 times. The heat capacity of $CO_2$ slurry ranged from 63 to 68% of that for pure $CO_2$. The predicted heat transfer coefficient of $CO_2$ slurry was 6 times higher than that of pure $CO_2$. In the separate model, the estimated pressure drop increased with an increase of $CO_2$-hydrate mole fraction, and was 60% of that of pure $CO_2$.

Sensing characteristics of polyaniline sensor coated with porous PVDF layers to methanol gas under various humidity conditions (다공성 PVDF막이 코팅된 Polyaniline 센서의 다양한 습도분위기의 메탄올 가스에 대한 감응특성)

  • Lim, Cheol-Beom;Sohn, Sung-Ok;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.205-210
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    • 2006
  • Hydrophobic polymer [ex. Poly(vinylidenfluoride)] layer was coated on polyaniline (PANi) sensor to reduce the contamination humidity. The differences in sensitivity to methanol gas detection in various humidity condition between pure-PANi sensor and sensor coated with poly(vinylidenfluoride) polymer (PVDF) (coated-PANi sensor) were investigated. Considering the relation between the density of pore, which was coated on the layer of the PANi sensor, and sensitivity was investigated. To fabricate the porous PVDF layer on PANi sensor, poly(vinylalcohol) (PVA), which is water-soluble polymer, was used. Coated-PANi sensor was less affected by humidity compared with pure-PANi sensor. And higher density of pore on PVDF layer led to higher sensitivity.