• 환경생물
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• 제34권1호
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• pp.18-29
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• 2016

김 양식을 하고 있는 해역의 물리 화학적인 해양환경 특성, 식물플랑크톤 색소 조성과 농도, 식물플랑크톤 및 방사무늬김의 일차 생산력을 2014년 3월에 김 양식이 이루어지고 있는 만호해역에서 조사를 하였다. 수온은 $9.1{\sim}9.6^{\circ}C$, 염분은 32.5~33.1이었고, 투명도는 높은 탁도로 인하여 유광층이 낮아져 0.7~1.5 m를 보였다. 수층의 용존 무기질소, 용존 무기인 및 규산 규소 각각의 농도는 $3.59{\sim}5.73{\mu}M$, $0.16{\sim}0.41{\mu}M$, $12.41{\sim}13.94{\mu}M$이었다. 클로로필 a 농도는 $0.51{\sim}1.25{\mu}g\;L^{-1}$이었고, $0.7{\sim}20{\mu}m$ 범위의 nanoplankton의 클로로필 a 농도가 58%를 차지하였다. 규조류의 marker 색소인 fucoxanthin의 농도는 $0.51{\sim}1.25{\mu}g\;L^{-1}$로서 전 정점에서 높은 값이었고, $20{\sim}200{\mu}m$ 범위의 fucoxanthin이 64%를 차지하였다. 식물플랑크톤에 의한 일차 생산력은 $57.72{\pm}4.67(51.05{\sim}66.71)mg\;C\;m^{-2}\;d^{-1}$이었고, $0.7{\sim}20{\mu}m$ 범위의 nanoplankton이 76.9%를 차지하였으며, 면적을 고려한 일차 생산력은 $11,337kg\;C\;d^{-1}$이었다. 방사무늬김에 의한 평균 일차 생산력은 $1,926{\pm}192(1,102{\sim}2,597)mg\;C\;m^{-2}d^{-1}$이었고, 면적을 고려한 일차 생산력은 $39,295kg\;C\;d^{-1}$이었다. 식물플랑크톤과 방사무늬김에 의한 일차 생산력을 토대로 계산된 만호해역의 일차 생산력은 $50,632kg\;C\;d^{-1}$로 나타났다. 만호해역의 식물플랑크톤에 의한 일차 생산력이 다른 해역보다 낮고, 김의 일차 생산력이 식물플랑크톤의 일차 생산력보다 약 3.5배 높았다.

• 한국입자에어로졸학회지
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• 제9권1호
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• pp.7-21
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• 2013

Twelve-hour size-resolved atmospheric aerosols were measured to determine size distributions of water-soluble organic carbon(WSOC) during daytime and nighttime, and to investigate sources and formation pathways of WSOC in individual particle size classes. Mass, WSOC, ${NO_3}^-$, $K^+$, and $Cl^-$ at day and night showed mostly bimodal size distributions, peaking at the size range of $0.32-0.55{\mu}m$(condensation mode) and $3.1-6.2{\mu}m$(coarse mode), respectively, with a predominant condensation mode and a minor coarse mode. While ${NH_4}^+$ and ${SO_4}^{2-}$ showed unimodal size distributions which peaked between 0.32 and $0.55{\mu}m$. WSOC was enriched into nuclei mode particles(< $0.1{\mu}m$) based on the WSOC-to-mass and WSOC-to-water soluble species ratios. The sources and formation mechanisms of WSOC were inferred in reference to the size distribution characteristics of inorganic species(${SO_4}^{2-}$, ${NO_3}^-$, $K^+$, $Ca^{2+}$, $Na^+$, and $Cl^-$) and carbon monoxide. Nuclei mode WSOC was likely associated with primary combustion sources during daytime and nighttime. Among significant sources contributing to the condensation mode WSOC were homogeneous gas-phase oxidation of VOCs, primary combustion emissions, and fresh(or slightly aged) biomass burning aerosols. The droplet mode WSOC could be attributed to aqueous oxidation of VOCs in clouds, cloud-processed biomass burning aerosols, and small contributions from primary combustion sources. From the correlations between WSOC and soil-related particles, and between WSOC and sea-salt particles, it is suggested that the coarse mode WSOC during daytime is likely to condense on the soil-related particles($K^+$ and $Ca^{2+}$), while the WSOC in the coarse fraction during nighttime is likely associated with the sea-salt particles($Na^+$).

• 한국물환경학회지
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• 제21권2호
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• pp.147-152
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• 2005

Fermentation efficiencies of organic wastes from the variety of sources were evaluated based on the production of total volatile acids(TVA) in batch reactor. Mixing and pH were not significant factors in producing TVA from the organic wastes. After a 10-day fermentation, final TVA concentrations in piggery, cattle, poultry, and primary settled sludge of domestic wastewater were 8,900, 2,900, 7,370 and 1,630 mg/L, respectively. The pH of organic wastes was decreased from neutral to 5.7. The ratio of TVA to $NH_4{^+}-N$ produced from the animal waste ranged from 11.5 to 30.1, whereas, that in the primary settled sludge of domestic wastewater, was 5.4. Possibility of fermented organic wastes as the electron donors for denitrification in the activated sludge was investigated. In both acclimated and nonacclimated activated sludge, higher denitrification rates were obtained with fermented piggery sludge added than with either methanol or acetate added. The fermented organic acids derived from the primary settled sludge gave the higher denitrification rate ($4.2mg\;NO_3-N/g\;vss{\cdot}hr$) in the acclimated activated sludge. Denitrification rate was $1.5mg\;NO_3-N/g\;vss{\cdot}hr$ in the nonacclimated sludge with the fermented acids from the primary settled sludge of domestic wastewater added.

• 한국물환경학회지
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• 제23권1호
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• pp.19-26
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• 2007

The lab-scale BNR processes fed with Municipal Wastewater Before or After Primary Clarifier (MWBPC or MWAPC) were operated to observe the behavior of particle organic matter in terms of nitrification and denitrification efficiency. As a result of the fractionation of the COD from MWBPC or MWAPC using an aerobic respirometric serum bottle reactor, the total mass of biodegradable organic matter from MWBPC is about 52% greater than the mass from MWAPC. Batch reactors were operated to observe the effect of the Particulate Organic Matter (POM) on substrate utilization for denitrification. Although the consumption of POM for denitrification was observed, the increment of the Specific Denitrification Rate (SDNR) was not great. In terms of the effect of POM on nitrification at different HRTs, activate sludge reactors were operated to determine the optimal HRT when MWBPC and MWAPC were fed relatively. All reactors showed a great organic matter removal efficiency. Reactors fed with MWAPC had obtained the nitrification efficiency above 90% when the HRT of 4 hr, at least, was maintained, while reactors fed with MWBPC had same efficiency when the HRT longer than 5 hr was kept. Three parallel $A^2/O$ systems fed with MWBPC or MWAPC relatively were operated to investigate the effects of POM on BNR processes with varying the HRT of an anoxic reactor. For all systems, the efficiency of organic matter removal and denitrification, respectively, was great and about the same. In case of denitrification efficiency, system with MWAPC had 1.5% lower than system with MWBPC at the same HRT of anoxic reactor of 2 hr, and the increasing the HRT of the anoxic reactor by 1 hr in systems fed with MWBPC resulted in a 3.5% increment. The denitrification rate was similar while the consumption of organic matter in systems fed with MWBPC was higher than system fed with MWBPC. It suggests that POM in MWBPC was not be used significantly as a substrate for denitrification in system with the HRT of 3 hr of an anoxic reactor.

• Corrosion Science and Technology
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• 제11권4호
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• pp.141-150
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• 2012

Stress corrosion cracks in Alloy 600 compact tension specimens tested at $325^{\circ}C$ in a simulated primary water environment of pressurized water reactor were analyzed by analytical transmission electron microscopy and secondary ion mass spectroscopy (SIMS). From a fine-probe chemical analysis, oxygen was found on the grain boundary just ahead of the crack tip, and chromium oxides were precipitated on the crack tip and the grain boundary attacked by the oxygen diffusion, leaving a Cr/Fe depletion (or Ni enrichment) zone. The oxide layer inside the crack was revealed to consist of a double (inner and outer) layer. Chromium oxides existed in the inner layer, with NiO and (Ni,Cr) spinels in the outer layer. From the nano-SIMS analysis, oxygen was detected at the locations of intergranular chromium carbides ahead of the crack tip, which means that oxygen diffused into the grain boundary and oxidized the surfaces of the chromium carbides. The intergranular chromium carbide blunted the crack tip, thereby suppressing the crack propagation.

• Ocean and Polar Research
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• 제25권4호
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• pp.459-468
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• 2003

Annual variation of water qualities in the Shihwa Lake were observed 18 times from June 1996 to October 2001. We studied at the station of the upper streams and near the water gate of lake. After the flow of the outer seawater through the water gate, the surface salinity in Shihwa Lake increased to the range of 25-30 psu in both stations after October 1998. Due to the declination of the salinity differences between the surface and the bottom water, the pycnocline in which had existed until 1997 has weakened, and made the water column mix vertically. This led to the improvement of anoxic/hypoxic environment at bottom waters after April 1998. However, despite the continuous flow of the outer seawater, the concentrations of chlorophyll-a at surface layer were varied from $2{\mu}g/l\;to\;60{\mu}g/l$, and these values indicated the eutrophication. The following organic matter load was greatly influencing the surface layer's COD concentration. During the rainy season, the salinity at the surface layer to the below 15 psu resulting in stratification between the surface and bottom layer. Organic matters that were provided from the surface layer to the bottom layer due to active primary production in the year exhausted dissolved oxygen at the bottom layer, and the bulks of organic matters at bottom gave rise to hypoxic or anoxic environment. It was observed that the enrichment of ammonia and phosphate were main factors to worsen the water quality of the Shihwa Lake. The results of examining the annual variations in Shiwha Lake through principal component analysis shown that water characteristics in the rainy season were similar with those before input of outer sea water.

• 한국물환경학회지
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• 제29권1호
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• pp.19-28
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• 2013

Artificial neural networks were used for time series modelling of algal dynamics of whole year and by season at the Paldang dam station (confluence area). The modelling was based on comprehensive weekly water quality data from 1997 to 2004 at the Paldang dam station. The results of validation of seasonal models showed that the timing and magnitude of the observed chlorophyll a concentration was predicted better, compared with the ANN model for whole year. Internal weightings of the inputs in trained neural networks were obtained by sensitivity analysis for identification of the primary driving mechanisms in the system dynamics. pH, COD, TP determined most the dynamics of chlorophyll a, although these inputs were not the real driving variable for algal growth. Short-term prediction models that perform one or two weeks ahead predictions of chlorophyll a concentration were designed for the application of Harmful Algal Alert System in Lake Paldang. Short-term-ahead ANN models showed the possibilities of application of Harmful Algal Alert System after increasing ANN model's performance.

• 한국해양환경ㆍ에너지학회지
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• 제1권2호
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• pp.96-108
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• 1998

대표적인 부영양화 해역인 일본의 뢰호내해를 대상으로 하여 해수ㆍ저질문의 욕존 산소와 영양염의 수수과정을 표현할 수ㆍ저질예측모델을 개발하여, 해역의 유입부하량과 수질의 응답특성, 부하량삭감의 영향해석 및 유입부하량과 수산자원의 관계 해석을 통하여 부영양화 해역의 수질관리방안에 대하여 연구하였다. 부하에 대응한 수질의 장기예측결과, 부하량과 수질의 응답특성이 해역에 따라 다르게 나타난다. 적상부하량의 간역추산방법으로서 인접해역의 부하영향 및 기여율을 포함한 부하삭감후의 수질예측에 대한 개산식을 제안하였다. 부하량 삭감효과의 수직계산결과 인(P) 뿐만 아니라 질소(N)의 부하삭감의 영향이 크게 기여함을 보였다. 유입부하량과 수산자원의 관계를 수질을 매개로 검토한 바, 뢰호내해와 같은 부영양화 해역에서는 유입부하량의 증가는 1차생산량의 증가에 반영되지만 2차생산 이후의 전송효율에도 한도가 있는 것으로 나타났다.

• 환경위생공학
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• 제3권1호
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• pp.27-39
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• 1988

This investigation was carried out to evaluate the removal effect of biological contaminants for the municipal sewage treatment process at Cheonggye Cheon terminal plant which in the first plant for municipal sewage treatment in Seoul area. It was conducted in raw influent, primary treatment water and secondary treatment water from September, 1986 to July, 1987. The results were as follow; 1, The primary treatment could eliminate microbials for $65.38\%$ of total bacteria, $64.35\%$ of total coliform, $62.16\%$ of fecal coliform $69.48\%$ of pseudomonas and $64.70\%$ of fecal streptococci in averages for a year respectively. 2. The secondary treatment could eliminate microbials for $97.50\%$ of total bacteria, $97.30\%$of total coliform, $95.95\%$ of fecal coliform, $97.00\%$ of pseudomonas and $96.53\%$ of fecal streptococci in average for a year respectively. 3. In the detect rate of pathogenic agent, salmonella spp was decreased $12.5\%$ to $4.2\%$ in primary treatment and it was not detected in secondary treatment, shigella spp was detected $4.2\%$ in influent water but it was not detected in primary and secondary treatment. 4. In the seasonal variation of treatment effect, the removal of summer was the highest, and the removal of all item in winter was lower than the other seasons. 5. There was significant correlation between water temperature and microbal all items (P<0.05) $NH_3-N$ and Microbal items (P< 0.01) at raw water.

• 한국물환경학회지
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• 제25권2호
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• pp.295-305
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• 2009

The purpose of this study was to understand of water quality characteristics of lake Paldang, especially at a certain representative site, right in front of Paldang dam ($P_2$ site) and to propose the directions of water quality management of lake Paldang. Water characteristics at $P_2$ site was investigated by principle components analysis and the Pearson correlation coefficient analysis. Also, seasonality was identified by the Kruskal-Wallis test and long term trend of nutrients and chlorophyll-a was analyzed by seasonal decomposition method at lake Paldang statistically. The primary factor affecting on water quality at $P_2$ site was identified as nutrients, while physical parameters, such as rainfall and inflow rate were also important factors. At the result of linear regression analysis particulate organic phosphorus (POP) vs total phosphorus (TP) showed very high correlation of 0.78. TP loading was increased annually from 1995 to 2006. Chlorophyll-a and nutrients show seasonality at $P_2$ site. Long term trend of Chlorophyll-a was increased by increase of TP at lake Paldang.