• Title/Summary/Keyword: Product diffusion

검색결과 333건 처리시간 0.028초

A Conformational Isomer of Soulattrolide from the Stem Bark of Calophyllum symingtonianum and Its Antibacterial Activity

  • Susanti, Deny;Attoumani, Nissad;Taher, Muhammad;Rezali, Mohd Fazlin;Sohrab, Md. Hossain;Hasan, Choudhury Mahmood;Zakaria, Zainul Amiruddin
    • Natural Product Sciences
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    • 제24권1호
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    • pp.47-53
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    • 2018
  • Callophylum symingtonianum (Guttiferae), an evergreen broad-leaved tree that usually grows in hill forests, can be found distributed in the Malay Peninsula. The barks, leaves, flowers and seeds is often used medicinally to treat diarrhea and rheumatism. In the present study, we isolated two inophyllum type coumarins, 12-O-ethylinophyllum D (1) and iso-soulattrolide (2) from the stembarks of C. symingtonianum together with their antibacterial activity. The compounds were isolated by chromatographic methods on a silica gel. The structures were established by spectroscopic methods including UV, IR, (1D and 2D) NMR and mass spectrometry as well as by comparison with several literature sources. The antibacterial activity of those compounds was tested using a disc-diffusion assay against Staphylococcus aureus, Bacillus cereus, Escherichia coli and Pseudomonas aeruginosa. Both compound exhibited mild inhibition against P. aeruginosa with both $111{\mu}g/ml$ MIC value. Compound 2 also inhibits S. aureus with $25{\mu}g/ml$ MIC value.

Novel process of rare-earth free magnet and thermochemical route for the fabrication of permanent magnet

  • Choi, Chul-Jin
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2013년도 자성 및 자성재료 국제학술대회
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    • pp.89-89
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    • 2013
  • Rare earth (RE) - transition metal based high energy density magnets are of immense significance in various engineering applications. $Nd_2Fe_{14}B$ magnets possess the highest energy product and are widely used in whole industries. Simultaneously, composite alloys that are cheap, cost effective and strong commercially available have drawn great attention, because rare-earth metals are costly, less abundant and strategic shortage. We designed rare-earth free alloys and fabrication process and developed novel route to prepare $Nd_2Fe_{14}B$ powders by wet process employing spray drying and reduction-diffusion (R-D) without the use of high purity metals as raw material. MnAl-base permanent magnetic powders are potentially important material for rare-earth free magnets. We have prepared the nano-sized MnAl powders by plasma arc discharge and micron-sized MnAl powders by gas atomization. They showed good magnetic property, compared with that from conventional processes. $Nd_2Fe_{14}B$ powders with high coercivity of more than 10 kOe were successfully synthesized by adjusting R-D step, followed by precise washing system. It is considered that this process can be applied for the recycling of RE-elements extracted from ewaste including motors.

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Factors Influencing New Media Subscription Based on Multigroup Analysis of IPTV and DCTV

  • Kang, Sang-Ug;Park, Seungbum;Lee, Sangwon
    • ETRI Journal
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    • 제36권6호
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    • pp.1041-1050
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    • 2014
  • As the Internet Protocol TV (IPTV) service enters the broadcasting market, the competition intensifies. This paper explains the factors influencing new media subscription and their influential differences on IPTV and digital cable TV (DCTV). We use the information systems success model and gratification opportunity theory to develop our research model. We sample 621 people and collect their responses through web-based measuring software. Structural model analysis shows that the willingness to subscribe to a new broadcasting medium is influenced by three characteristics of the medium: media richness, interactivity, and video quality. Multigroup analysis reveals that motivation to use a medium partially differs between IPTV and DCTV. This research concludes that the IPTV service is not attractive enough to act as a substitute for the already existing DCTV. In addition, for the IPTV service to proliferate, its business model should be promoted with new and differentiated revenue structures and services. The managerial implications in this study help new media businesses set business goals and product functionality, and allocate resources for the continued diffusion of IPTV.

오피니언 마이닝을 통한 스마트 워치 출시 전후 소비자 반응 분석 (Comparing Customer Reactions Before and After of a Smart Watch Release through Opinion Mining)

  • 이종호;박희준
    • 한국빅데이터학회지
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    • 제1권1호
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    • pp.1-7
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    • 2016
  • 인터넷의 확산으로 트위터와 같은 SNS가 확산되었고, 컴퓨터 처리 능력의 발달로 빅 데이터 처리가 가능해졌다. 본 연구에서는 현재 주목 받고 있는 기술인 스마트 워치에 대해 다루고 있으며 최근 출시되었던 삼성 갤럭시 기어 S2를 대상으로 연구를 진행하고 있다. 스마트 워치의 출시 전, 후에 게시되었던 트위터 데이터를 수집하여 실제 SNS 사용자들이 신제품 출시에 어떻게 반응하고 있으며 어떠한 다른 양상을 보이는지 분석한다. 분석을 통해 기업 실무자들에게 출시 전, 출시 후 각각에 마케팅에 대응하는 방법에 관한 가이드라인을 제공하며 본 연구에서 사용된 분석 프레임워크는 다른 분야 및 제품에서도 사용 가능한 연구 가이드라인이 된다.

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Removal of organic acid salts from 1,3-propanediol fermentation broth by electrodialysis

  • Wang, Xiao-Lin;Gong, Yan;Yu, Li-Xin;Tang, Yu;Liu, De-Hua
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.19-24
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    • 2004
  • ED method is employed to effectively remove the organic acid salts in actual PDO fermentation broth. The lower electrical potential is selected to avoid the serious membrane fouling so as to ensure a stable and durative desalination process. Under the selected operation conditions, about 90% of organic acids salts are removed from PDO fermentation broth successfully by ED process. To reduce the loss of PDO product due to the diffusion, the operation time should be considered carefully. And based on mass balance equation and irreversible thermodynamics approach, a mathematical model is developed to describe the desalination process of an aqueous solution containing neutral solute by ED method. While the influence of concentration polarization is reflected by decreasing the conductivity of membrane, the model is verified well to describe the ED processes under varied operation conditions. Through the model, ED process of actual PDO fermentation broth is simulated to get a suitable scope of initial concentration in concentrated compartment.

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Effect of CrN barrier on fuel-clad chemical interaction

  • Kim, Dongkyu;Lee, Kangsoo;Yoon, Young Soo
    • Nuclear Engineering and Technology
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    • 제50권5호
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    • pp.724-730
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    • 2018
  • Chromium and chromium nitride were selected as potential barriers to prevent fuel-clad chemical interaction (FCCI) between the cladding and the fuel material. In this study, ferritic/martensitic HT-9 steel and misch metal were used to simulate the reaction between the cladding and fuel fission product, respectively. Radio frequency magnetron sputtering was used to deposit Cr and CrN films onto the cladding, and the gas flow rates of argon and nitrogen were fixed at certain values for each sample to control the deposition rate and the crystal structure of the films. The samples were heated for 24 h at 933 K through the diffusion couple test, and considerable amount of interdiffusion (max. thickness: $550{\mu}m$) occurred at the interface between HT-9 and misch metal when the argon and nitrogen were used individually. The elemental contents of misch metal were detected at the HT-9 through energy dispersive X-ray spectroscopy due to the interdiffusion. However, the specimens that were sputtered by mixed gases (Ar and $N_2$) exhibited excellent resistance to FCCI. The thickness of these CrN films were only $4{\mu}m$, but these films effectively prevented the FCCI due to their high adhesion strength (frictional force ${\geq}1,200{\mu}m$) and dense columnar microstructures.

생강 페이스트의 저장 안정성 (Storage Stability of Ginger(Zingiber officinale Roscoe) Paste)

  • 조길석;장영상;신효선
    • 한국식품영양과학회지
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    • 제26권6호
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    • pp.1140-1146
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    • 1997
  • Storage stability of ginger paste product was investigated from the standpoint of the inhibition of nonenzymatic browning and loss of gingerol contents. For the experimentations, control, 0.04% of N-acetyl-L-cysteine in ginger paste(NAcCys), and combination treatment of NAcCys, 0.92 of water activity and 6.30 of pH in ginger paste (mixed treatment) were stored at 3$0^{\circ}C$ for 40 days and analyzed for browning and gingerol contents. In addition the changes in sugars, organic acids, ascorbic acids, amino acids, and sensory quality were determined. The results revealed that the mixed treatment agent was effective in preventing both nonenzymatic browning and loss of gingerol contents. The inhibition by combination treatment might be resulted from the control of radical formations by sulfhydryl groups of NAcCys and the increase of diffusion resistance in lower water activity. Browning development and total gingerol contents were found to be correlated to some physicochemical characteristics of ginger paste; that is, browning development to amino acid and color value in sensory evaluation, and total gingerol contents to flavor in sensory evaluation.

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Comparison of Bioleaching Kinetics of Spent Catalyst by Adapted and Unadapted Iron & Sulfur Oxidizing Bacteria - Effect of Pulp Density; Particle Size; Temperature

  • Pradhan, Debabrata;Kim, Dong-Jin;Ahn, Jong-Gwan;Gahan, Chandra Sekhar;Chung, Hun-Saeng;Lee, Seoung-Won
    • 대한금속재료학회지
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    • 제49권12호
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    • pp.956-966
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    • 2011
  • Bioleaching studies of metals from a spent catalyst were conducted using both adapted and unadapted bacterial cultures. The bacterium used in this experiment was Acidithiobacillus ferrooxidans. A comparison of the kinetics of leaching was made between the two cultures by varying the leaching parameters, including the pulp density, particle size and temperature. Both cultures showed similar effects with respect to the above parameters, but the leaching rates of all metals were higher with the adapted compared to the unadapted bacterial cultures. The leaching reactions were continued for 240 h in the case of the unadapted bacterial culture, but only for 40 h in the case of the adapted bacterial culture. The leaching reactions followed first order kinetics. In addition, the kinetics of leaching was concluded to be a diffusion control model; therefore, the product layers were impervious.

용매를 매체로 한 Hexanitrohexaazaisowurtzitane(HNIW)의 상전이 속도에 관한 연구 (Study on Solvent Mediated Phase Transformation Kinetics of Hexanitrohexaazaisowurtzitane(HNIW))

  • 김준형;임유진
    • 한국추진공학회지
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    • 제4권4호
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    • pp.9-17
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    • 2000
  • 준안정상인 $\beta$형 HNIW의 용해와 안정상인 $\varepsilon$형 HNIW의 성장 특성을 고려한 모델식을 물질수지와 한께 계산하는 방법으로 결정성장 속도와 용해 속도를 계산하였다. 제시된 모델은 용액을 매체로 하여 진행되는 $\beta$$\longrightarrow$$\varepsilon$전이 현상에 대한 속도론적 데이터를 모사 하는데 유용하였다. 2 단 모델을 이용한 유효 인수로부터, 격정성장 과정에서 표면 축적 단계의 영향은 작으며, 확산 의존성은 ethyl acetate와 chloroform의 혼합 용매 중 chloroform의 함량이 증가함에 따라 감소함을 보였다. 이들 속도론 적 계수들을 이용한 수치모사를 통하여 $\varepsilon$-HNIW의 입자 크기를 예측하는 것이 가능하였다.

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용탕조건에 따른 상용 차량용 어댑터 하우징의 열적특성에 관한 연구 (A Study on Thermal Characteristics of Adaptor Housing for Commercial Vehicles according to Molten Metal Condition)

  • 고동국;명순식;강병용;김민수
    • 한국기계기술학회지
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    • 제20권6호
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    • pp.745-750
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    • 2018
  • In this study, the thermal behavior of adaptor housing was analyzed by the numerical method. The boundary conditions used to die casting process were the temperature of molten metal and injection time. As the temperature of the molten metal increased, the tensile strength of the product decreased by the blow hole generated in the molten metal, and the decreasing tendency was gradually decreased. As the injection time of the molten metal increased, the heat flux rose, but the degree of the increase was very small. So, the injection time of the molten metal had little effect on the thermal behavior and diffusion of the adapter housing. As a result, the heat of the molten metal was transferred into the housing and the thermal behavior spread widely.