• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.39-42
• /
• 2007

Hydrogen fuel cell is clean and efficient technology along with high energy densities. While there are many different types of fuel cells, the proton exchange membrane fuel cell stands out as one of the most promising for transportation and small stationary applications. This paper focuses on design of bipolar plate for proton exchange membrane fuel cell. The bipolar plate model is realistically and accurately simulated velocity distribution, current density distribution and its effect on the PEMFC system using CFD tool FLUENT.

• Journal of Astronomy and Space Sciences
• /
• v.32 no.3
• /
• pp.181-187
• /
• 2015

Storm sudden commencements (SSCs) occur due to a rapid compression of the Earth's magnetic field. This is generally believed to be caused by interplanetary (IP) shocks, but with exceptions. In this paper we explore possible causes of SSCs other than IP shocks through a statistical study of geomagnetic storms using SYM-H data provided by the World Data Center for Geomagnetism - Kyoto and by applying a superposed epoch analysis to simultaneous solar wind parameters obtained with the Advanced Composition Explorer (ACE) satellite. We select a total of 274 geomagnetic storms with minimum SYM-H of less than -30nT during 1998-2008 and regard them as SSCs if SYM-H increases by more than 10 nT over 10 minutes. Under this criterion, we found 103 geomagnetic storms with both SSC and IP shocks and 28 storms with SSC not associated with IP shocks. Storms in the former group share the property that the strength of the interplanetary magnetic field (IMF), proton density and proton velocity increase together with SYM-H, implying the action of IP shocks. During the storms in the latter group, only the proton density rises with SYM-H. We find that the density increase is associated with either high speed streams (HSSs) or interplanetary coronal mass ejections (ICMEs), and suggest that HSSs and ICMEs may be alternative contributors to SSCs.

• Transactions of the Korean hydrogen and new energy society
• /
• v.25 no.4
• /
• pp.378-385
• /
• 2014

In this research, we investigate electrical performance and electrochemical properties of graphene supported Pt (Pt/G) and PtM (M = Ni and Y) alloy catalysts (PtM/Gs) that are synthesized by modified polyol method. With the PtM/Gs that are adopted for oxygen reduction reaction (ORR) as cathode of proton exchange membrane fuel cells (PEMFCs), their catalytic activity and ORR performance and electrical performance are estimated and compared with one another. Their particle size, particle distribution and electrochemically active surface (EAS) area are measured by TEM and cyclic voltammetry (CV), respectively. On the other hand, regarding ORR activity and electrical performance of the catalysts, (i) linear sweeping voltammetry by rotating disk electrode and rotating ring-disk electrode and (ii) PEMFC single cell tests are used. The TEM and CV measurements demonstrate particle size and EAS of PtM/Gs are compatible with those of Pt/G. In case of PtNi/G, its half-wave potential, kinetic current density, transferred electron number per oxygen molecule and $H_2O_2$ production % are excellent. Based on data obtained by half-cell test, when PEMFC singlecell tests are carried out, current density measured at 0.6V and maximum power density of the PEMFC single cell employing PtNi/G are better than those employing Pt/G. Conclusively, PtNi/Gs synthesized by modified polyol shows better ORR catalytic activity and PEMFC performance than other catalysts.

• Nuclear Engineering and Technology
• /
• v.37 no.3
• /
• pp.279-286
• /
• 2005

A prototype of a relativistic proton generation system, based on laser-induced plasma interaction, has been designed and fabricated. The system is composed of three major parts: a fs TW laser; a target chamber, including targets and controls; and a diagnostic system for charged particles and lasers. An Offner-type pulse stretcher for chirped pulse amplification (CPA) and eight pass pre-amplifier are installed. The main amplifier will be integrated with a new pumping laser. The design values of the laser at the first stage are 1 TW in power and 50 fs in pulse duration. We expect to generate protons with their maximum energy of approximately 3 MeV and the flux of at least $10^6$ per pulse using a 10 $\mu$m Al target. A prototype target chamber with eight 8-inch flanges, including target mounts, has been designed and fabricated. For laser diagnostics, an adaptive optics based on the Shack-Hartmann type, beam monitoring, and alignment system are all under development. For a charged particle, CR-39 detectors, a Thomson parabola spectrometer, and Si charged-particle detectors will be used for the density profile and energy spectrum. In this paper, we present the preliminary design for laser-induced proton generation. We also present plans for future work, as well as theoretical simulations.

• Journal of the Korean Ceramic Society
• /
• v.40 no.2
• /
• pp.159-166
• /
• 2003

The preparation method for composite membranes of high temperature operation above $100^{\circ}C$ for Polymer Electrolyte Membrane Fuel Cells (PEMFCs ) was presented, using perfluorosulfonylfluoride Nafion resin and mordenite, in addition to the physical properties, proton conductivity and single cells performance for it. The composite membranes were fabricated via melting of Nafion resin with various mordenite content. As the increase of mordenite content, at high temperature range, proton conductivity of the composite membrane increased due to the late dehydration rate of existent water in the mordenite. Also, from the result of the current-voltage relationship for single cells under $130^{\circ}C$ operation condition, the composite membrane cell with l0 wt% mordenite content showed better performance than that of the others over the entire current density range. This result indicated that the existent water in the composite membrane with l0 wt% mordenite content was higher than that with the others, thereby maintains its conductivity. Based upon the results of experiments, therefore, a Nafion/mordenite composite membrane prepared by this work is thought to be a satisfactory polymer electrolyte membrane for PEMFC operation above $100^{\circ}C$.

• Journal of the Korean Ceramic Society
• /
• v.46 no.6
• /
• pp.695-699
• /
• 2009

We studied the transfer of oxygen vacancy and proton in Y-doped BaZr$O_3$ (BYZ) using density functional theory (DFT). An oxygen vacancy was generated in the $2{\times}2{\times}2$ BYZ superstructure by replacing two Zr atoms with two Y atoms to satisfy the charge neutrality condition. The O vacancy transfer between the first and second nearest O atom sites from a Y atom showed the lowest activation energy barrier of 0.42 eV, compared to the other transfers between first and first, and second and second in the superstructure. Two protons were inserted in the structure by adding a proton and hydroxyl that were supplied by the dissociation of a water molecule. The two protons bonded to the first and second nearest O atoms were energetically the most favorable. The activation energy barrier for a proton transfer in the structure was 0.51 eV, when either proton transferred to its neighbor O atom. This value was well matched with the experimentally determined one.

• Membrane Journal
• /
• v.22 no.3
• /
• pp.155-170
• /
• 2012

Fuel cells have been considered as alternative power generation system in the twenty-first century because of eco-friendly system, high power density and efficiency compare with petroleum engine system. Proton exchange membranes (PEMs) are the key components in fuel cell system. Currently, Nafion has been used in fuel cell system. However, Nafion has disadvantages such as low conductivity at high temperature and high cost. The researchers have focused to reach the high properties such as high proton conductivity, low permeability to fuel, good chemical/thermal stability, good mechanical properties and low manufacturing cost. Various methods have been developed for preparation of proton exchange membrane with high performance and commercialization of fuel cell system. The hybrid organic/inorganic membrane has the potentials to provide a unique combination of organic and inorganic properties with improved proton conductivity and mechanical property at high temperatures. So, this paper presents an overview of research trend for the composite membranes prepared by organic/inorganic system using various inorganic materials.

• The Bulletin of The Korean Astronomical Society
• /
• v.37 no.2
• /
• pp.118.1-118.1
• /
• 2012

In situ observations from the Wind spacecraft that statistically analyzed the solar wind proton at 1 AU has indicated that the measured proton temperature anisotropies seems to be regulated by the oblique instabilities (the mirror and oblique firehose). This result is in contradiction with the prediction of linear kinetic theory that the ion-cyclotron (for ${\beta}_{\parallel}$ < 2) and parallel firehose (for ${\beta}_{\parallel}$ <10) would dominate over the oblique instabilities. Various kinds of physical mechanisms have been suggested to explain this disagreement between the observations and linear theory. All of the suggestions consider the solar wind as a unoform magnetized plasma. However the real space environment is replete with the intermediate spatio-temporal scale variations associated with various physical quantities, such as the magnetic field intensity and the solar wind density. In this paper we present that the pervasive intermediate-scale temporal variation of the local magnetic field intensity can lead to the modification of the proton temperature anisotropy versus beta inverse correlation for temperature-anisotropy-driven instabilities. By means of quasilinear kinetic theory involving such temporal variation, we construct the simulated solar wind proton data distribution associated the magnetic fluctuations in (${\beta}_{\parallel}$, $T_{\perp}/T_{\parallel}$) space. It is shown that the theoretically simulated proton distribution and a general trend of the enhanced fluctuations bounded by the oblique instabilities are consistent with in situ observations. Furthermore, the measure magnetic compressibility can be accounted for by the magnetic spectral signatures of the unstable modes.

• Membrane Journal
• /
• v.14 no.3
• /
• pp.240-249
• /
• 2004

Crosslinked PVA membranes were achieved by esterification between the hydroxyl groups of PVA and carboxyl group of sulfosuccinic acid (SSA). SSA containing sulfonic group was used as a chemical crosslinking agent as well as a donor of fixed anionic group ($-SO_3$H). The crosslinking density of membranes was controlled by SSA content and calculated using polar and non-polar solvent. The crosslinking density measured by using non-polar solvent such as xylene and benzene increases with SSA content. However, using the polar solvent such as water and methanol, the crosslinking density increases up to SSA content of 20 wt% and above the content decrease due to sulfonic acid groups. The crosslinked PVA membranes were studied in relation with water diffusion coefficient and mechanical property as well as proton conductivity and methanol permeability as a function of crosslinking density. These properties were all dependent on the effect of SSA content.

• Korean Chemical Engineering Research
• /
• v.56 no.2
• /
• pp.151-155
• /
• 2018

Degree of membrane degradation in Proton Exchange Membrane Fuel Cells (PEMFC) is mainly evaluated by the hydrogen crossover current density. The hydrogen crossover current density is measured by linear sweep voltammetry (LSV), which differs from the DOE protocol and the NEDO protocol. In this study, two protocols were compared during PEMFC operation and accelerated stress test. In the LSV method by the DOE method, the scan rate change affects the hydrogen crossover current density, but the NEDO method does not affect the hydrogen crossover current density. In the course of 15,000 cycles of polymer membrane wet/dry cycle, the DOE method was sensitive to membrane degradation, but the NEDO method was less sensitive to membrane degradation than the DOE method.