• Korean Chemical Engineering Research
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• 제47권5호
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• pp.546-552
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• 2009

이번 연구에서는 밀배아유의 기능성 향상을 위해 고정화 효소를 이용한 밀배아유의 효소적 에탄올 반응을 수행했고, 효소적 에탄올 반응의 비가압조건과 가압조건을 중점적으로 비교 분석했다. 비가압조건 효소적 에탄올 반응 수행은 밀배아유와 99.9% 에탄올 혼합물에 두 가지 고정화 효소인 Lipozyme TL-IM과 Lipozyme RM-IM를 1~5 w%(밀배아 기준 무게비)로 25 ml 플라스크에 shaking machine 상에서 $40{\sim}70^{\circ}C$, 120 rpm 조건으로 실험을 수행했다. 가압조건상에서의 효소적 에탄올 반응 조건은 고정화 효소 2 w%, 반응 시간 24시간, 반응 온도 $40{\sim}60^{\circ}C$ 및 반응 압력 75, 100, 150, 200 bar으로 수행했다. 실험으로부터 회수된 sample은 트리글리세라이드의 분해 정도를 살펴보기 위해 모노-, 디-, 트리글리세라이드를 HPLC를 이용하여 분석했다. 밀배아유의 전반적인 전환율은 반응온도와 고정화 효소의 농도에 따라 증가했고, 최적 반응 조건은 가압조건 $50^{\circ}C$, 100 bar이었다.

• 한국수소및신에너지학회논문집
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• 제22권1호
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• pp.51-59
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• 2011

Sulfur-Iodine (SI) cycle, which thermochemically splits water to hydrogen and oxygen through three stages of Bunsen reaction, HI decomposition, and $H_2SO_4$ decomposition, seems a promising process to produce hydrogen massively. Among them, the decomposition of $H_2SO_4$ ($H_2SO_4=H_2O+SO_2+1/2O_2$) requires high temperature heat over $800^{\circ}C$ such as the heat from concentrated solar energy or a very high temperature gas-cooled nuclear reactor. Because of harsh reaction conditions of high temperature and pressure with extremely corrosive reactants and products, there have been scarce and limited number of data reported on the pressurized $H_2SO_4$ decomposition. This work focuses whether the $H_2SO_4$ decomposition can occur at high pressure in a noble-metal reactor, which possibly resists corrosive acidic chemicals and possesses catalytic activity for the reaction. Decomposition reactions were conducted in a Pt-lined tubular reactor without any other catalytic species at conditions of $800^{\circ}C$ to $900^{\circ}C$ and 0 bar (ambient pressure) to 10 bar with 95 wt% $H_2SO_4$. The Pt-lined reactor was found to endure the corrosive pressurized condition, and its inner surface successfully carried out a catalytic role in decomposing $H_2SO_4$ to $SO_2$ and $O_2$. This preliminary result has proposed the availability of noble metal-lined reactors for the high temperature, high pressure sulfuric acid decomposition.

• Journal of the Korean Wood Science and Technology
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• 제25권1호
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• pp.1-7
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• 1997

Kraft oak lignin and ricestraw lignin from acetosolve pulping were dissolved in 50/50 mixture of tetralin/m-cresol solvent. The dissolved lignin was reacted in the pressurized autoclave which was operating at $350{\sim}500^{\circ}C$ of reaction temperature and 10~20 atms of reaction pressure respectively_Hydrogen pressure of 60~80kg/$cm^2$ was exercising into the pressurized autoclave reactor to create thermochemical hydrogenolysis reaction. It was identified by GLC, GC-MS and HPLC that the alkyl-aryl-${\beta}$-O-4 ether bond of lignin was cleaved and degraded into various smaller molecules of aromatic compound such as phenols and cresols under the reaction conditions around $300^{\circ}C$ and 10 atms of reaction temoerature and pressure. Hydrogenolysis reaction of lignin compound which was done above $500^{\circ}C$ of reaction temperature and 20 atms of reaction pressure showed that the amount of aromatic compound such as phenols and cresols degraded from reactant lignin was decreasing with newly present and increasing water out of product mixtures. It was supposed that new aliphatic compound of high molecular weight hydrocarbon is composed due to higher reaction temperature and pressure of hydrogenolysis reaction such as $500^{\circ}C$ and 20 atms, even though it was almost impossible, to identify what kind of degraded products it was by HPLC.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.791-793
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• 2009

Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

• Tribology and Lubricants
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• 제33권6호
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• pp.309-314
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• 2017

This paper presents a theoretical investigation of the dynamic characteristics of externally pressurized air pad bearings with closed loop grooves. These grooves are made on the surface of bearings to reduce the number of supply holes so that manufacturing costs can be reduced. The semi-implicit method is applied to calculate the time varying pressure profile on the air bearing surface owing to the advantages of numerical stability and fast time tracing characteristics. The static pressure of the groove bearings is much higher than that without grooves, so the groove bearings can provide high load carrying capacity. The equation of motion considering vertical motion and tilting motion are also solved using the Runge-Kutta 4th order method. By combining the semi-implicit method and the Runge-Kutta method, fast calculations of the dynamic behavior of the air bearing can be achieved. The variations of bearing reaction force, air film reaction moment, height, and tilting angle are investigated for the step force input, which is 20% higher than the bearing reaction, when the nominal clearance is 6 mm. The effect of the groove width and the groove depth are investigated by calculating the dynamic behavior. The possibility of the air hammering with the depth of the groove is found and discussed.

• 한국연소학회지
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• 제21권4호
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• pp.23-29
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• 2016

Reactivity of gasification defined by bouardard reaction is critical parameter in efficiency of the gasifier. In this study, char reactivity of the gasification was derived from the experiments using the intrinsic reaction kinetics model. Pressurized wire mesh heating reactor (PWMR) can produce high temperature and high pressure conditions up to 50 atm and 1750 K, respectively and PWMR was designed to evaluate the intrinsic reaction kinetics of $CO_2$ gasification. In this study, Kideco and KCH (sub-bituminous Indonesian coal) were pulverized and converted into char. Experiments used the PWMR were conducted and the conditions of the temperature and pressure were 1373~1673 K, 1~40 atm. To distinguish the pressure effect from high pressurized condition, internal and external effectiveness factors were considered. Finally, the intrinsic kinetics of the Kideco and KCH coal char were derived from $n^{th}$ order reaction rate equations.

• 한국수소및신에너지학회논문집
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• 제23권4호
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• pp.337-345
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• 2012

To check effects of operating variables on reaction characteristics of WGS catalyst for SEWGS process, water gas shift reaction tests were carried out in a pressurized fluidized bed reactor using commercial WGS catalyst and sand(as a substitute for $CO_2$ absorbent) as bed materials. Simulated syngas(mixed with $N_2$) was used as a reactant gas. Operating temperature was $210^{\circ}C$ and operating pressure was 20 bar. WGS catalyst content, steam/CO ratio, gas velocity, and syngas concentration were considered as experimental variables. CO conversion increased as the catalyst content and steam/CO ratio increased. CO conversion at fluidized bed condition was higher than that of fixed bed condition. However, CO conversion were maintained almost same value within the fluidized bed condition. CO conversion decreased as the syngas concentration increased. The optimum operation condition was confirmed and long time water gas shift reaction test up to 24 hours at the optimum operating conditions was carried out.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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• pp.23-31
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• 1999

가압 조건하에서의 석탄가스화 특성을 규명하기 위해, 온도, 압력, 산소/석탄비, 수증기/석탄비 등을 변화시켜가며 로토탄(Sub A)에 대하여 PDTF(Pressurized drop tube furnace) 실험을 수행하였다. 실험결과, 상압 조건에서보다 가압조건에서의 가스화가 탄소 전환율과 냉가스효율의 측면에서 더 유리한 것으로 측정되었다. 최대의 냉가스효율을 보이는 산소/석탄비(무게기준)는 0.5∼0.7(g/g)로 측정되었고, 온도가 충분히 높은 경우에만 수증기/석탄비의 증가가 냉가스효율의 증가를 가져왔다. 압력이 증가할수록 열분해에 의한 탄소전환의 비중은 감소하고 대신 기고반응(heterogeneous reaction)에 의한 탄소전환의 비중이 증가하였다.

• 약학회지
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• 제27권3호
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• pp.245-247
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• 1983

In Bucherer-Berg's reaction of $\alpha$-piperidinoacetophenone with KCN and ($NH_{4})_{2}CO_{3}$ in dilute alcohol solution to form hydantoin, the expected 5-phenyl-5-piperidinomethylhydantoin was not formed. In this reaction $\alpha$-piperidinomethyl group was eliminated and 5-phenylhydantoin was obtained. According to GC/MS study of the reaction mixture, the one of the chromatograms, which has mole peak 124, was identified as a-piperidinoacetonitrile. Under the pressurized condition, diphenylhydantil was obtained instead of 5-phenylhydantoin, which might have dimerized to the former.

• Nuclear Engineering and Technology
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• 제29권5호
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• pp.375-384
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• 1997

Relative power density distributions of the Kori Unit 1 pressurized water reactor are calculated by Monte Carlo modeling with the MCNP code. The Kori Unit 1 core is modeled on a three-dimensional representation of the one-eighth of the reactor in-vessel component with reflective boundaries at 0 and 45 degrees. The axial core model is based on half core symmetry and is divided into four axial segments. Fission reaction density in each rod is calculated by following 100 cycles with 5,000 test neutrons in each cycle after starling with a localized neutron source and ten noncontributing settle cycles. Relative assembly power distributions are calculated from fission reaction densities of rods in assembly. After 100 cycle calculations, the system converges to a k value of 1.00039 $\geq$ 0.00084. Relative assembly power distribution is nearly the same with that of the Kori Unit 1 FSAR. Applicability of the full-scope Monte Carlo simulation in the power distribution calculation is examined by the relative root moan square error of 2.159%.