• Title/Summary/Keyword: PtD

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UV Enhanced NO2 Sensing Properties of Pt Functionalized Ga2O3 Nanorods

  • An, Soyeon;Park, Sunghoon;Mun, Youngho;Lee, Chongmu
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1632-1636
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    • 2013
  • $Ga_2O_3$ one-dimensional (1D) nanostructures were synthesized by using a thermal evaporation technique. The morphology, crystal structure, and sensing properties of the $Ga_2O_3$ nanostructures functionalized with Pt to $NO_2$ gas at room temperature under UV irradiation were examined. The diameters of the 1D nanostructures ranged from a few tens to a few hundreds of nanometers and the lengths ranged up to a few hundreds of micrometers. Pt nanoparticles with diameters of a few tens of nanometers were distributed around a $Ga_2O_3$ nanorod. The responses of the nanorods gas sensors fabricated from multiple networked $Ga_2O_3$ nanorods were improved 3-4 fold at $NO_2$ concentrations ranging from 1 to 5 ppm by Pt functionalization. The Pt-functionalized $Ga_2O_3$ nanorod gas sensors showed a remarkably enhanced response at room temperature under ultraviolet (UV) light illumination. In addition, the mechanisms via which the gas sensing properties of $Ga_2O_3$ nanorods are enhanced by Pt functionalization and UV irradiation are discussed.

The Effect of Cr Dosage on FePt Nanoparticle Formation

  • Won, C.;Keavney, D.J.;Divan, R.;Bader, S.D.
    • Journal of Magnetics
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    • v.11 no.4
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    • pp.182-188
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    • 2006
  • The search for high-density recording materials has been one of most active and vigorous field in the field of magnetism. $FePt-L1_{0}$ nanoparticle has emerged as a potential candidate because of its high anisotropy. In this paper, we provide an overview of recent work at Argonne National Laboratory that contributes to the ongoing dialogue concerning the relation between structure and properties of the FePt nanoparticle system. In particular we discuss the ability to control structure and properties via dosing with Cr. Cr-dosed FePt films were grown via molecular beam epitaxy and annealed at $550^{\circ}C$ in an ultrahigh vacuum chamber, and were studied with the surface magneto-optic Kerr effect (SMOKE), scanning electron microscopy (SEM) and x-ray magnetic circular dichroism (XMCD). We found that small dosage of Cr helps to generate $L1_{0}$ phase FePt magnetic nanoparticles with small size, defined shape and regular spatial distribution on MgO (001) substrate. The nanostructures are ferromagnetic with high magnetic coercivity (${\sim}0.9T$) and magnetic easy axis in the desired out-of-plane orientation. We also show that controlling the lateral region where nanostructures exist is possible via artificial patterning with Cr.

A thermal properties of micro hot-plate fabricated by using the Pt/Cr bilayer (Pt/Cr 이중층을 이용한 미세 발열체의 제작과 발열특성)

  • Yi, Seung-Hwan;Suh, Im-Choon;Sung, Yong-Kwon
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1982-1984
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    • 1996
  • In this paper, we have evaluated the physical characteristicsof the Pt/Cr bilayer, fabricated the micro hot plate by using the Pt/Cr bilayer and E-beam evaporated oxide as a passivation layer, and simulated the thermal distribution by using the commercial software FIDAP. From the researches the sheet resistance of Pt/Cr bilayer didn't be affected by the Cr layer thickness. This results was considered due to the Cr-oxide resided at the interface between Pt and Cr layer. After manufacturing the hot plate, we measured its temperature by type k thermo-couple and I.R. thermo-vision system. In those experiments, the emission coefficient( ${\varepsilon}$ ) of the E-beam evaporated oxide was 0.5 and the temperature of centural region was reached about $305\;^{\circ}C$ at 1.3 watts. The temperature simulation obtained by FIDAP commercial package stewed that the temperature of centural region was about $311\;^{\circ}C$ after 5 sec.

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The Development of Electronic Transformer for 245kV GIS (245kV GIS용 전자식변성기 개발)

  • Kim, Young-Min;Kim, Min-Soo;Kim, Jung-Bae;Lee, Hahk-Sung
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.373-374
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    • 2008
  • 지금까지 변전소나 발전소에서 전류, 전압을 계측하는 수단으로서 주로 철심과 권선으로 구성되어진 변류기(CT), 계기용 변압기(PT)가 사용되어져 왔다. 최근, 2차측의 계측기나 보호 Relay의 Digital 화가 진전되어져 있다. 또한, Digital Network로 총합한 Intelligent 변전소가 시범적으로 구축되어짐에 따라 Digital Network에 대응한 초고압용 신형 CT, VD가 요구되어지고 있다. 상기와 같은 요구로 인해 당사에서는 기존의 CT.PT의 단점을 보완할 수 있는 245kV GIS용 로고스키코일형 CT와 Capacitive Voltage Divider를 개발 중에 있으며, 센서 자체의 특성시험에서 IEC 60044-7, 8 1Class 기준을 만족하는 특성을 얻을 수 있었다. 이러한 신형 CT.VD의 적용으로 종래의 CT.PT가 차지하는 공간이 필요 없게 되어 컴팩트한 GIS의 구조가 가능하게 될 것이다.

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Performance Charateristics of Direct Borohydrides Fuel Cell with Novel Catalyst (귀금속 촉매를 사용한 직접 보로하이드라이드 연료전지의 특성 연구)

  • Jung, M.K.;Shin, D.R.;Seol, Y.K.;Jung, D.H.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.6-11
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    • 2005
  • Direct borohydrides fuel cell (DBFC) was emerged to complement the problem of DMFC's low performance and methanol crossover to the cathode and to apply the fuel cell to portable and mobile devices. In this study, the characteristics of novel catalysts was tested to establish the electrode preparation process of DBFC. Pt black and carbon supported-Pt by paste method were used as the cathode catalysts. Pt black, carbon supported-Au and $AB_5$ alloy were used as the anode catalysts. The characteristics of the electrodes were analyzed by XRD, SEM, EDS. The performance test of single cell using the electrodes were carried out in order to evaluate the electrode performance. In the result, the maximum power output was obtained as 366 mW/mg when using Pt/C as anode and cathode catalysts.

Effect of Red Ginseng Saponins on Intestinal Contractility (장평활근의 수축성에 대한 홍삼 Saponins의 효과)

  • 신동호;오정이
    • Journal of Ginseng Research
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    • v.22 no.3
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    • pp.200-205
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    • 1998
  • Isolated rabbit jejunal segments were used to study the effects of ginseng total saponins (GTS) , protopanaxatriol saponins (PT) and protopanaxadiol saponins (PD) on intestinal contractility. GTS, PT and PD caused a dose-dependent decrease in intestinal spontaneous movements, and PT was the most efficacious of them. The effect of GTS, PT and PD were not blocked by pretreatment with phentolamine (10-6 M), yohimbine (10-6 M), d1-propranolol (10-6 M), naloxone(10-6∼10-5M), Nu-nitro-L-arginine methyl ester (10-4 M), methylene blue (10-5M), and N-ethylmaleimide (10-4 M). However, pretreatment with tetraethylammonium chloride (3-10 mM) antagonized the effect of GTS, PT and PD. Furthermore, 4-amlnopyridine (1 mM) also inhibited the effect of GTS, PT and PD. The results suggest that GTS, PT and PD inhibited the spontaneous movements in isolated rebait jejunum by causing hyperpolarization through an activation of K+ channels directly.

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EFFECTS OF Pt AND Cr ADDITION ON MAGNETIC PROPERTIES IN Co-Cr-P-Pt MAGNETIC THIN FILMS

  • Sohn, H.K.;Shin, K.H.;Lee, T.D.;Kang, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.618-622
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    • 1995
  • We studied the effects of Pt and Cr addition in a new Co-Cr-P-Pt alloy system with the coercivity higher than 2000 Oe even when they were deposited without substrate heating and bias voltage. The coercivity of the films increased from 1000 to 2000 Oe or higher by addition of 12 at.%Pt. The variation of the anisotropy field with increasing Pt content was similar to that of the coercivity. This indicate that the increase of the coercivity might be associated with increase of the anisotropy field with Pt addition. With the addition of Cr, the coercivity of the films increased up to 8 at.%Cr and the coercive squareness of the films decreased. The angular variation of coercivity deviated at a lower angle from domain wall motion mode as the Cr content increases. From these result, it is believed that the grain isolation of the films is enhanced with the addition of Cr.

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Hydrogen Sulfide Sensing Characteristics Depending on Electrolytes of Pt/CNT Liquid Electrochemical Sensors (Pt/CNT 전극 기반 전기화학식 센서의 전해질에 따른 황화수소 감지 특성)

  • Yuntae Ha;JinBeom Kwon;Suji Choi;Soobeen baek;Daewoong Jung
    • Journal of Sensor Science and Technology
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    • v.32 no.3
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    • pp.194-198
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    • 2023
  • With the recent development of industrial technology, the problem of odor due to leakage of toxic gas discharged from industrial complexes is gradually increasing. Among them, hydrogen sulfide is a colorless representative odorous substance that can cause pain through irritation of the mucous membranes of the eyes and respiratory tract, and is a gas that can cause central nervous system paralysis and suffocation when exposed to high concentrations. Therefore, in order to improve the odor problem, research on a gas sensor capable of quickly and reliably detecting a leak of hydrogen sulfide is being actively conducted. A lot of research has been done on the existing metal oxide-based hydrogen sulfide gas sensor, but it has the disadvantage of requiring low selectivity and high temperature operating conditions. Therefore, in this study, a Pt/CNT-based electrochemical hydrogen sulfide gas sensor capable of detecting at low temperatures with high selectivity for hydrogen sulfide was developed. A working electrode capable of selectively detecting only hydrogen sulfide was fabricated by synthesizing Pt nanoparticles as a catalyst on functionalized CNT and applied to an electrochemical hydrogen sulfide gas sensor. It was confirmed that the manufactured Pt/CNT-based electrochemical hydrogen sulfide gas sensor has a current change of up to 100uA for hydrogen sulfide, and the both response time and recovery time were within 15 seconds.

Interplay of collagen and mast cells in periapical granulomas and periapical cysts: a comparative polarizing microscopic and immunohistochemical study

  • Deepty Bansal;Mala Kamboj;Anjali Narwal;Anju Devi;Nisha Marwah
    • Restorative Dentistry and Endodontics
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    • v.47 no.1
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    • pp.12.1-12.11
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    • 2022
  • Objectives: This pilot study aimed to establish the interrelationship between collagen and mast cells in periapical granulomas and periapical cysts. Materials and Methods: An observational cross-sectional study was conducted on the paraffin-embedded tissue sections of 68 specimens (34 periapical granulomas and 34 periapical cysts). The specimens were stained with picrosirius to observe collagen fiber birefringence and anti-tryptase antibody to evaluate the mast cell count immunohistochemically. The mean number and birefringence of collagen fibers, as well as the mean number of mast cells (total, granulated, and degranulated), and the mean inflammatory cell density were calculated. The data obtained were analyzed using the Kruskal Wallis test, Mann Whitney U test, and Spearman correlation test (p < 0.05). Results: The mean number of thick collagen fibers was higher in periapical cysts, while that of thin fibers was higher in granulomas (p = 0.00). Cysts emitted orange-yellow to red birefringence, whereas periapical granulomas had predominantly green fibers (p = 0.00). The mean inflammatory cell density was comparable in all groups (p = 0.129). The number of total, degranulated, and granulated mast cells exhibited significant results (p = 0.00) in both groups. Thick cyst fibers showed significant inverse correlations with inflammation and degranulated mast cells (p = 0.041, 0.04 respectively). Conclusions: Mast cells and inflammatory cells influenced the nature of collagen fiber formation and its birefringence. This finding may assist in the prediction of the nature, pathogenesis, and biological behavior of periapical lesions.