• Applied Biological Chemistry
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• 제43권4호
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• pp.285-290
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• 2000

본 연구는 논에서 강우에 의한 질소와 인산의 유출특성을 조사하였다. 이를 위하여 농업이외의 오염원이 비교적 적은 전라북도 진안군 마령면 평지리 일대 $5,000\;m^2$의 논을 시험포장으로 선정하여 1997년 5월 1일부터 1998년 4월 30일까지 12개월 동안 유출수 중 질소와 인의 시기별 함량변화 및 논에서의 유출수문 자료를 수집하였다. 논에서의 평균 유효유량은 관개기간 동안에 77.0 mm, 비관개기간 동안에는 21.2 mm로 나타났으며, 초기유출우량은 관개기간 동안 6.3-33.7 mm의 범위로 평균 12.9 mm, 비관개기간 동안 5.9-12.5 mm의 범위로 평균 9.2 mm로 산정되었다. 유출계수는 관개기간 중 0.59-1.36, 비관개기간 동안에는 0.57-0.86의 범위를 나타내었다. 관개기간과 비관개기간 사이에 영양물질의 유출특성에 차이가 없는지를 조사한 결과, 질소원과 인산원은 시기별로 유출량의 차이가 나타나지 않은 반면, 부유물질은 시기별로 차이를 나타내고 없었다. 논에서 강우-유출 중 발생하는 유출수량을 이용한 유출부하량 예측 결과, 질소원은 유출부하량 예측이 가능하였지만, 입자태 성분의 형태로 유출이 발생하는 부유물질과 전인은 약간의 오차가 발생하였다.

• 대한화학회지
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• 제54권3호
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• pp.338-349
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• 2010

이 연구에서는 중학교 3학년에 가르치는 일정성분비의 법칙과 관련된 앙금생성실험수업과 모형을 이용한 수업의 효과를 비교하였다. 연구 대상은 중학교 3학년 250명이었으며, 각각 앙금생성 실험반과 모형반으로 구분하였다. 연구 결과, 앙금생성 실험반은 수용액 안에 각각의 원소들이 분리되어 있다고 생각하는 비율이 상대적으로 높았으며, 두 용액을 섞으면 새로운 화합물이 만들어진다고 인식하는 비율도 모형반보다 높았다. 앙금생성에 대한 학생들의 인식에는 두 집단이 큰 차이가 없었으며, 오답의 비율이 높아 교수전략이 학생들의 인식을 교정하는데 효율적이지 못함을 확인하였다. 비록 실험 결과로부터 규칙성을 찾는 비율은 모형을 사용하는 집단이 높았지만, 실험 결과로부터 반응물 사이의 일정비 결합을 추론하는 학생들의 비율은 두 집단이 유사하였다. 이러한 연구 결과를 통해 실험과 모형을 통해 일정성분비를 추론하는 것은 중학생의 수준에서 쉽지 않다는 점을 알 수 있다.

• 한국대기환경학회지
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• 제5권2호
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• pp.1-11
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• 1989

Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

• 공업화학
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• 제4권3호
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• pp.601-615
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• 1993

PC/PA6 블랜드를 세 가지 서로 다른 방법으로 블랜드한 후 이들의 상용성에 관하여 조사하였다. DSC에 의한 열적 성질 측정결과, Tg는 전 조성에 있어 각각의 온도부근에서 나타나며, 융점과 결정화온도는 큰 변화가 없었다. SEM관찰 역시 PC, PA6 블랜드는 각각 5%의 아주 낮은 조성에서부터 상분리가 확인되었다. 또한 실험적으로 측정된 Tg값을 Flory- Huggins식에 도입하여 polymer-polymer interaction parameter(${\chi}_{12}$)값을 계산한 결과, solution casting, solution precipitation, 압출블랜드의 경우 0.0381, 0.0411, 0.0418로 각각 계산되었으며, ${\chi}_{12}$의 임계값 $({\chi}_{12})_c$가 0.0271로 계산됨에 따라 결국 PC/PA6 블랜드는 전 조성에 걸쳐 상용성이 부족하였다.

• 한국대기환경학회지
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• 제12권3호
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• pp.323-332
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• 1996

Precipitation samples were collected by the wet-only sampling method at Seoul from September 1993 to June 1995. Sample were analysed for the anions $(NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, and F^-)$ and cations $(Na^+, K^+, Ca^{2+}, Mg^{2+}, and NH_4^+)$ in addition to pH and electric conductivity. In order to establish the chemical analysis data of high quality, the assurance checks for analytical data of precipitation were performed by considering the ion balance and by comparing the measured conductivity with the calculated conductivity. As we applied the various assurance checking methods by the ion balance used until recently to a data set measured in this study, the f value expressed as $\Sigma C/\Sigma A$ was found to be not appropriate for the data screening. Also, the scattering plot between cations and anions in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a data set of samples of various concentration levels. The h value defined as (A-C)/C for C $\geq$ A and (A-C)/A for C < A was used to check the ion balance. However, the standard of data screening by h value must very in response to total ion concentration of samples. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance of evaluating by h value and the conductivity balance. Further the quality control was achieved by these quality assurance methods. As the result, 67 samples among total 77 were obtained as valid. As the central tendency value for a statistical summary in the analytical parametr of samples, the volume-weighted mean value was found to represent more the general chemistry of precipitation rather than the arithmetic mean. The volume-weighted mean pH was 5.0 and 25% of samples was less than this mean. The concentrations of sufate and nitrate in precipitation were 90.4 ueq/L and 32.4 ueq/L which made up 59% and 21% of all anions. The raion of $SO_4^{2-}/(NO_3^- + NO_2^-)$ in precipitation was 2.7, which indicates that the contributions of $H_2SO_4$ and $HNO_3$ to the acidity of precipitation are 70% and 30%, respectively.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
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• pp.405-407
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• 2005

To evaluate the main hydrogeochemical characteristics, river waters are investigated using element리 and isotopic compositions in South Korea. In this area, the chemical compositions are mostly classified into three groups; $Ca^{2+}-{HCO_3}^-$ type, $Ca^{2+}-Cl^{-}-{NO_3}^-$ type and $Ca^{2+}-{HCO_3}^{-}-Cl^{-}-{NO_3}^-$ type. These types are affected by two major factors: water-rock interaction and anthropogenic inputs such as sewage and fertilizers. Based on the values of ${\delta}^{18}O$ and ${\delta}D$, most of waters are originated from precipitation except two samples contaminated. The lithology and geography of basins mainly control the water chemistry. Elemental and isotopic compositions show that water chemistry are mainly controlled by three end members, especially by carbonate dissolution, and suggest that anthropogenic input affect the water chemistry. Also, three weathering sources are identified: silicates, dolomite and limestone.

• 한국응용과학기술학회지
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• 제14권3호
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• pp.97-101
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• 1997

An intracellular, soluble 1,4-benzoquinone reductase was purified from Baker's Yeast by ammonium sulfate precipitation, DEAE-Sephacel anion exchange chromatography, and Sephacryl S-200 gel filtration chromatography. 1,4-Benzoquinone reductase was achieved 123.8 fold purification from crude homogenate with a yield of 11.1%.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.9-12
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• 1994

The gravimetric determination of scandium by di-(2-ethylhexyl)phosphate(DEHPA) as a precipitant and the mole ratio of Sc-DEHPA arecipitation obtained in ethanol medium have been investigated. Scandium can be determined by gravimetric method of precipitation of Sc-DEHPA and the mole ratio of Sc-DEHPA is found as 1 :2 in ethanol medium.

• Environmental Engineering Research
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• 제25권1호
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• pp.88-95
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• 2020

An investigation of rare metals recovery from LiNi_xCo_yMn_zO₂ cathode material of the end-of-life lithium-ion batteries is presented. To determine the influence of reductant on the leach process, the cathode material (containing Li 7.6%, Co 20.4%, Mn 19.4%, and Ni 19.3%) was leached in H₂SO₄ solutions either with or without H₂O₂. The optimal process parameters with respect to acid concentration, addition dosage of H₂O₂, temperature, and the leaching time were found to be 2.0 M H₂SO₄, 4 vol.% H₂O₂, 70℃, and 150 min, respectively. The yield of metal values in the leach liquor was > 99%. The leach liquor was subsequently treated by precipitation techniques to recover nickel as Ni(C₄H₇N₂O₂)₂ and lithium as Li₂CO₃ with stoichiometric ratios of 2:1 and 1.2:1 of dimethylglyoxime:Ni and Na₂CO₃:Li, respectively. Cobalt was recovered by solvent extraction following a 3-stage process using Na-Cyanex 272 at pH_eq ~5.0 with an organic-to-aqueous phase ratio (O/A) of 2/3. The loaded organic phase was stripped with 2.0 M H₂SO₄ at an O/A ratio of 8/1 to yield a solution of 114 g/L CoSO₄; finally recovered CoSO₄.xH₂O by crystallization. The process economics were analyzed and found to be viable with a margin of $476 per ton of the cathode material.

• 한국대기환경학회지
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• 제22권1호
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• pp.15-24
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• 2006

Precipitation samples were collected at Anmyeon (1997 - 2004), Uljin, and Gosan (1998 ~ 2004), the background area of the Korean Peninsula. These samples were analyzed for the concentration of 9 major ionic components ($F^{-}$,$Cl^{-}$, $NO_{3}^{-}$, $SO_{4}^{2-}$, $Na^{+}$, $NH_{4}^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$) with including a pH and an electric conductivity. Data quality for these samples was verified by ion balance and conductivity balance which are based on GAW manual for precipitation chemistry and the number of valid data at Anmyeon, Uljin, and Gosan is 249, 173, and 188, respectively. During the study period, the precipitation-weighted average pH at Anmyeon, Uljin, and Gosan was found to be 4.81, 4.87 and 4.89, respectively and each annual average pH was showed below pH 5.6 for every site. From the frequency survey on the precipitation acidity, the occurrence rate of acid rain below pH 5.6 is greater than $80\%$ for every site. Particularly, the highest occurrence rate for strong acid rain below pH 4.5 was found at Anmyeon, $32.1\%$, compared with other sites ($10.4\%$ at Uljin, $15.4\%$ at Gosan). That's because acidifying species (nss-$SO_{4}^{2-}$, $NO_{3}^{-}$) are remarkably high concentration at Anmyeon.