• Title/Summary/Keyword: Propane gas

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Cometabolic Biodegradation of Fuel Additive Methyl tert-Butyl Ether(MTBE) by Propane- and Butane-Oxidizing Microorganisms (프로판 및 부탄 이용 미생물에 의한 휘발유 첨가제 MTBE의 동시분해)

  • 장순웅
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.45-52
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    • 2003
  • A gas-substrate degrading bacterium, Nocardia SW3, was isolated from the gasoline contaminated aquifer using propane and butane as carbon and energy sources. We have examined the effects of substrate concentration, temperature and pH on the gas substrate degradation as well as MTBE cometabolic degradation. The result for the effect of substrate concentration showed that the maximum degradation rates of propane and butane were 30.6 and 25.4 (n㏖/min/mg protein) at 70 $\mu$㏖, respectively. The optimum temperature and pH for the degradation of gas substrate were $30^{\circ}C$ and 7, respectively. Substrate degradation activity, however, was still active in broad range of pH from 5 to 8 and temperature between $15^{\circ}C$and$35^{\circ}C$. The degradation activity of Nocardia SW3 for the MTBE was similar to the both substrates. The observed maximal transformation yields ($T_y$) were 46.7 and 35.0 (n㏖ MTBE degraded $\mu$㏖ substrate utilized), and the maximal transformation capacities ($T_c$) were 320 and 280 (n㏖MTBE degraded/mg biomass used) for propane and butane oxidizing activity on MTBE, respectively. And also, TBA was detected as by-product of MTBE and it was continuously degraded further.

Effect of Relative Humidity on Explosion Pressure for Gas Group IIB, IIA, and I (상대습도에 따른 가스 그룹 IIB, IIA, I의 폭발압력 분석)

  • Yongtae Kim;Kihyo Jung
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.51-58
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    • 2023
  • Determination of explosion reference pressure is important in designing and testing flameproof enclosures (Ex d). Although relative humidity affects to explosion pressure, its effect is not well investigated for the gas group IIB, IIA, and I. This study tested explosion pressure for Ethylene (8 vol.%), Propane (4.6 vol.%), and Methane (9.8 vol.%), which are the representative gas of the gas group IIB, IIA, and I, at ambient temperature and atmospheric pressure (1 atm) under different relative humidity (0% ~ 80%). Ethylene- and Propane-air mixed gases generally tended to decrease as the relative humidity increased; however, explosion pressure was largely dropped at 20% of relative humidity compared to 0% and 10% of relative humidity. On the other hand, Methane-air mixture gas showed similar pressures at 0% and 10% of relative humidity; but no explosion occurred at more than 20%. The results of this study can be used in setting a testing protocol of explosion reference pressure for designing and testing a flameproof enclosure.

Performance and Emissions Characteristics of a Converted Liquefied Petroleum Gas (LPG) Engine with Mixer and Liquid Propane Injection (LPi) System

  • Choi, Gyeung-Ho;Kim, Jin-Ho;Cho, Ung-Lae;Chung, Yon-Jong;Han, Sung-Bin
    • Journal of Energy Engineering
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    • v.14 no.3 s.43
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    • pp.187-193
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    • 2005
  • In this study, the performance and emission characteristics of a liquefied petroleum gas (LPG) engine converted from a diesel engine were examined by using mixer system and liquid propane injection (LPi) system. A compression ratio of 21 for the base diesel engine, was modified to 8, 8.5, 9 and 9.5. The engine performance and emissions characteristics are analyzed by investigating engine power, brake mean effective pressure (BMEP), brake specific fuel consumption (BSFC), volumetric efficienry, CO, THC and NOx. Experimental results showed that the LPi system generated higher power and lower emissions than the conventional mixer fuel supply method.

Influence of Propane and Butane on Engine Performance in a Homogeneous Charge Compression Ignition(HCCI) Engine (균질혼합압축점화기관에서 프로판과 부탄연료가 기관성능에 미치는 영향)

  • Choi Gyeung Ho;Kim Ji Moon;Han Sung Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.3 s.234
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    • pp.417-423
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    • 2005
  • This paper describes the engine performance of a Homogeneous Charge Compression Ignition(HCCI) engine according to Exhaust Gas Recirculation(EGR), cylinder-to-cylinder, fuel of propane and butane. HCCI engines are being considered as a future alternative for diesel and gasoline engines. HCCI engines have the potential for high efficiency, very low NOx emissions and very low particulate matter(PM). On experimental work, we have done an evaluation of operating conditions in a 4-cylinder compression engine. The engine has been run with propane and butane fuels at a constant speed of 1800rpm. This work is intended to investigate the HCCI operation of the engine in this configuration that has been modified from the base diesel engine. The performance and emissions of the engine are presented. In this paper, the start of combustion(SOC) is defined as the $50{\%}$ point of the peak rate of heat release. SOC is delayed slightly with increasing EGR. As expected, NOx emissions were very low for all EGR range and nbuned HC and CO emission levels were high. CO and HC emissions are lower with using propane than butane as fuels of HCCI engines.

Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Jung, Jae-Uk;Nam, Woo-Seok;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.85-88
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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A Study on the MESG of Flammable Ternary Gas Mixtures (3성분계 인화성 혼합가스의 MESG에 관한 연구)

  • Hwang, Kyungyong;Byeon, Junghwan;Rhee, Kyunam;Lee, Taeck-Kie
    • Journal of the Korean Institute of Gas
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    • v.20 no.3
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    • pp.30-37
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    • 2016
  • Electrical apparatuses for use in the presence of flammable gas atmospheres have to be specially designed to prevent them from igniting the explosive gas. Flameproof design implies that electrical components producing electrical sparks are contained in enclosures and withstand the maximum pressure of internal gas or vapours. In addition, any gaps in the enclosure wall have to designed in such a way that they will not transmit a gas explosion inside the enclosure to an explosive gas or vapours atmosphere outside it. In this study, we explained some of the most important physical mechanism of MESG(Maximum Experimental Safe Gap) that the jet of combustion products ejected through the flame gap to the external surroundings do not have an energy and temperature large enough to initiate an ignition of external gas or vapours. We measured the MESG and maximum explosion pressure of ternary gas mixtures(propane-acetylene-air) by the test method and procedure of IEC 60079-20-1:2010. As a result, the composition of propane gas that has lower explosive power than acetylene gas in the ternary gas mixtures makes greater effects on MESG and explosion pressure.

A Study on the Performance of an LPG (Liquefied Petroleum Gas) Engine Converted from a Compression Ignition Engine

  • Choi, Gyeung-Ho;Kim, Tae-Kwon;Cho, Ung-Lae;Chung, Yon-Jong;Caton, Jerald;Han, Sung-Bin
    • Journal of Energy Engineering
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    • v.16 no.1 s.49
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    • pp.1-6
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    • 2007
  • The purpose of this study was to investigate the reduction of exhaust gas temperature in a LPG engine that had been converted from a diesel engine. A conventional diesel engine was modified to a LPG (Liquefied Petroleum Gas) engine by replacing the diesel fuel injection pump with a LPG fuel system. The research was performed by measuring the exhaust gas temperature upon varying spark ignition timing, airfuel ratio, compression ratio, and different compositions of butane and propane. Engine power and exhaust temperature were not influenced by various butane/propane fuel compositions. Finally, among the parameters studied in this investigation, spark ignition timing is one of the most important in reducing exhaust gas temperature.

On the $SnO_2$ Semiconductor Gas Sensor ($SnO_2$ 소결체 반도체 Gas Sensor에 관한 연구)

  • 박순자;이재열
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.93-98
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    • 1983
  • The sensitivity characteristics of $SnO_2$-based gas sensor prepared by sintering method have been studied at the presence of CO and Propane gas. Samples mixed with 1wt% $La_2O_3$ and 1wt% $PdCl_2$ showed highest sensitivity to CO and propane gas at 250$^{\circ}$C but the addition of $CeO_2$ did not enhance the sensitivity. For slectivity for gas a $SnO_2-La_2O_3$ (1wt%) sample without $PdCl_2$ showed better results. A sample sintered sintered at 115$0^{\circ}C$ has shown the optimum condition in sensitivity and electroding

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Propane Reforming in Gliding Arc Plasma Reformer for SynGas Generation (합성가스 생성을 위한 글라이딩 아크 플라즈마 개질기에서 프로판 개질)

  • Yang, Yoon-Cheol;Chun, Young-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.11
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    • pp.869-875
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    • 2009
  • The purpose of this paper is to investigate the optimal condition of the syngas production by reforming of propane using Gliding arc plasma reformer. The gliding arc plasma reformer in 3 phases has been newly designed and developed with a quick starting and fast response time. It can be applicable to the various types of fuels (Hydrocarbons $C_xH_y$), and it has a high conversion rate of fuels and high production of hydrogen. The parametric screening studies were carried out according to the changes of a steam feed amount i.e., steam/carbon ratio, total gas flow rate and input electric power. The optimum operating conditions were S/C ratio 2.8, total gas flow rate of 14 L/min and input electric power of 2.4 kW. The result of optimum operating conditions showed the 55 % $H_2$, 14 % CO, 15 % $CO_2$, 10 % $C_3H_8$ and 4 % $CH_4$. Also, $C_3H_8$ conversion, $H_2$ yield and $H_2$ selectivity were 90 %, 42 %, 15 %, respectively. The energy efficiency and specific energy requirements were 37 % and 334 kJ/mol respectively.

Cost Analysis of High-Calorie Synthetic Natural Gas (고열량 합성천연가스 제조원가 분석)

  • Kim, Hyungsik;Park, Jinmo;Han, Jaryoung;Lee, Youngchul
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.67-71
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    • 2018
  • The calorific value of general synthetic natural gas(SNG) mainly composed of methane is $9,300kcal/m^3$ or less. In order to use such synthetic natural gas as city gas in Korea, it is necessary to heat up to $10,200kcal/m^3$. Generally, propane gas is commonly used to control the calorific value of SNG. However, the price of propane gas has fluctuated widely and has been higher than the cost of producing SNG. So if the high-calorie SNG can be produced directly instead of the calorie control by propane mixing, the production price of SNG can be significantly reduced. In this paper, based on the US NETL analysis, we compare the cost of methane based SNG production and the cost of high-calorie SNG direct production.