• 한국세라믹학회지
• /
• 제39권4호
• /
• pp.420-426
• /
• 2002

가열가수분해반응에 의하여 제조된 구형의 $ZrO_2$ 겔을 수열결정화시켜 순수한 $ZrO_2$ 분말과 $Y2_O_3$, CaO 등 상안정화제가 도핑된 $ZrO_2$ 분말을 합성하였다. 합성된 $ZrO_2$ 결정분말들은 평균 10nm 크기의 일차 입자들로 구성된 이차입자들이었다. 이차입자의 평균 크기는 $0.4{\mu}m$였고, 수열결정화과정에서 겔의 구형 형상이 그대로 유지되었으며 일차 입자들 사이에는 약한 응집으로 존재하였다. 입자모양, 크기, 상분율, 도핑된 분율 등을 SEM, TEM, XRD, ICP로 연구하였고 구형 겔의 수열결정화기구를 논의하였다.

• 한국세라믹학회지
• /
• 제50권6호
• /
• pp.434-438
• /
• 2013

Monodispersed 3Y-$ZrO_2$ spherical agglomerates were synthesized by thermal hydrolysis process followed by crystallization processes (hydrothermal treatment and calcination). The crystallization process affected the properties of the final particles, such as the primary particle size, the agglomeration state, and the fraction of $ZrO_2$ monoclinic phase. The hydrothermal treated spherical particles were porous microstructures (weak agglomerates) composed of small primary particles with a size of 14 nm, but the calcined spherical particles had a dense microstructure due to the hard aggregation between primary particles. While the calcined particles had a low green density due to the hard aggregation, hydrothermal treated ones were soft agglomerates and had a deflection point at 50 MPa due to the rearrangement of secondary spherical particles and the filling of the interstices with the primary particles. Finally, the green density of hydrothermally treated $ZrO_2$ particles was 58% at 200 MPa.

• 폴리머
• /
• 제36권3호
• /
• pp.332-337
• /
• 2012

본 연구는 약물의 용해도에 따른 서방성 용출 거동의 특성을 파악하기 위해 수행되었으며, 이에 따라 고분자의 입도에 따른 염산벤라팍신과 카바마제핀의 정제를 제조하였다. 사용된 고분자는 경구를 통한 서방성 약물전달 시스템 설계에 가장 널리 사용되는 히드록시 프로필 메틸셀룰로오스(HPMC)이며, HPMC의 입도 분포에 따른 팽윤 속도의 차이는 중요한 특성으로 약물의 용출에 큰 영향을 미친다. HPMC 입도에 따른 정제 표면을 분석하기 위해 SEM을 사용하였으며, 결정학적 특성을 파악하기 위해 DSC를 이용하여 분석하였고, 용출 특성의 주요 메카니즘을 파악하기 위해 용출 모델식을 적용하였다. 본 연구를 통해 약물의 용해도 및 HPMC의 입도에 따라 약물의 용출 거동을 조절할 수 있었다.

• 한국세라믹학회지
• /
• 제42권11호
• /
• pp.722-728
• /
• 2005

A wet-chemical route was utilized to obtain nanosized crystalline goethite ($\alpha$-FeOOH) particle, which was known as an oxidation catalyst in reducing carbon monoxide (CO) and dioxine during incineration. A cost-effective $FeSO_4{\cdot}7H_2O$ was used as starting raw material and a successive process of hydrolysis-oxidation was utilized as synthetic method. The effects of the initial $Fe^{2+}$ concentration, hydrolysis time and oxidation period on the crystalline phase and particle characteristics were systematically investigated by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and BET analyses. It was found that the spindle-shaped crystalline $\alpha$-FeOOH particle with the width of 70 nm and the length of 200 nm could be obtained successfully when the initial concentration of 1.5 M, hydrolysis time of 4h, and oxidation period of 10 h, respectively. In addition, it was observed that the spindle-shaped $\alpha$-FeOOH particle consisted of nano-sized primary crystallites of $30\~50\;nm$, which were de-agglomerated into individual particle and successively re­agglomerated into spherical or irregular-shaped agglomerates beyond certain periods in the hydrolysis and oxidation process.

• 한국수학사학회지
• /
• 제18권4호
• /
• pp.49-66
• /
• 2005

유한요소법(Finite Element Methods)은 지난 수십 년 동안 다양한 공학문제를 해석하는 주요 수치해석기법으로서, 지속적으로 연구$\cdot$개발되어 오늘에 이르고 있다. 그러나, 유한요소법은 계산을 위하여 요소망을 구성해야 하고 일부의 문제에 대하여서는 요소망을 재구성하는 등 특별한 처리기법과 계산의 소요가 필요하다. 이와같은 단점을 극복하기 위하여 무요소법(Meshfree Methods)이라 불리우는 일단의 수치해석 기법들이 고안되었다. 무요소법은 요소를 사용하지 않고 절점(node)만을 이용하여 함수를 근사하는 수치해석기법이다. 본 논문에서는 무요소법이 고안된 배경과 그 연산구조를 소개하고 무요소법의 대표적인 방법들인 Smoothed Particle Hydrodynamics(SPH)방법, 무요소 갤러킨 방법(Meshfree Galerkin Methods) 그리고 무요소 선점법(Meshfree Point Collocation Methods)의 기본 개념과 이들 수치해석기법의 방법론을 알아본다. 그리고 이들 방법의 장단점과 그 적용 예를 통하여 무요소 계산법의 유효함을 보인다.

• Ocean and Polar Research
• /
• 제23권4호
• /
• pp.395-400
• /
• 2001

A time-series sediment trap was deployed at 1,034 m water depth in the eastern Bransfield Strait from December 25, 1998 to December 24, 1999. About 99 % of total mass fluxes were observed during the austral summer and fall (January, February, and March). The annual total mass flux was $49.2g\;m^{-2}$. Biogenic materials including biogenic silica, organic matter, and carbonate accounted for about 67% of total particle flux, and lithogenic materials contributed about 29%. Biogenic silica was the most dominant (42% of the total flux) in these components. The next most important biogenic component was organic matter, comprising 24% of total mass flux. Calcium carbonate contributed a small fraction of total mass flux, only 0.6%. The annual organic carbon flux was $5.2g\;C\;m^{-2}$ at 1,034m water depth. The annual primary production was estimated to be $21.6g\;C\;m^{-2}$ at the sediment trap site, which seems to be highly underestimated. About 5.5% of the surface water production of organic carbon sinks below 1,034m water depth.

• Environmental Engineering Research
• /
• 제12권2호
• /
• pp.72-80
• /
• 2007

Experiments were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted VOCs. The identified primary constituents emitted from the car air freshener in this study were $\alpha$-pinene, $\beta$-pinene, $\rho$-cymene and limonene. Formation of ultra-fine particles (4.4-160 nm) was observed when ozone was injected into the chamber containing emitted monoterpenes from the air freshener. Particle number concentrations, particle mass concentrations, and surface concentrations were measured in time dependent experiments to describe the particle formation and growth within the chamber. The irritating secondary gaseous products formed during the ozone-initiated reactions include formaldehyde, acetaldehyde, acrolein, acetone, and propionaldehyde. Ozone concentration (50 and 100 ppb) and temperature (30 and $40^{\circ}C$) significantly affect the formation of particles and gaseous products during the ozone-initiated reactions. The results obtained in this study provided an insight on the potential exposure of particles and irritating secondary products formed during the ozone-initiated reaction to passengers in confined spaces.

• 한국분말재료학회지
• /
• 제24권6호
• /
• pp.444-449
• /
• 2017

Aluminum nitride (AlN) powder specimens are treated by high-energy bead milling and then sintered at various temperatures. Depending on the solvent and milling time, the oxygen content in the AlN powder varies significantly. When isopropyl alcohol is used, the oxygen content increases with the milling time. In contrast, hexane is very effective at suppressing the oxygen content increase in the AlN powder, although severe particle sedimentation after the milling process is observed in the AlN slurry. With an increase in the milling time, the primary particle size remains nearly constant, but the particle agglomeration is reduced. After spark plasma sintering at $1400^{\circ}C$, the second crystalline phase changes to compounds containing more $Al_2O_3$ when the AlN raw material with an increased milling time is used. When the sintering temperature is decreased from $1750^{\circ}C$ to $1400^{\circ}C$, the DC resistivity increases by approximately two orders of magnitude, which implies that controlling the sintering temperature is a very effective way to improve the DC resistivity of AlN ceramics.

• 대한화장품학회지
• /
• 제24권3호
• /
• pp.73-80
• /
• 1998

This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

• 천문학회보
• /
• 제39권1호
• /
• pp.29-29
• /
• 2014

A fundamental problem in space physics is to explain the origin of energetic charged particles in space close to the Earth and the significant temporal variations of their flux. The particles are primarily electrons and protons although energetic heavy ions such as O+ are sometimes non-negligible. By "energetic" we mean a rather broad energy range of particles from a few tens of keV to well above MeV. Drastic variations of the particle fluxes (by >3 orders of magnitude) occur over both a short time scale like a few minutes and a long time scale like the 11-year sunspot cycle. In this talk I will focus on relativistic energy electrons (~MeV) trapped within the Earth's magnetosphere. They are a primary element of the space weather since they can cause damage to satellites, so often called "killer electrons". Considering that the source particles in both the solar wind and the ionosphere are relatively cold (~eV), the quasi-permanent existence of these very energetic particles close to the Earth has been a surprise to space physicists for decades. Complex electromagnetic processes such as wave-particle interactions within the magnetosphere are believed to play a major role in generating these killer electrons. While detailed physics remains an active research area, for this lecture I will introduce a synthesized picture of how solar activities are related to wave-particle interaction physics inside the magnetosphere. This can be applied to other astrophysical systems.