• 한국수소및신에너지학회논문집
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• 제24권4호
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• pp.320-325
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• 2013

TUnitized reversible fuel cells (URFC) combine the functionality of a fuel cell and electrolyzer in one unitized device. For a URFC with proton exchange membrane, a titanium (Ti)-felt is applied to the gas diffusion layer (GDL) substrate at the oxygen electrode, and additionally titanium (Ti)-powders and TiN-powders are loaded in the GDL substrate as a micro porous layer (MPL). Double porous layer with TiN MPL was not acceptable for the URFC because both of fuel cell performance and electrolysis performance are degraded. The double porous layer with Ti-powder loading in the Ti-felt substrate influence rearly for the electrolysis performance. In contrast, the change of pore-size distribution brings a significant improvement of fuel cell performance under fully humidification conditions. This fact indicates that the hydrophobic meso-pores in the GDL play an important role for mass transport.

• Macromolecular Research
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• 제15권6호
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• pp.587-594
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• 2007

Well defined amphiphilic diblock copolymers of poly(styrene-b-vinylbenzylphosphonic acid) (PS-b-PVBPA) were prepared by controlled radical polymerization technique, two-step hydrolysis reactions using trime-thylsilyl bromide from the corresponding phosphonic ethyl ester. By indirect, backward pH titration of the block copolymer, a good titration curve of a dibasic acid was observed. The IEC values obtained from both backward pH titration and volumetric back titration were almost identical. Thermal gravimetric analysis (TGA) of the phosphonic acid containing block copolymer showed a high thermal stability up to $400^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.572-575
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• 2008

Flow-field design has much influence over the performance of proton exchange membrane fuel cell (PEMFC) because it affects the pressure magnitude and distribution of the reactant gases. To obtain the pressure magnitude and distribution of reactant gases in four kinds of flow-field designs without additional measurement equipment, computational fluid dynamics (CFD) analysis was performed. After the CFD analysis, the performance values of PEMFC according to the flow-field configurations were measured via a single cell test. As expected, the pressure differences due to different flow-field configurations were related to the PEMFC performance because the actual performance results showed the same tendency as the results of the CFD analysis. A large pressure drop resulted in high PEMFC performance. So, the single serpentine configuration gave the highest performance. On the other hand, the parallel flow-field configuration gave the lowest performance because the pressure difference between inlet and outlet was the lowest.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.254-256
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• 2009

The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

• 설비공학논문집
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• 제28권9호
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• pp.367-372
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• 2016

Gas diffusion layer (GDL) of PEMFCs plays a role that it diffuses the reactant gases to the catalyst layer on the membrane and discharge water from the catalyst layer to the channel. Physical parameters related to the mass transport of GDL are mostly from the uncompressed GDLs while actual GDLs in the assembled stacks are compressed. In this study, the relation of compression and strain of GDLs with various Polytetrafluoroethylene (PTFE) loading is measured experimentally and In-plane gas permeability is measured at the condition that the GDLs are in compressive strain. The gas permeability decreased with the loading of PTFE and the presentation of gas permeability under compressive stain is expected to improve the accuracy of modeling work of mass transport in the GDL.

• 한국정밀공학회지
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• 제25권1호
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• pp.115-121
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• 2008

In this paper, a three-dimensional computational fluid dynamic model of a proton exchange membrane fuel cell(PEMFC) with serpentine flow channel is presented. A steady state, single phase and isothermal numerical model has been established to investigate the influence of the GDL (Gas Diffusion Layer) parameters. The GDL is made of a porous material such as carbon cloth, carbon paper or metal wire mesh. For the simplicity, the GDL is modeled as a block of material having numerous pathways through which gaseous reactants and liquid water can pass. The porosity, permeability and thickness of the GDL, which are employed in the model parameters significantly affect the PEMFC performance at the high current region.

• 전기학회논문지
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• 제62권1호
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• pp.105-108
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• 2013

To resolve global environmental problems, many automobile companies are making a great deal of effort to develop so-called green-cars. One of the solutions is an electric vehicle equipped with the PEMFC (Proton Exchange Membrane Fuel Cell) stack. However, the cost of the stack, at the moment, is still too high. This obstacle must be resolved for commercialized fuel cell cars. One of the reasons for high cost is a relatively large amount of Pt (platinum) in the membrane. In this paper, a method for reducing the Pt-loading is introduced. Furthermore, the durability of the stack will be important for a company to stay competitive in world markets (in the future). For this, the diagnosis of the stack must be conducted on-line. Some diagnosis methods as key technology are also introduced in this paper.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.13-16
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• 2006

Electro-electrodialysis (EED) experiments were carried out for the HI concentration from HIx $(HI-H_2O-I_2)$ solution to improve the Hl decomposition reaction in the thermochemical water-splitting is (iodine-Sulfur) process. EED cell is composed of the collector electrode and electrolyte. Nafion 117 which was cation exchange membrane used as an electrolyte, and the activated carbon cloth used as an electrode. The HI concentration experiment was carried out using the HIx solution and molar ratio of the $I_2$ were varied from 1 to 3 mole. The cell voltages were decreased as temperature increase. And, membrane properties such as transport number of proton and electro-osmosis coefficient were decreased as temperature increase

• 신재생에너지
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• 제5권4호
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• pp.75-78
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• 2009

The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

• 한국수소및신에너지학회논문집
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• 제33권2호
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• pp.164-175
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• 2022

In this work, sulfonated poly (ether ether ketone) (SPEEK) composite membranes including strontium zirconate (SrZrO₃) were fabricated by the electrospinning method. Fourier-transform infrared spectroscopic analysis and X-ray diffraction analysis were used to identify the chemical structure and the crystallinity of SrZrO₃ and electrospun composite membranes. The thermal stability of the pure SPEEK and SPEEK/SrZrO₃ electrospun composite membranes were investigated by using thermogravimetric analysis. The physicochemical properties and proton conductivity were enhanced with the addition of different weight ratio of SrZrO₃ nanofiller (2, 4 and 6 wt%) in SPEEK polymer. The optimized SPEEK/SrZrO₃-4 electrospun membrane containing 4 wt% of SrZrO₃ showed a high proton conductivity compared to other electrospun SPEEK/SrZrO₃ composite membranes. The results indicate that electrospun composite membranes incorporating these perovskite nanofillers should be explored as potential candidates for use in proton exchange membrane fuel cells.