• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.4
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• pp.439-444
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• 2011

To determine the test gases for gas appliances of new gas group, the interrelation between gas interchangeability, including thermal efficiency, of 13A gas appliances and present 13A test gases was experimentally investigated. The test results show that the Wobbe indices in the case of incomplete combustion and the flame lifting limit gas for the new gas group are respectively 2% higher than the upper limit and 1% lower than the lower limit of the Wobbe index range. The most suitable composition of R gas is 96 mol% of methane and 4 mol% of propane; LNG could be also used as R gas. Further, analysis results showed that the hydrogen concentration of flash back limit gas could be lowered from 30 vol% to 23 vol%.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.6
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• pp.1652-1660
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• 1990

Combined radiative-convective heat transfer in a hot gas tube flow has been investigated numerically and experimentally. In the numerical analysis, a standard k-.epsilon. model is used for the evaluation of turbulent shear stresses and spherical harmonics method with the Weighted Sum of Gray Gases Model for the solution of radiative transfer equation. In the experimental study measured are the velocity and temperature of the hot gas flow generated by the propane gas combustion, and tude wall heat flux distribution. Numerical results are compared with experimental ones and it is confirmed that P-3 provides quite reliable results in the analysis of the combined radiation-convection system.

• The Journal of Advanced Prosthodontics
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• v.5 no.1
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• pp.44-50
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• 2013

PURPOSE. The aim of this study was to evaluate the effects of repeated porcelain firing process on the corrosion rates of the dental alloys. MATERIALS AND METHODS. Cr-Co, Cr-Ni and Pd-Ag alloys were used for this study. Each metal supported porcelain consisted of 30 specimens of 10 for 7, 9 and 11 firing each. Disc-shaped specimens 10 mm diameter and 3 mm thickness were formed by melting alloys with a propane-oxygen flame and casted with a centrifuge casting machine and then with the porcelain veneer fired onto the metal alloys. Corrosion tests were performed in quintuplicate for each alloy (after repeated porcelain firing) in Fusayama artificial saliva solution (pH = 5) in a low thermal-expansion borosilicate glass cell. Tamhane and Sheffe test was used to compare corrosion differences in the results after repeated firings and among 7, 9 and 11 firing for each alloy. The probability level for statistical significance was set at ${\alpha}$=0.05. RESULTS. The corrosion resistance was higher (30 mV), in case of 7 times firing (Commercial). On the other hand, it was lower in case of 11 times firing (5 mV) (P<.05). Conclusion. Repeated firings decreased corrosion resistance of Pd-Ag, Cr-Co and Cr-Ni alloys. The Pd-Ag alloy exhibited little corrosion in in vitro tests. The Cr-Ni alloy exhibited higher corrosion resistance than Cr-Co alloys in in vitro tests.

• The Korean Journal of Physiology and Pharmacology
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• v.2 no.3
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• pp.395-401
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• 1998

We have synthesized new platinum(II) analogs containing 1,2-diaminocyclohexane (dach) as a carrier ligand, 1,3-bis(diphenylphosphino) propane (DPPP) /1,2-bis(diphenylphosphino)ethane (DPPE) as a leaving group and nitrates to improve solubility. In the present study, the cytotoxicity of $[Pt(trans-l-dach)(DPPP)]\;2NO_3$ (KHPC-001) and $[Pt(trans-l-dach)(DPPE)]\;2NO_3$ (KHPC-002) was evaluated and compared on various P-388 cancer cell lines and porcine kidney cell line ($LLC-PK_1$). The new platinum complexes demonstrated high efficacy on P-388 mouse leukemia cell line as well as cisplatin-resistant (P-388/CDDP) and adriamycin-resistant (P-388/ADR) P-388 cell lines. The intracellular platinum content was measured by a flame atomic absorption spectrophotometer (FAAS), and it was comparable to the results of $IC_{50}$ of the three complexes on $LLC-PK_1$ and P-388/S cells, while only DPPE compound was accumulated in high volume in P-388/ADR and P-388/CDDP cells. While the DNA-interstrand cross-links of KHPC-001, KHPC-002 and cisplatin were similar on P-388/S leukemia cells, these new platinum complexes were much less DNA cross-linking to a kidney derived cell line, $LLC-PK_1$. These results indicate that KHPC-001 and KHPC-002 are a third-generation platinum complexes with potent antitumor activity and low nephrotoxicity.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.811-818
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• 2018

A fire and explosion accident caused by a liquefied petroleum gas (LPG) welding and cutting torch gas leak occurred 10 m underground at the site of reinforcement work for bridge columns, killing four people and seriously injuring ten. We conducted a comprehensive investigation into the accident to identify the fundamental causes of the explosion by analyzing the structure of the construction site and the properties of propane, which was the main component of LPG welding and cutting work used at the site. The range between the lower and upper explosion limits of leaking LPG for welding and cutting work was examined using Le Chatelier's formula; the behavior of LPG concentration change, which included dispersion and concentration change, was analyzed using the fire dynamic simulator (FDS). We concluded that the primary cause of the accident was combustible LPG that leaked from a welding and cutting torch and formed a explosion range between the lower and upper limits. When the LPG contacted the flame of the welding and cutting torch, LPG explosion occurred. The LPG explosion power calculation was verified by the blast effect computation program developed by the Department of Defense Explosive Safety Board (DDESB). According to the fire simulation results, we concluded that the welding and cutting torch LPG leak caused the gas explosion. This study is useful for safety management to prevent accidents caused by LPG welding and cutting work at construction sites.

• Fire Science and Engineering
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• v.26 no.5
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• pp.21-27
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• 2012

A real A real scale fire test was performed in accordance with KS F ISO 9705 test method to investigate the combustion characteristics of glass wool sandwich panels. To do this, six kinds of specimens having different density and thickness were examined. The glass sandwich panels were installed inside the room, which had internal dimensions of 2.4 m wide${\times}3.6m$ deep${\times}2.4m$ high. also, combustion characteristic are determined through the exposure of specimens to flame by the propane gas burner has a capacity of 100 kW (10 minutes) and 300 kW (10 minutes) for total 25 minutes of test time. Results of the real sale fire test, it was found that maximum HRR of each specimen was 333.2~365.5 kW, maximum heat flux was 12.4~12.9 kW/$m^2$ And, maximum internal temperature for all specimens was not over $500^{\circ}C$. During the real scale fire test, flash-over didn't occur and the difference by density and thickness of specimen was not found from the results of HRR, heat flux, and internal temperature measurement.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.2
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• pp.179-188
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• 2011

Experiments were conducted in a constant-pressure combustion chamber to investigate the effects of hydrocarbon addition on cellular instabilities of syngas-air flames. The measured laminar burning velocities were compared with the predicted results computed using reliable kinetic mechanisms with detailed transport and chemistry. The cellular instabilities that included hydrodynamic and diffusional-thermal instabilities of the hydrocarbon-added syngas-air flames were identified and evaluated. Further, experimentally measured critical Peclet numbers for fuel-lean flames were compared with the predicted results. Experimental results showed that the laminar burning velocities decreased significantly with an increase in the amount of hydrocarbon added in the reactant mixtures. With addition of propane and butane, the propensity for cell formation was significantly diminished whereas the cellular instabilities for methane-added syngas-air flames were not suppressed.