• Title/Summary/Keyword: Precipitation density

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Effect of Sigma Phase on Electrochemical Corrosion Characteristics of a Deposited Metal of ER2594 (ER2594 용착금속의 전기화학적 부식특성에 미치는 시그마상의 영향)

  • Jung, Byong-Ho;Kim, Si-Young;Seo, Gi-Jeong;Park, Joo-Young
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.75-81
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    • 2015
  • A deposited metal specimen of ER2594 which is a super duplex steel welding wire used to investigate the effect of sigma(${\sigma}$) phase on electrochemical corrosion characteristics was prepared by gas tungsten arc welding. Aging treatment was conducted for the specimen at the temperature range of $700^{\circ}C$ to $900^{\circ}C$ for 5 to 300 minutes after annealing at $1050^{\circ}C$. Corrosion current density has decreased a little with an increase of aging time over 60 minutes at $700^{\circ}C$ to $900^{\circ}C$ and the uniform corrosion of deposited metal had more influence on the precipitation of ferrite than the precipitation of sigma phase. Therefore, the precipitation of sigma phase did not have much effect on the uniform corrosion. Pitting potential representing pitting corrosion has shown decreasing tendency as the precipitation of sigma phase increased. The degree of sensitization representing intergranular corrosion has shown increasing tendency as the precipitation of sigma phase increased at $700^{\circ}C$ to $800^{\circ}C$, while it has decreased at $900^{\circ}C$ for 60 to 300 minutes.

Correlation analysis between climate indices and Korean precipitation and temperature using empirical mode decomposition : I. Data decomposition and characteristic analysis (경험적 모드분해법을 이용한 기상인자와 우리나라 강수 및 기온의 상관관계 분석 : I. 자료의 분해 및 특성 분석)

  • Ahn, Si-Kweon;Choi, Wonyoung;Kim, Taereem;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.49 no.3
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    • pp.197-205
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    • 2016
  • Recently, natural hazards have occurred frequently due to climate change. The research need for predicting variability and tendency of precipitation and temperature has been increased. However, it is difficult to determine the characteristics of precipitation and temperature within a confidence range since they change due to complex factors with choppy and too many components. If their characteristics having more than one component are decomposed, then it can be useful for determining the variation of such characteristics more accurately. In this study, Korean precipitation and temperature were decomposed and their Intrinsic Mode Function (IMF) were extracted from Empirical Mode Decomposition (EMD). Finally, the characteristics of Korean precipitation and temperature data were analyzed in terms of periodicity and tendency.

The model development and verification for surface branch wood fuels moisture prediction after precipitation during spring period at the east coast region (영동지역 봄철 소나무림에서 강우후 지표연료 직경별 연료습도변화 예측모델 개발 및 검증)

  • Lee, Si-Young;Lee, Myung-Woog;Kwon, Chun-Geun;Yeom, Chan-Ho;Lee, Hae-Pyeong
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.11a
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    • pp.434-437
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    • 2008
  • In this study, we developed a fuel moisture variation prediction model on each day after precipitation during a spring forest fire exhibition period. For this research, we selected plots in pine forest on Sam-Chuck si and Dong-hae si in Kangwon do according to a forest density(low, mediate, high) and classified a surface woody fuel by a diameter.(below 0.6cm, $0.6{\sim}3cm$, $3{\sim}6cm$, and above 6cm). A validity of this model was verified by applying a fuel moisture variation after precipitation in this spring. In the result, $R^2$ was $0.76{\sim}0.92$. This model will be a useful for improvement of a forest fire danger rate forcast through a prediction a fule moisture in forest.

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Fabrication Characteristics and Electrochemical Studies of SOFC Unit Cell using ScSZ-based Electrolyte Powder prepared by Co-precipitation Synthesis (공침법에 의한 고체산화물연료전지용 ScSZ계 전해질의 제조공정 특성 및 전기화학적 평가)

  • Kang, Ju Hee;Lee, Ho Jae;Kim, Ho-Sung;Jeong, Jong Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.138.2-138.2
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    • 2010
  • Scandium-doped zirconium, ScSZ-based electrolyte, provides higher oxygen conductivity than YSZ and nano-based electrolyte materials are ideal for fabricating thin film electrolyte membrane of SOFC unit cell. Moreover, it may be applied to anode and cathode as well as electrolyte as ionic conductor. In this report, nano-based ScSZ-based electrolyte powder was prepared by co-precipitation synthesis. The particle size, surface area and morphology of the powder were observed by SEM and BET. Thin film electrolyte of under $10{\mu}m$ was fabricated by tape casting and co-firing using the synthesized ScSZ-based powders, and ionic conductivity and gas permeability of electrolyte film were evaluated. Finally, the SOFC unit cell was fabricated using the anode-supported electrolyte prepared by a tape casting method and co-sintering. Electrochemical evaluations of the SOFC unit cell, including measurements such as power density and impedance, were performed and analyzed.

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WO3 Fabrication and Thermal Spray Coating of WC-Co using Recycled Ammonium Paratungstate (APT) (재활용 APT를 이용한 WO3 제조와 WC-Co 의 용사코팅)

  • Chung, J. K.;Kim, S. J.;On, J. H.;Moon, H. S.;Pee, J. H.;Ha, T. K.;Park, S. Y.
    • Transactions of Materials Processing
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    • v.24 no.4
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    • pp.287-292
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    • 2015
  • The possibility of chemical precipitation for recycled ammonium paratungstate (APT) was studied. WO3 particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT:DI-water. At the 500℃ sintering temperature, the X-ray diffraction results showed that APT completely decomposed to WO3. For the granulated powder WC-Co, vacuum heat treatment at proper temperatures increases tap density and flow-ability. Hardness of the WC-Co thermal spray coating layer was measured in the range HV 831~1266. Spray conditions for the best characteristic values were an oxygen flow rate=1500 scfh, a fuel flow rate = 5.25gph and a gun distance = 320mm.

Preparation of Ce0.8Gd0.2O1.9 Powder by Milling of CeO2 Slurry and Oxalate Precipitation (CeO2 슬러리 분쇄와 옥살산 침전을 이용한 Ce0.8Gd0.2O1.9 분말의 합성)

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.183-188
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    • 2010
  • $Ce_{0.8}Gd_{0.2}O_{1.9}$(GDC20) powder was synthesized by milling of $CeO_2$ slurry and Gd oxalate precipitation. The mixture of $CeO_2$ powder and Gd precipitates calcined at $600^{\circ}C$ for 2 h showed the particle size distribution similar to that of $CeO_2$ powder, which had been milled during the synthesis process. Attrition milling of the calcined powder with an average particle size of $0.36\;{\mu}m$ for 2 h resulted in a decrease in the particle size to $0.24\;{\mu}m$. Although the milled powder consisted of small particles(<$1\;{\mu}m$), a small amount of fine platy $Gd_2O_3$ particles, which had been survived in the milling process, was observed. Sintering of the powder compacts for 4 h showed relative densities of 80.7% at $1300^{\circ}C$ and 97% at $1400^{\circ}C$, respectively. Densification was found to almost complete at $1500^{\circ}C$, resulting in a dense and homogeneous microstructure with a relative density of 99.5%.

Water Physiology of Panax ginseng Charcteristics of reproductit.e organs and precipitation rate and humidity of shade system. (인삼의 수분생리 II. 생식기관의 특성과 일복의 누수량 및 습도)

  • Park, Hoon
    • Journal of Ginseng Research
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    • v.6 no.1
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    • pp.84-99
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    • 1982
  • Water content and its seasonal change in reprodltctive organs were reviewed in relation to cultivation practice s. Precipitati on and humidity under shade roof were reviewed in relation to shading ,jystem and environmental factors. High water content of reproductive organs suggests vulnerability to water stress during reproductive growth stage. Watering during dehisconce treat menu seems to keep optimum temperature but cnoventional practice seems to be too often In watering. Information effe on water physiology of seeds is too rare to develop seed storing method and ctive seed use. Dehiscent mechanism was considered in terms of water absorption of embryo. Precipitation rate of conventional shade roof reaclled to 38% and at line level 50% and varied with shade patterns. Precipitation rate under shade has been investigated for itself but should be investigated in relation to light intensity and soil moisture content Relative humidity under shade depends mainly on air humidity and soil moisture, considerably on shade materials and lithe on pole height, bed width or plant density. Since relative humidity was lower in afternoon it was often less than 50% even in summer with high temperature suggesting possible disorder of phi biological function especially in photosynthesis. More information was needed on optimum humidity for productive physiological function of leaf.

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Effect of Process Variables and exisisting Ions on Highly Active Nano-sized ITO Powders Prepared by Precipitation Method (고활성 ITO (Indium-Tin Oxide) 나노 분말을 침전법으로 합성시의 공정 변수 및 존재하는 이온의 영향)

  • Lee, In-Gyu;Noh, Bong-Hyun
    • Journal of Powder Materials
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    • v.15 no.6
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    • pp.450-457
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    • 2008
  • The objectives of this study were the development of a synthesis technique for highly active nanosized ITO powder and the understanding of the reaction mechanisms of the ITO precursors. The precipitation and agglomeration phenomena in ITO and $In_{2}O_{3}$ precursors are very sensitive to reaction temperature, pH, and coexisting ion species. Excessive $Cl^-$ ion and $Sn^{+4}$ ions had a negative effect an synthesizing highly active powders. However, with a relevant stabilizing treatment the shape and size of ITO and $In_{2}O_{3}$ precursors could be controlled and high density sintered products of ITO were obtained. By applying the reprecipitation process (or stabilization technique), highly active ITO and $In_{2}O_{3}$ powders were synthesized. Sintering these powders at $1500^{\circ}C$ for 5 hours produced 97% dense ITO bodies.

A Study on the Precipitation Behaviors in Rapidly Solidified AI-Li-Ti Alloys (급냉응고된 AI-Li-Ti 합금의 시효석출거동에 관한 연구)

  • Kim, Jae-Dong;Jeong, Hae-Young
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.3
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    • pp.279-286
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    • 1995
  • As Al-Li based alloys are to find widespread use in aerospace and other structural applications in which their low-density high specific stiffness properties be exploited, their mechanical properties must adequately match those of the which they intended to replace. In order to develop these purposed, the precipitation behaviors of the rapidly solidified Al-Li-Ti alloys aged at various temperature were investigated. ${\delta}'$ phase precipitated homogeneously in the matrix during not only melt quenching but also aging at the aging temperature of $160^{\circ}C\;and\;210^{\circ}C$. The addition of the Ti in Al-Li alloy promoted the formation of $\delta$' phase. The addition of Ti on the ${\delta}'$ solvus line had a little effect over the thermodynamics ${\delta}'$ solvus line. The reason for these behavior was that the ${\delta}'$ phase was suppressed to precipitate as much as supercooling by melt quenching. The discontinuous precipitation reaction occurred by the preferential growth of ${\delta}'$ phase due to the migration of grain boundary provided the driving force dependent of solute concentration fluctuations.

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A Study on the Development of Nanorod-Type Ni-Rich Cathode Materials by Using Co-Precipitation Method (공침법을 통한 나노로드 형태의 니켈계 양극 소재 개발에 관한 연구)

  • Joohyuk Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.2
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    • pp.215-222
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    • 2024
  • Ni-rich cathode materials have been developed as the most promising candidates for next-generation cathode materials for lithium-ion batteries because of their high capacity and energy density. In particular, the electrochemical performance of lithium-ion batteries could be enhanced by increasing the contents of nickel ion. However, there are still limitations, such as low structural stability, cation mixing, low capacity retention and poor rate capability. Herein, we have successfully developed the nanorod-type Ni-rich cathode materials by using co-precipitation method. Particularly, the nanorod-type primary particles of LiNi0.7Co0.15Mn0.15O2 could facilitate the electron transfer because of their longitudinal morphology. Moreover, there were holes at the center of secondary particles, resulting in high permeability of the electrolyte. Lithium-ion batteries using the prepared nanorod-type LiNi0.7Co0.15Mn0.15O2 achieved highly improved electrochemical performance with a superior rate capability during battery cycling.