• Journal of the Korean Ceramic Society
• /
• v.26 no.6
• /
• pp.771-782
• /
• 1989

Synthesis of $\beta$-Sialon powder was attempted with carbothermal reduction of porous glass. The porous glass was prepared by heat and hydrothermal treatments of 9.32 Li2O.46.5B2O3.37.2SiO2.6.98Al2O3 glass. Carbon pyrolyzed from propane gas was deposited on the porous glass, thereafter activated carbon was added as reducing agents. The synthesized $\beta$-Sialon powder was pressureless sintered at 175$0^{\circ}C$ for 1hr in N2 atmosphere. The characterization of the $\beta$-Sialon powder was performed with XRD, BET, SEM and particle size analysis. The sinterability and mechanical properties of the sintered bodies were investigated in terms of bulk density, M.O.R., fracture toughness, morphology of microstructure and etc. The reduction effect of deposited carbon was better than that of activated carbon mechanically added. The formation of SiC was precominant over that of Si2ON2 and $\beta$-Sialon owing to low partial pressure of N2 inside the pore, wehreas on the surface of porous glass the formation of Si2ON2 and $\beta$-Sialon were predominant. Thereafter, SiC reduced unreacted glass to be $\beta$-Sialon. Single phase of $\beta$-Sialon(Z=1.92) was obtained from PGA porous glass having the largest pore radius by the simultaneous reduction and nitridation method at 145$0^{\circ}C$ for 5hrs. The bulk density, M.O.R., and KIC of the sitered body are 3.17g/cc, 434.4MPa and 4.1MPa.m1/2, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.10
• /
• pp.1025-1031
• /
• 2011

Autoignition characteristic is an important parameter for designing diesel or PCCI engines. In particular, diesel spray flames are lifted from the nozzle and the initial flame is formed by an autoignition phenomenon. The lifted nature of diesel spray flames influences soot formation, since air will be entrained into the spray core by the entrainment of air between the nozzle region and the lifted flame base. The objective of the present study was to identify the effect of heat loss on the ignition delay time by adopting a coflow jet as a model problem. Methane ($CH_4$), ethylene ($C_2H_4$), ethane ($C_2H_6$), propene ($C_3H_6$), propane ($C_3H_8$), and normal butane (n-$C_4H_{10}$) fuels were injected into high temperature air, and the liftoff height was measured experimentally. As the result, a correlation was determined between the liftoff height of the autoignited lifted flame and the ignition delay time considering the heat loss to the atmosphere.

• Clean Technology
• /
• v.25 no.1
• /
• pp.81-90
• /
• 2019

A dielectric barrier discharge (DBD) plasma reactor packed with $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst was used for the dry ($CO_2$) reforming of propane (DRP) to improve the production of syngas (a mixture of $H_2$ and CO) and the catalyst stability. The plasma-catalytic DRP was carried out with either thermally or plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst at a $C_3H_8/CO_2$ ratio of 1/3 and a total feed gas flow rate of $300mL\;min^{-1}$. The catalytic activities associated with the DRP were evaluated in the range of $500{\sim}600^{\circ}C$. Following the calcination in ambient air, the ${\gamma}-Al_2O_3$ impregnated with the precursor solution ($Ni(NO_3)_2$ and $Ce(NO_3)_2$) was subjected to reduction in an $H_2/Ar$ atmosphere to prepare $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst. The characteristics of the catalysts were examined using X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectrometry (EDS), temperature programmed reduction ($H_2-TPR$), temperature programmed desorption ($H_2-TPD$, $CO_2-TPD$), temperature programmed oxidation (TPO), and Raman spectroscopy. The investigation revealed that the plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst exhibited superior catalytic activity for the production of syngas, compared to the thermally reduced catalyst. Besides, the plasma-reduced $Ni-CeO_2/{\gamma}-Al_2O_3$ catalyst was found to show long-term catalytic stability with respect to coke resistance that is main concern regarding the DRP process.

• Journal of the Korean Institute of Gas
• /
• v.5 no.2 s.14
• /
• pp.36-42
• /
• 2001

A leak of fuel gas in partially confined area creates a flammable atmosphere and give rise to an explosion, which is one of the most common accident in domestic. Observations from accident in domestic suggest that some explosions are caused by a quantify of fuel significantly less than lower explosion limit(LEL) amount required to fill the room, which is attributed to inhomogeneous mixing of leaked gas. The minimum amount of leaked gas for explosion is highly dependent on the mixing degree in the area. For lighter gas, such as methane, a high concentration tends to build up in the space from ceiling of room. But heavy gas, such as propane, a high concentration tends to build up in the space from bottom of room. This paper presents a method for analysing the explosion hazard in a room with very small amount of leaked gas. Based on explosion limit concentration, the gaussian distribution model is used to estimate the minimum amount of leak which yields a specified explosion pressure. The results demonstrate that catastrophic structural damage can be achieved with a volume of fuel gas which is less than 0.5 percent of the total enclosed volume in domestic. The method will help analyzing hazard to develop new safe device as well as investigating accident.

• Elastomers and Composites
• /
• v.46 no.4
• /
• pp.295-303
• /
• 2011

A series of new aromatic polyhydroxyamides (PHAs) containing imide ring were prepared by direct polycondensation reaction of imide-diacids and two types of bis(o-aminophenol)s including 3,3'-dihydroxybenzidine and 2,2-bis(3-amino-4-hydroxyphenyl)hexafluoropropane. The polymers were characterized by FT-IR, FT-NMR, DSC and TGA. The inherent viscosities of the PHAs measured at $35^{\circ}C$ in DMAC solution were in the range of 0.49-1.13 dL/g. PHA 2 and 3, except PHA 1, were soluble in polar solvents such as DMAc, DMF and NMP. PHA 4, 5, and 6 containing 6F group showed a higher solubility in less polar solvents. But the polybenzoxazoles (PBOs,) were insoluble in a variety of solvents except partially soluble in sulfuric acid. The PBO 1, 2 and 3 showed maximum weight loss temperature in the range of $650-656^{\circ}C$ and relatively high char yields in the range of 57.4-61.9 % under a nitrogen atmosphere. These results suggested that the introduction of imide or diimide ring in the main chain was effective in improving the thermal stability of PHAs and PBOs.