• Title/Summary/Keyword: Precipitation Behavior

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Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

Precipitation Behavior of α-Cr Particle in B2-type Intermetallic Compounds β-NiAl (B2형 금속간화합물 β-NiAl중에 α-Cr입자의 석출거동)

  • Han, Chang-Suck;Kim, Youn-Che
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.91-102
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    • 1996
  • Microstructural control to produce multiphase structure has received much attention to improve the high temperature strength as well as low temperature ductility of intermetallics. Transmission electron microscopic investigation has been carried out concerning the effect of Cr-precipitation on the mechanical properties of B2-ordered NiAl containing 4 to 8 mol% of Cr. By aging at temperatures around 973 K after solution annealing, fine spherical precipitates took place homogeneously in the NiAl matrix and the alloys hardened appreciably. Selected area electron diffraction (SAED) patterns have not revealed any additional extra-spots during aging, because the Cr-particles show cube-cube orientation relationship and keep a perfect coherency with the ordered matrix lattice. Dislocations were confirmed to bypass the particles during deformation. Although the dispersion of Cr-particles increased the yield strength of NiAl at intermediate temperature, the strength decreased appreciably at higher temperatures.

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Investigation of Water Quality and Hydrological Characteristic When Red Tide Develop in the Mouth of Hyeongsan River (형산강 하류 적조발생시 수질 및 수문학적 특성 검토)

  • Lee, Chang-Soo
    • Journal of Environmental Science International
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    • v.18 no.10
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    • pp.1155-1162
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    • 2009
  • To investigate the influence of water area calmness on the red tide development, runoff phenomena due to antecedent precipitation of red tide development day were analyzed. There were examined the water quality variation properties at about the same time of the red tide develop. The red tide was developed when the stage and discharge nearly had not changed. It was estimated that the stability of particle behavior in the mouth of river effected on the red tide develop. Also, the concentrations of $COD_{Mn}$ were increased about 241~629% when the red tide developed.

Condensational Growth of Fine Aerosol Particles to Increase Precipitation Efficiency (집진효율 향상을 위한 미세 에어로졸 입자의 응축에 의한 성장 연구)

  • Han, Sang-Woo;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.8
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    • pp.1069-1076
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    • 2000
  • As the environmental problems grow, the regulation of the pollutants emitted from power plants increases. Most of the pollutants in particle phase are removed by particle removal facilities, but fine particles between 0.1 micron and I micron in diameter have a low removal efficiency compared to particles in other size ranges. Therefore the present concern has concentrated on the removal of those fine particles. The purpose of this study is to grow fine particles by condensation to the range larger than I micron. Theoretically the general dynamic equation is solved with an assumption that the particle size follows a log-normal distribution to calculate the temporal behavior of the size distribution. Experiments have been carried out to compare the results with the theoretical predictions. Particles grown by condensation are sampled by impactors and observed with SEM photographs.

Enhancement of Mechanical Properties of 5052 Al Alloy by Cryogenic and Warm rolling (극저온 압연 및 온간 압연 기술을 이용한 5052 알루미늄 합금의 기계적 성질의 향상)

  • Gang, U.G.;Lee, S.H.;Lee, J.C.;Nam, W.J.
    • Transactions of Materials Processing
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    • v.17 no.2
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    • pp.102-106
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    • 2008
  • Cryogenic rolling combined with warm rolling has been found more effective than a single cryogenic rolling process in improving the strength of a 5052 Al alloy. In this study, cryo-rolled 5052 Al alloys were warm-rolled at $175^{\circ}C$. A notable increase of tensile strength was achieved by the precipitation during warm rolling process. Mechanical behavior of this alloy was investigated using hardness and tensile tests. It was found that the cryogenic rolling process combined with warm rolling process was very effective in improving tensile strength.

Effect of Aluminium and Boron on Formability for Cu Bearing Extra Low Carbon Steel Sheets (Cu첨가 극저탄소 고 강도강의 가공성에 미치는 Al과 B의 영향)

  • Kim, S.I.;Chung, K.H.;Hong, M.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.302-305
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    • 2009
  • This paper examines the effect of nitride formation on formability for Cu bearing high strength extra low carbon (ELC) steel sheets. For this purpose, we have investigated the effect of addition of aluminium (Al) and boron (B) on texture and precipitation behavior of the ELC steel during continuous annealing. Mechanical properties and microstructures of the ELC steel sheets were analyzed as well using uni-axial tensile test, electron back-scattered diffraction (EBSD) technique and transmission electron microscopy (TEM) following pilot rolling and continuous annealing. It has been found that the addition of Al and B increases the precipitation of AlN and BN. What is more, the scavange of solute nitrogen is effective in increasing the formability of the ELC steels. In addition, the Al and B addition improves the aging property of the ELC steel.

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Large enhancement in mechanical properties of the 5052 Al alloys by cryogenic and warm rolling (극저온 압연 및 온간 압연 기술을 이용한 5052 알루미늄 합금의 기계적 성질의 향상)

  • Gang, E.G.;Lee, S.H.;Lee, J.C.;Nam, W.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.10a
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    • pp.81-83
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    • 2007
  • Cryogenic rolling combined with warm rolling has been found to be more effective than only cryogenic rolling procedure in improving the strength of a 5052 Al alloy. In this study, cryo-rolled 5052 Al alloys were aged at $175^{\circ}C$. Warm rolling was conducted after dipping plates into silicon oil bath. A notable increase of tensile strength is achieved by the precipitation during warm rolling. The mechanical behavior of this alloy was investigated by hardness and tensile tests. The microstructure was investigated by transmission electron microscopy. It was found that the cryogenic rolling combined with warm rolling was very effective in improving tensile strength.

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Temporal Variation and Spatial Distribution of Water Resources (수자원 분포의 시공간적 변동)

  • 김성준
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.3
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    • pp.175-196
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    • 2002
  • The increase of meteorological uncertainty and unstable fluctuation of its behavior due to the global warming affect the temporal variation and spatial distribution of water resources and water use patterns in agriculture. There have been steady efforts to understand hydrological components and deal with such water related problems. This paper reviews firstly, the future effect of water resources due to climate changes, secondly, recent progress for precipitation, evapotranspiration, soil moisture, and thirdly, GIS/RS based integrated information systems conducted by both researchers and government ministries. There should be continuous studies and investments to cope with climate changes, and to accomplish sustainable development with the help of agricultural water resources. Some research topics were suggested to attempt with substantial contents considering our present capability and situation.

Precipitation Behavior of Ammonium Vanadate from Solution Containing Vanadium (바나듐 함유 수용액의 암모늄바나데이트 침전거동 고찰)

  • Yoon, Ho-Sung;Chae, Sujin;Kim, Chul-Joo;Chung, Kyeong Woo;Kim, Minseuk
    • Resources Recycling
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    • v.28 no.5
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    • pp.42-50
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    • 2019
  • In this study, the precipitation reaction of vanadium and ammonium chloride in aqueous solution was investigated in order to recover vanadium. Ammonium metavanadate having a crystal structure of [$NH_4VO_3$] was precipitated from aqueous solution containing vanadium at pH 9.2 ~ 9.4, and ammonium polyvanadate having a crystal structure of [$(NH_4)_2V_6O_{16}$] was precipitated when the pH of the aqueous solution containing vanadium was adjusted with sulfuric acid. Ammonium polyvanadate [$(NH_4)_2V_6O_{16}$] precipitated at a temperature of $80{\sim}90^{\circ}C$ and pH 2, and at a temperature of $40^{\circ}C$ and pH 6 ~ 8 of aqueous solution. In the acidic region of aqueous solution pH 2, the vanadium content of the aqueous solution should be at least 3,000 mg/L and the precipitation temperature should be maintained at $80^{\circ}C$ or higher in order to obtain a precipitation ratio of 99% or more. When the ammonium vanadate was precipitated in the alkaline region, the vanadium content was more than 10,000 mg/L and the precipitation temperature was maintained at $40^{\circ}C$ to increase the precipitation ratio. Aluminum was not precipitated regardless of the vanadium content and pH of the aqueous solution. However, the iron component reacts with ammonium chloride to precipitate into ammonium jarosite. Therefore, Fe component must be preferentially removed in order to increase the recovery of vanadium.

A Review of Precipitation Susceptibility in Warm Boundary Layer Clouds (따뜻한 구름에서의 강수민감도에 대한 고찰)

  • Jung, Eunsil
    • Journal of the Korean earth science society
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    • v.40 no.2
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    • pp.109-118
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    • 2019
  • Cloud-aerosol interactions are considered to be one of the most important forcing mechanisms in the climate system. However, there is considerable disagreement on the magnitude and even on the sign of how aerosol perturbations affect cloud fraction and lifetime. Furthermore, aerosol effects on clouds and precipitation are not readily separable from the effects of meteorology. This review paper summarizes the study of precipitation susceptibility $S_o$, which qualifies how aerosol perturbations alter the magnitude of the precipitation rate (R) while minimizing the effects of macrophysical factors such as cloud depth (H) and liquid water path (LWP). The analysis shows that the precipitation susceptibility $S_o$ for the warm marine boundary layer clouds is insensitive to aerosol perturbations at low LWP (equivalently low H). However, R decreases as aerosols increase at intermediate LWP. This is because aerosols act as cloud seed and produce numerous small-sized particles, which impede the collision and coalescence process that leads to precipitation. At high LWP, $S_o$ decreases with increasing LWP as there are enough water contents in the clouds. The LWP or H dependent $S_o$ behavior differs depending on the predominant cloud physics processes in the clouds.