• 전기화학회지
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• 제6권2호
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• pp.153-157
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• 2003

전기이중층 축전용량(electric double layer capacitance)과 유사축전용량(pseudo-capacitance)을 함께 갖는 하이브리드 전기화학 축전기에 대한 연구를 수행하였다. 양극은 $Ni(OH)_2$ 활성탄소가 복합된 전극을 사용하였으며 음극은 활성탄소를 활물질로 사용하므로써 비대칭 전극 구조를 갖는다. 셀 실험을 위하여 $5\times5cm^2$ 크기인 전극을 제작 사용하였다. Cyclic voltammetry측정 및 교류 임피던스 측정실험을 통하여 각각의 셀들이 갖는 전기화학적 거동을 조사하였고 충 방전 실험을 통하여 양극과 음극의 최적 질량비를 조사하였다.

• 전기화학회지
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• 제3권4호
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• pp.241-245
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• 2000

비정질 $MnO_2\;nH_2O$ 전극재료를 사용한 pseudo-capacitor를 설계 제작하여 특성을 평가하였다. 100mV/s의 cyclic voltammogram으로부터 측정한 결과, 이 전극재료의 안정한 potential window는 1V이고 비용량은 250F/g이었다. TDMA(Time Division Multiplex Algorithm) pulse 시험에서 TDMA 시스템 (2 parallel-pseudo-capacitor systems) 은 0.22V의 ohmic voltage drop과 0.38V의 capacitor voltage drop을 보여주었다. 이 TDMA system의 total voltage drop이 0.60V이므로 TDMA 위성통신 휴대전화의 요건인 1V maximum voltage drop을 충족하였다. 또한, 이 system의 ESR과 비용량은 각각 $55m{\Omega}$과 105mF이었다. 따라서 이 TDMA system이 위성통신 휴대전화를 위한 load-leveling 캐패시터로 응용 가능함을 확인하였다.

• Carbon letters
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• 제23권
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• pp.9-16
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• 2017

This paper introduces a nitrogen-doped ordered mesoporous carbon (NOMC) derived from glucosamine with hybrid capacitive behaviors, achieved by successfully combining electrical double-layer capacitance with pseudo-capacitance behaviors. The nitrogen doping content of the fabricated NOMC reached 7.4 at% while its specific surface area ($S_{BET}$) and total pore volume reached $778m^2g^{-1}$ and $1.17cm^3g^{-1}$, respectively. A dual mesoporous structure with small mesopores centered at 3.6 nm and large mesopores centered at 9.9 nm was observed. The specific capacitance of the reported materials reached up to $328Fg^{-1}$, which was 2.1 times higher than that of pristine CMK-3. The capacitance retention rate was found to be higher than 87.9% after 1000 charge/discharge cycles. The supplementary pseudocapacitance as well as the enhanced wettability and conductivity due to the incorporation of nitrogen heteroatoms within the carbon matrixes were found to be responsible for the excellent capacitive performance of the reported NOMC materials.

• 대한기계학회논문집A
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• 제28권1호
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• pp.70-78
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• 2004

This paper presents study of efficiency of wavelet transformation for on-line chatter detection during hard fuming process. From comparison with other time series and statistical methods such as fast fourier transformation (FFT), Kurtosis and standard deviation (STD), wavelet transform is better than others in on-line chatter detection. With using wavelet function with pseudo frequency corresponding to chatter frequency, chatter could be detected more sensitively. And for both force signal from dynamometer and displacement signal from capacitance type cylindrical sensor (CCS), wavelet transform with DB2 function on level 4 could be well used for chatter detection in hard turning process.

• JSTS:Journal of Semiconductor Technology and Science
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• 제14권4호
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• pp.443-450
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• 2014

This paper presents a 20-Gb/s optical receiver circuit fabricated with standard 65-nm CMOS technology. Our receiver circuits are designed with consideration for parasitic inductance and capacitance due to bonding wires connecting the photodetector and the circuit realized separately. Such parasitic inductance and capacitance usually disturb the high-speed performance but, with careful circuit design, we achieve optimized wide and flat response. The receiver circuit is composed of a transimpedance amplifier (TIA) with a DC-balancing buffer, a post amplifier (PA), and an output buffer. The TIA is designed in the shunt-feedback configuration with inductive peaking. The PA is composed of a 6-stage differential amplifier having interleaved active feedback. The receiver circuit is mounted on a FR4 PCB and wire-bonded to an equivalent circuit that emulates a photodetector. The measured transimpedance gain and 3-dB bandwidth of our optical receiver circuit is 84 $dB{\Omega}$ and 12 GHz, respectively. 20-Gb/s $2^{31}-1$ electrical pseudo-random bit sequence data are successfully received with the bit-error rate less than $10^{-12}$. The receiver circuit has chip area of $0.5mm{\times}0.44mm$ and it consumes excluding the output buffer 84 mW with 1.2-V supply voltage.

• 한국정보과학회논문지:시스템및이론
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• 제26권12호
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• pp.1458-1467
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• 1999

VLSI 공정 기술이 발달하면서 이웃한 전선 간의 간격이 점점 더 가까워 지고 있으며, 그에 따라 인접 전선 간의 혼신 문제가 심각해지고 있다. 본 논문에서는 3층 그리드 채널 배선에 적용 가능한 혼신을 최소화시키는 배선층 할당 방법을 제안한다. 이 방법은 선형 의사 불린 최적화 기법에 맞도록 고안되었으며, 적절한 변수 선택 휴리스틱과 상한값 추정 방법을 통하여 최적의 결과를 짧은 시간 안에 찾아낸다. 실험 결과를 통하여, 일반적인 0/1 정수 선형 프로그래밍 기법과 비교하여 성능과 수행시간 면에서 우수함을 보인다. Abstract Current deep-submicron VLSI technology appears to cause crosstalk problem severe since it requires adjacent wires to be placed closer and closer. In this paper, we deal with a horizontal layer assignment problem for three layer HVH channel routing to minimize coupling capacitance, a main source of crosstalk. It is formulated in a 0/1 integer linear programming problem which is then solved by a linear pseudo boolean optimization technique. Experiments show that accurate upper bound estimation technique effectively reduces crosstalk in a reasonable amount of running times.

• Carbon letters
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• 제13권3호
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• pp.157-160
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• 2012

In this work, iron oxide ($Fe_3O_4$) nanoparticles were deposited on multi-walled carbon nanotubes (MWNTs) by a simple chemical coprecipitation method and $Fe_3O_4$-decorated MWNTs (Fe-MWNTs)/polypyrrole (PPy) nanocomposites (Fe-MWNTs/PPy) were prepared by oxidation polymerization. The effect of the PPy on the electrochemical properties of the Fe-MWNTs was investigated. The structures characteristics and surface properties of MWNTs, Fe-MWNTs, and Fe-MWNTs/PPy were characterized by X-ray diffraction and X-ray photoelectron spectroscopy, respectively. The electrochemical performances of MWNTs, Fe-MWNTs, and Fe-MWNTs/PPy were determined by cyclic voltammetry and galvanostatic charge/discharge characteristics in a 1.0 M sodium sulfite electrolyte. The results showed that the Fe-MWNTs/PPy electrode had typical pseudo-capacitive behavior and a specific capacitance significantly greater than that of the Fe-MWNT electrode, indicating an enhanced electrochemical performance of the Fe-MWNTs/PPy due to their high electrical properties.

• 전기화학회지
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• 제10권2호
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• pp.141-144
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• 2007

Polypyrrole(PPy) was composite with MWNT to attain cycle stable by chemical method. We have been considered PPy is the ideal material for high energy density electrochemical capacitor due to pseudo capacitor reaction. In this study we found that increase in cycle life due to composite MWNT. Also PPy/MWNT composite material have resulted larger capacitance and exhibits better electrochemical behavior. The structural feature was investigated by using SEM and TEM. The PPy/CNT composite is not only a promising ultracapacitor material for energy storages but also has a good possibility because of its great capacitive properties, simple preparation and low cost.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.1365-1366
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• 2007

Cobalt oxide was composite with MWNT to attain cycle stable by chemical method. We have been considered CoOx is the ideal material for high energy density electrochemical capacitor due to pseudo capacitor reaction. In this study we found that decrease in resistance due to composite MWNT. Also CoOx/MWNT composite material have resulted larger capacitance and exhibits better electrochemical behavior. The structural feature was investigated by using SEM. The CoOx/MWNT composite is not only a promising ultracapacitor material for energy storages but also has a good possibility because of its great capacitive properties, simple preparation and low cost.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.425-431
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• 2005

비표면적이 큰 혼합 활성탄과 전도도가 높은 전도성고분자 폴리피롤을 이용하여 낮은 임피던스와 높은 에너지밀도를 가지는 새로운 형태의 슈퍼커패시터를 제조하였다. 전극 활성물질로 활성탄 BP-20과 MSP-20을 사용하였고, 전기 전도도를 높이기 위하여 활성탄에 전도성 개량제 카본블랙(Super P)과 2-naphthalenesulfonic acid(2-NSA)로 도핑된 전도성 고분자 폴리피롤을 첨가하였다. 용액상태의 유기 결합제 poly(vinylidenefluoride-co-hexafluoropropylene) [P(VdF-co-HFP)/NMP]에 전극 소재들을 혼합시켜 전극을 제조하였다. 실험 결과 최적의 전극 배합비는 78(MSP-20: BP-20=1 : 1) : 17 (Super P : Ppy=10:7) : 5 [P(VdF-co-HFP)] wt％이었다. 폴리피롤이 7 wt％ 첨가된 단위셀의 비정전용량은 28.02 F/g, DC-ESR은 $1.34{\Omega}$, AC-ESR은 $0.36{\Omega}$, 에너지밀도는 19.87 Wh/kg, 동력밀도는 9.77 kW/kg이었다. 500회 충 방전 실험 후 초기 정전용량의 80％를 유지하여 사이클 특성이 우수하였다. 폴리피롤을 첨가함으로써 낮은 내부 저항, 슈도용량(pseudo capacitance)의 발현, 낮은 전하전이저항 및 빠른 반응속도에 의하여 급속한 충 방전이 가능하였다. 그리고 활성탄의 흡탈착에 의한 비패러데이 용량과 폴리피롤의 산화 환원에 의한 슈도용량의 복합현상 때문에 비정전용량이 높게 나타났다.