• Title/Summary/Keyword: Pu

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Manufacturing and Characteristics Analysis of PU/MWNT Composite Film for Forming (발포용 PU/MWNT 복합필름의 제조와 특성분석)

  • Park, Jun-Hyeong;Kim, Jeong-Hyun;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.362-372
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    • 2010
  • This paper surveys the physical properties of the multiwall carbon nanotube (MWNT) and polyurethane composite film for improvement of mechanical properties and electrical characteristics. The modification of MWNT was carried out by acid treatment with nitric and sulphuric acid mixed solution, and then followed by thermal treatment for enhancing MWNT dispersion with polyurethane. This modified MWNT was mixed with polyurethane by changing the loading content of MWNT and dispersion time under the dimethylformamide solution in the ultrasonic wave apparatus. Various physical characteristics of the modified PU/MWNT films were measured and analyzed in terms of the loading content and dispersion time. The maximum absorbance of the PU/MWNT films were observed with the 2wt% loading at dispersion times of 2 and 24 hour, respectively. The minimum electrical volume resistivity of PU/MWNT film was shown at the loading content of 0.5wt% or more irrespective of dispersion treating time. However the optimum condition was assumed to 2wt% loading at dispersion time of 2 hours by assessing the surface profile of the film using video microscope. The breaking stress and strain of the PU/MWNT film decreased with increasing loading content, but no change of physical properties was shown with increasing in dispersion time.

Power Allocation Schemes For Downlink Cognitive Radio Networks With Opportunistic Sub-channel Access

  • Xu, Ding;Feng, Zhiyong;Zhang, Ping
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.6 no.7
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    • pp.1777-1791
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    • 2012
  • This paper considers a downlink cognitive radio (CR) network where one secondary user (SU) and one primary user (PU) share the same base station (BS). The spectrum of interest is divided into a set of independent, orthogonal subchannels. The communication of the PU is of high priority and the quality of service (QoS) is guaranteed by the minimum rate constraint. On the other hand, the communication of the SU is of low priority and the SU opportunistically accesses the subchannels that were previously discarded by the PU during power allocation. The BS assigns fractions ?? and 1 ?? of the total available transmit power to the PU and the SU respectively. Two power allocation schemes with opportunistic subchannel access are proposed, in which the optimal values of ??'s are also obtained. The objective of one scheme is to maximize the rate of the SU, and the objective of the other scheme is to maximize the sum rate of the SU and the PU, both under the PU minimum rate constraint and the total transmit power constraint. Extensive simulation results are obtained to verify the effectiveness of the proposed schemes.

Polyurethane Nanocomposites with Organoclay (유기화 점토를 이용한 폴리우레탄 나노 복합재료)

  • 안영욱;장진해;박연흠;박종민
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.381-388
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    • 2002
  • The properties of polyurethane (PU) nanocomposites with organoclay have been compared in terms of their thermo-mechanical properties, morphology, and gas permeability. Hexadecylamine-montmorillonite ($C_{16}$-MMT) was used as an organoclay to make PU hybrid films. The properties were investigated as a function of organoclay content (1-4 wt%) in the PU matrix. Transmission electron microscopy (TEM) photographs showed that most clay layers were dispersed homogeneously into the matrix polymer in nano-scale, although some particles of clay were agglomerated. We also found that the addition of only a small amount of organoclay was enough to improve the thermal stabilities and mechanical properties of PU hybrid films while gas permeability was reduced. Even at low organoclay content (<5 wt%), the PU nanocomposite showed much better thermo-mechanical properties, and lower gas permeability than pure PU.

Analyses and improvement of fuel temperature coefficient of rock-like oxide fuel in LWRs from neutronic aspect

  • Shelley, Afroza
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1156-1163
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    • 2020
  • Fuel temperature coefficient (FTC) of PuO2+ZrO2 (ROX) fueled LWR cell is analyzed neutronically with reactor- and weapons-grade plutonium fuels in comparison with a U-free PuO2+ThO2 (TOX), and a conventional MOX fuel cells. The FTC value of a ROX fueled LWR is smaller compared to a TOX or a MOX fueled LWRs and becomes extremely positive especially, at EOL. This is because when fuel temperature is increased, thermal neutron spectrum is shifted to harder, which is extreme at EOL in ROX fuel than that in TOX and MOX fuels. Consequently at EOL, 239Pu and 241Pu contributes to positive fuel temperature reactivity (FTR) in ROX fuel, while they have negative contribution in TOX and MOX fuels. The FTC problem of ROX fuel is mitigated by additive ThO2, UO2 or Er2O3. In ROX-additive fuel, the atomic density of fissile Pu becomes more than additive free ROX fuel especially at EOL, which is the main cause to improve the FTC problem. The density of fissile Pu is more effective to decrease the thermal spectrum shifts with increase the fuel temperature than additive ThO2, UO2 or Er2O3 in ROX fuel.

Correlations between Zirconium Isotopes and Burnup Parameters in PWR Spent Nuclear Fuels

  • Kim, Jung-Suk;Chun, Young-Shin;Lee, Chang heon;Kim, Won-Ho;Eom, Tae-Yun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.551-556
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    • 1998
  • The correlation of isotope composition of Zr with the turnup and some heavy isotopes in PWR uranium dioxide fuel has been investigated. The total and partial ($^{235}$ U) burnup were determined by $^{148Nd}$ and by U and Pu mass spectrometric method, respectively. After separating Zr from the fuel samples, its isotope composition was measured by mass spectrometry. In addition, the quantities of the U and Pu in the spent fuel were determined by isotope di lution mass spectrometric method using $^{233}$ U and $^{242}$ Pu as spikes. The content of some heavy isotopes, $^{235}$ U, $^{239}$ Pu and $^{241}$ Pu, and the Pu Contribution to total turnup were expressed by the correlation with Zr isotope ratios, $^{91}$ Zr/$^{96}$ Zr and $^{93}$ Zr/$^{96}$ Zr The correlations by isotope compositions measured were compared wi th those calculated from ORIGEN2 code.

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The Synthesis of One-step Type Hydrophilic Non-porous Polyurethane Resin and the Physical Property of its Coated Fabric for the Garment (One-step형 친수무공형 폴리우레탄 수지 합성과 코팅 처리한 의류용 직물의 물성)

  • Yang, Sung-Yong;Kim, Hyun-Ah;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.131-139
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    • 2011
  • This study surveyed on the synthesis of one-step type hydrophilic non-porous PU resin and the physical property of the coated fabric for the garment. Three kinds of chain extender such as MEG, 1,4-BD and NPG were used for the preparation of one-step type hydrophilic non-porous PU resin in order to examine the effect of chain extender on the physical properties of PU-coated fabric. And the effects of isocyanate on the physical properties of PU coated fabric were surveyed by mixing with various TDI and MDI ratios. In addition, the physical properties of the coated fabric treated with one-step type hydrophilic non-porous PU resin were examined according to the pre-treatment conditions such as cire finishing. Finally, the washing durability of the coated fabrics was assessed. The coated fabrics treated with PU resin synthesized with PEG1000, MEG and TDI/MDI (6/4) showed the best physical properties. Considering the pre-treatment conditions, best performance of hydraulic pressure, water vapor permeability, and water repellency were obtained with top roller rotation ratio of 150% under 50 ton pressure at $170^{\circ}C$.

The Effect of Repetitive Compression on the Fatigue Properties of Foam for Footwear Mid-sole (반복압축이 스포츠화용 발포체의 피로특성에 미치는 영향)

  • Park, Cha-Cheol
    • Elastomers and Composites
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    • v.40 no.4
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    • pp.242-248
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    • 2005
  • To study the fatigue properties of three type of foams for footwear midsole, polyurethane(PU), phylon(PH) and injection phylon(IP) foams were prepared with different hardnesses. Three types of foams were repetitively compressed for 50,000 cycles at 50 rpm. Cell shapes of foams were deformed with repetitive compression. The extent of cell deformation of IP was larger than those of PH and PU. Permanent strain of foam was made by repetitively compressing the foam, and the extent of IP was larger than those of PU and PH. Maximum compression forces of three types of the foams were decreased with the repetitive compression, and IP had the largest decrease in compression load of foam with compression. Decreases in maximum compression force of three types of foams were increased with increase of the hardness of foam.

Photoprotection effect of Pu'er tea and Curcuma longa L. extracts against UV and blue lights

  • Doyeong Son;Ji-Su Jun;KwangWon Hong
    • Journal of Applied Biological Chemistry
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    • v.66
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    • pp.106-113
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    • 2023
  • Plant extracts have been studied due to their potential as photoprotective agents against UV and blue light exposure. Previous studies have revealed that several plant extracts have photoprotection capacities and synergistic effects with synthetic products. However, such results for pu'er tea and Curcuma longa L. have not been reported yet for a cosmetic formulation. Thus, the objective of this study was to evaluate photoprotection capacities of pu'er tea and C. longa L. extracts for a sunscreen compound. The pu'er tea extract improved sun protection factor value of 2-ethyl-hexyl methoxycinnamate (a synthetic sunscreen compound) by 46% and showed a high antioxidant capability that could help skin recover from photo-induced damage. C. longa L. extract also showed a potential to protect skin from blue light-induced damage because it not only had a maximum absorption peak at the blue light range, but also protected human fibroblasts from blue light-induced damage. The addition of both extracts shifted the critical wavelength of 2-ethyl-hexyl methoxycinnamate from 350 nm to 386 nm, giving it a broad-spectrum feature. Thus, pu'er tea and C. longa L. extracts may enhance the photoprotection ability of synthetic sunscreen products.

Effect of Acrylic Acid on the Physical Properties of UV-cured Coating Films for Metal Coating (금속코팅용 광경화 코팅필름의 물성에 대한 아크릴산(Acrylic acid)의 영향)

  • Seo, Jong-Chul;Choi, Jun-Suk;Jang, Eui-Sung;Seo, Kwang-Won;Han, Hak-Soo
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.75-82
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    • 2011
  • Five different composition UV-cured poly(urethane acrylate-co-acrylic acid) (PU-co-AA) films have been prepared by reacting isophorone diisocyanate(IPDI), polycaprolactone triol(PCLT), 2-hydroxyethyl acrylate(HEA), and different weight ratio trimethylolpropane triacrylate(TMPTA) and acrylic acid(AA) as diluents, and characterized using a Fourier transform infrared spectroscopy(FT-IR). The adhesion properties onto the stainless steel, morphology, mechanical hardness, and electrical property of UV-cured PU-co-AA films were investigated as a function of acrylic acid(AA) content. All the PU-co-AA films are structure-less and the molecular ordering and packing density decreased with increasing content of AA due to the flexible structure and -COOH side chains in AA. The crosscut test showed that PU-co-AA films without AA and with low content of AA showed 0% adhesion(0B) and the adhesion of PU-co-AA films in the range of 40-50% AA increased dramatically as the content of AA increases. The pull-off measurements showed that the adhesion force of PU-co-AA films to stainless steel substrate varied from 6 to 31 kgf /$cm^2$ and increased linearly with increasing AA content. The mechanical hardness also decreased as the content of AA increases. This may come from relatively linear and flexible structure in AA and low crystallinity in PU-co-AA films with higher content of AA. The higher AA-containing PU-co-AA films showed higher dielectric constant due to the increase of polarization by introducing AA monomer. In conclusion, the physical properties of UV-cured PU-co-AA films are strongly dependent upon the content of AA and the incorporation of AA in polyurethane acrylate is very useful way to increase the adhesion strength of UV-curable polymers on the stainless steel substrate.

Fast HEVC Encoding based on CU-Depth First Decision (CU 깊이 우선 결정 기반의 HEVC 고속 부호화 방법)

  • Yoo, Sung-Eun;Ahn, Yong-Jo;Sim, Dong-Gyu
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.49 no.3
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    • pp.40-50
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    • 2012
  • In this paper we propose the fast CU (Coding Unit) mode decision method. To reduce computational complexity and save encoding time of HEVC, we divided CU, PU (Prediction Unit) and TU (Transform Unit) decision process into two stages. In the first stage, because $2N{\times}2N$ PU mode is mostly selected among $2N{\times}2N$, $N{\times}2N$, $2N{\times}N$, $N{\times}N$ PU modes, proposed algorithm uses only $2N{\times}2N$ PU mode deciding depth of each CU in the LCU (Largest CU). And then, proposed method decides exact PU and TU modes at the depth level which is decided in the first stage. In addition, early skip decision rule is applied to the proposed method to obtain more efficient computational complexity reduction. The proposed method reduces computational complexity of the HEVC encoder by simplifying a CU depth decision method. We could obtain about 50% computational complexity reduction in comparison with HM 3.3 HEVC reference software while bitrate compressed by the proposed algorithm increases only 2%.