• 제목/요약/키워드: Primary mineral

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Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.37-43
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    • 2005
  • [ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

Dietary Intake Ratios of Calcium-to-Phosphorus and Sodium-to-Potassium Are Associated with Serum Lipid Levels in Healthy Korean Adults

  • Bu, So-Young;Kang, Myung-Hwa;Kim, Eun-Jin;Choi, Mi-Kyeong
    • Preventive Nutrition and Food Science
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    • v.17 no.2
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    • pp.93-100
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    • 2012
  • The purpose of this study was to identify food sources for major minerals such as calcium (Ca), phosphorus (P), sodium (Na) and potassium (K), and to evaluate the relationship between dietary intake of these minerals and serum lipids in healthy Korean adults. A total of 132 healthy men and women completed a physical examination and dietary record and provided blood samples for lipid profile analysis. Results showed the following daily average mineral intakes: 373.4 mg of calcium, 806.0 mg of phosphorous, 3685.8 mg of sodium, and 1938.3 mg of potassium. The calcium-to-phosphorus and sodium-to-potassium ratio was about 0.5 and 2.0, respectively. The primary sources for each mineral were: vegetables (24.9%) and fishes (19.0%) for calcium, grains (31.4%) for phosphorus, seasonings (41.6%) and vegetables (27.0%) for sodium, and vegetables (30.6%) and grains (18.5%) for potassium. The correlation analysis, which has been adjusted for age, gender, total food consumption, and energy intake, showed significantly positive correlations between Ca/P and serum HDL cholesterol levels, between Na intake and the level of serum total cholesterol, and between Na/K and the level of serum cholesterol and LDL cholesterol. Our data indicates that the level of mineral consumption partially contributes to serum lipid profiles and that a diet consisting of a low Ca/P ratio and a high Na/K ratio may have negative impacts on lipid metabolism.

Effect of Primarily Solidified Structure on the Microstructure and the Mechanical Properties of High Cr White Iron (고크롬 백주철의 미세조직과 기계적 특성에 미치는 초기응고 조직의 영향)

  • Jo, Hyun-Wook;Do, Jeong-Hyeon;Jo, Won-Je;Chung, Hyun-Deuk;Lee, Je-Hyun;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.178-184
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    • 2015
  • Due to excellent abrasion resistance the high-chrome white irons are widely used in mining and mineral industries. Minor variation of carbon content in 28% chrome white iron resulted in difference in primarily solidified microstructure. Sub-eutectic (hypoeutectic) composition led to formation of primarily solidified dendrites. Formation of primarily solidified dendrites which were supersaturated with carbon and chrome also caused precipitation of fine secondary carbides that are different from relatively large plate type $M_7C_3$ carbides in the eutectic structure. Small portion of primarily solidified dendrite expected to contribute significantly to the improvement of abrasion resistance of the white iron because the dendrites provided mechanical support to carbides. The relative fraction of primary dendrite increased with reduction of carbon content from the eutectic composition. The increased fraction of primary dendrite increased hardness value of the white irons.

The effect of blast-induced vibration on the stability of underground water-sealed gas storage caverns

  • Zhou, Yuchun;Wu, Li;Li, Jialong;Yuan, Qing
    • Geosystem Engineering
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    • v.21 no.6
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    • pp.326-334
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    • 2018
  • Underground water-sealed gas storage caverns have become the primary method for strategic storage of LPG. Previous studies of excavation blasting effects on large-scale underground water-sealed gas storage caverns are rare at home and abroad. In this paper, the blasting excavation for underground water-sealed propane storage caverns in Yantai was introduced and field tests of blasting vibration were carried out. Field test data showed that the horizontal radial velocity had a major controlling effect in the blasting vibration and frequencies would not cause the vibration velocity concentration effects. In terms of the influence of blasting vibration on adjacent caverns, the dynamic finite element model in LS-DYNA soft was established, whose reliability was verified by field test data. The numerical results indicated the near-blasting side was primary zone for the structural failure and tensile failure tended to occur in the middle of the curved wall on the near-blasting side. Meanwhile, the safety criterions for adjacent caverns based on stress wave theory and according to statistic relationship between peak effective tensile stress and peak particle velocities were obtained, respectively. Finally, with Safety Regulations for Blasting in China (GB6722-2014) taken into account, a final safety criterion was proposed.

Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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MINERAL PROCESSING and COPPER EXRACTIVE METALLURGY Complete Metal Recovery

  • Kim, J.Y.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.22-34
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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Carcass Composition and Cuts of Bulls and Steers Fed with Three Concentrate Levels in the Diets

  • do Prado, Ivanor Nunes;Passetti, Rodrigo Augusto Cortez;Rivaroli, Dayane Cristina;Ornaghi, Mariana Garcia;de Souza, Kennyson Alves;Carvalho, Camila Barbosa;Perotto, Daniel;Moletta, Jose Luiz
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.9
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    • pp.1309-1316
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    • 2015
  • In this paper, weight, carcass dressing, weights of the primary cuts, weights of the physical components of the primary cuts, and weights of the main commercial cuts of 66 $Purun{\tilde{a}}$ animals, of which 33 were bulls and 33 were steers were evaluated. These animals, with an average age of 19 months at the beginning of the experiment, were finished in a feedlot system during 116 days, and were fed with diets containing three levels of concentrate (0.8%, 1.1%, and 1.4% of body weight). The concentrate was formulated with 25% soybean meal, 73% ground corn grain, 1% of a mineral mix, and 1% of limestone. The interaction between sexual groups and the concentrate level was not significant for any of the variables. Likewise, no effect of the concentrate level was detected on the same variable traits. The bulls demonstrated higher hot carcass weights (265.1 vs 221.7 kg) and a higher proportion of forequarter (38.4% vs 36.1%) however the steers presented with higher proportions of side (19.7% vs 18.5%) and hindquarter (44.2% vs 43.1%). The bulls produced higher yields of muscle in the three primary cuts, there by resulting in higher yields of edible portions of the carcass. The bulls also produced higher weights of tenderloin, knuckle, topside, flat, eye round, rump, and rump cover. The finishing of young bulls in feedlot is to be recommended, since the animals produce carcasses with higher amounts of edible meat and higher yields of commercial cuts, thus allowing for a better price for the carcass. Low concentrate level could be used due to the lower cost of production for farmers.

Status and Survey of Pulp Treatment by Korean Pediatric Dentists (한국 소아치과의사의 치수치료 술식에 대한 실태조사)

  • Bae, Jee Soo;Kim, Ik-Hwan;Choi, Hyung-Jun;Song, Je Seon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.47 no.3
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    • pp.277-292
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    • 2020
  • The pulp treatment of primary and immature teeth in the children and adolescents is affected by the environment of the patients, clinical careers and dentists performing the techniques, as well as clinical modalities and pulpal diagnosis. The purpose of this study was to investigate the current status of pulp treatment performed in real clinical practice, as well as the reasons behind the choice of treatment methods. The study was conducted on a total of 153 members of the Korean Academy of Pediatric Dentistry, and statistical data from the Health Insurance Review and Assessment Service (HIRA) from 2010 to 2018 were analyzed together. Both the survey results and the statistics from the HIRA showed that 1-visit pulpectomies of primary teeth were most common, and the frequency of the use of the Ni-Ti file was increased in children with primary or mixed-dentition. In the treatment of immature permanent teeth, regenerative endodontic treatment by individual dentists was found to be less frequent than in university hospitals.

Assessment of Anthropometry, Nutritional Compositions and Contribution of School Meals to the Daily Nutrient Requirements of Primary School Children from Rural Communities

  • Ijarotimi O. Steve;Omotayo S. Amos
    • Journal of Community Nutrition
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    • v.8 no.4
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    • pp.171-176
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    • 2006
  • The study aims to evaluate the nutritional status and influence of school meal intakes on RDA of primary school children in Akure community, Ondo State, Nigeria. A cross-sectional study was conducted among 728 primary school children aged between 6 and 15 years. Data were collected using interviewer-administered semi-structured questionnaires. The questionnaires collect information on demographic characteristics and home dietary intake of the subjects. The heights and weights of the children were measured using a standard procedure and height-far-age and weight-far-height z-score were determined. The children's school meal intakes were weighed for 4 days and samples were collected for chemical analysis. The results showed that 37.8% of the children were not wasted, 35.7% mildly wasted, 18.7% moderately wasted and 7.8% severely wasted. Also, 57.8% were not stunted, 29.3% mildly stunted, 11.0% moderately stunted and 1.9% were severely stunted. The subjects' home dietary intakes showed that 73.6% ate starchy food only, 19.9% ate protein based food, while 11.6% and 11.5% consumed fruits/vegetables and snacks to complement home meals respectively. The chemical composition of school meal was energy 379 - 413kcal, moisture content 5.9 -7.3g, carbohydrate 56.5 - 69.4g, fat 4.6 - 12.7g, crude fiber 0.1 - 2.4g, ash content 3.6 - 8.5g and protein 14.9 - 22.3g. The mineral contents were calcium 45.9 - 59.2mg, sodium 5004 - 59.6mg, zinc 2.3 - 3.1mg, magnesium 55.0 - 61.6mg, potassium 55.3 - 69.3mg, copper 0.2 - 0.3 mg, while others 1.3 - 1.9mg, 243 - 659mg and 831 - 9,510mg were iron, phosphorous and vitamin-A respectively. The contribution of school meals to subjects' RDA was within 2.9% and 1540%. In summary, school meal intake contributed positively to the RDA and nutritional status of the school children.

Gene Expression of Exposure to Mineral Trioxide Aggregate(MTA) on Dental Pulp Cells (Mineral Trioxide Aggregate(MTA)에 의한 치수세포의 유전자 발현변화)

  • Choi, Yu-Seok;Lee, Nan-Young;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.1
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    • pp.30-38
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    • 2008
  • Dental pulp cells are assumed to possess the capacity to elaborate both bone and dentin matrix under the pathological conditions following tooth injury. The purpose of this study is to examine the effects of mineral trioxide aggregate (MTA) on various gene expression regarding dentinogenesis and cell viability assay in cultured primary human dental pulp cells. The author also examined the effects of this material on cellular alkaline phosphatase activity as a potential indicator of dentinogenesis. For gene expression on MTA, reverse transcriptase polymerase chain reaction was performed using primer sets of glyceraldehyde-3-phosphate dehydrogenase, type I collagen, alkaline phosphatase(ALP), osteonectin, and dentin sialoprotein after 2 and 4 days. Cell viability assay showed that the proportion of MTA-treated pulp cells which had been exposed for 5 days to MTA was higher than that of the control cells. Among the genes investigated in this study, ALP and osteonectin(SPARC) were increased in MTA treated group than in control. These findings suggest that this dental pulp culture system may be useful in the future as a model for studying the mechanisms underlying dentin regeneration after the treatment with MTA. Exposure to MTA material would not induce cytotoxic response in the dental pulp cells. In addition, MTA could influence the behavior of human pulp cells by increasing the ALP activity and SPARC synthesis.

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