• Title/Summary/Keyword: Pt(111)

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Effect of Pd impurity on the Cube-texture in Cold Rolled and Recrystallized PtPd alloy for the Application to RABiTS (초전도 테이프 기판을 위한 PtPd 합금의 압연 및 재결정 정렬에 대한 Pd 첨가물의 영향)

  • Yoo, Ja-Eun;Youm, Do-Jun
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.292-295
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    • 1999
  • We investigated the effects of Pd impurities on cube-textures in cold rolled and recrystallized PtPd tapes The sample were made from Pt$_{1-x}Pd_x$ alloys (x from 0 to0.34) by rolling at low temperature. The thickness of the tapes were about 100 ${\mu}$m. The PtPd[111] pole figures of X-ray Diffraction for all the samples indicated similar deformed textures. But the recrystallized textures after annealing showed that a better cube texture was formed in the sample of larger x. The final textures were sensitive to annealing time and temperature when x was increased.

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Structural Properties of KLN Thin Film Deposited on Pt Coated Si Substrate (Pt 코팅된 Si 기판에 제조한 KLN 박막의 구조적 특성)

  • 박성근;이기직;백민수;전병억;김진수;남기홍
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.410-416
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    • 2001
  • KLN thin films were fabricated on Pt coated Si(100) wafer using an rf-magnetron sputtering method. The grown KLN thin film consists of 4-fold grains. In this experiment, the structure of 4-fold grained thin film was investigated using XRD and SEM measurements. Pt layer was also deposited using the rf-magnetron sputtering method,. XRD measurement showed that he Pt thin film has Gaussian distribution form with strong (111) direction orientation. The KLN thin film has preferred-orientation of (001) direction, and the peak consists of 2 separate peaks; one with broad FWHM and the other with narrow FWHM. The sharp peak is due to single crystal, and combining with Em results, the 4-fold grain consists of singel crystals with c-axis normal to substrate.

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An Analysis of the Growing Orientation of PMN-PT Single Crystal Using the Laue Back-Reflection Method (라우에 배면반사법을 이용한 PMN-PT 단결정 성장 방향 분석)

  • Joh, Cheeyoung;Seo, Hee-Seon;Kwon, Byung-Jin;Lee, Won-Ok;Lee, Sang-Goo;Kim, Min-Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.787-791
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    • 2015
  • In this paper, the growing orientation of PMN-PT single crystal is analyzed using the Laue-Back Reflection Method. Two kinds of PMN-PT single crystals are grown using the Bridgman growing method in the [001] and [111] directions and their the Laue photographs are simulated assuming cubic crystal systems. From the comparison between simulation and test results, it can be concluded that the single crystals are grown in the desired crystal orientations.

A Study of the Electrode Catalyst Migration and Aging Mechanism of PEMFC (고분자연료전지 내 촉매 이동 및 노화메커니즘에 관한 연구)

  • Lee, Yoon-Hee;Lee, Ki-Suk;Yun, Jong-Jin;Byun, Jung-Yeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.3
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    • pp.256-263
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    • 2012
  • We studied the degradation phenomenon of Pt catalyst in PEMFC. We used the electron microscope analysis technique including the ultra-microtome pretreatment method, FEG-SEM and TEM analysis methods for analysis of Pt nanoparticles. The Pt catalyst degradation is observed not only in electrode site but also in membrane site. We investigated these various degradation phenomena. The cathode electrode layer thickness is reduced. The size of the catalyst is increased much larger than initial size in membrane site. The catalyst moved from electrode layer to the electrolyte membrane. The rounded shape of catalyst was changed to the polygon. As a result, we found that the catalyst degradation processes of migration and coarsening occurred by the followings mechanisms; (1) dissolution of Pt ; (2) diffusion of Pt ion ; (3) Pt ion chemical reduction in membrane; (4) Coarsening of Pt particles (Ostwald ripening) ; (5) polygon shape change of Pt by {111} plane growth.