• Title/Summary/Keyword: Pre-treatment process

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Effects of Acid Treatment of Carbon on Electroless Copper Plating (피도금 탄소재의 산처리가 무전해 동도금에 미치는 영향)

  • Shin, Ari;Han, Jun Hyun
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.265-273
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    • 2016
  • The effects of surface modification by nitric acid on the pre-treatment of electroless copper plating were investigated. Copper was electroless-plated on the nitric acid treated graphite activated by a two-step pre-treatment process (sensitization + activation). The chemical state and relative quantities of the various surface species were determined by X-ray photoelectron spectroscopy (XPS) after nitric acid modification or pre-treatment. The acid treatment increased the surface roughness of the graphite due to deep and fine pores and introduced the oxygen-containing functional groups (-COOH and O-C=O) on the surface of graphite. In the pre-treatment step, the high roughness and many functional groups on the nitric acid treated graphite promoted the adsorption of Sn and Pd ions, leading to the uniform adsorption of catalyst ($Pd^0$) for Cu deposition. In the early stage of electroless plating, a lot of tiny copper particles were formed on the whole surface of acid treated graphite and then homogeneous copper film with low variation in thickness was formed after 30 min.

Effect of Pre-Aging Conditions on Bake-Hardening Response of Al-0.4 wt%Mg-1.2 wt%Si-0.1 wt%Mn Alloy Sheets

  • Lee, Kwang-jin;Woo, Kee-do
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.448-453
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    • 2011
  • Pre-aging heat treatment after solution heat treatment (SHT) of Al-0.4 wt%Mg-1.2 wt%Si-0.1 wt%Mn alloy sheets for auto-bodies was carried out to investigate the effect of pre-aging and its conditions on the bake-hardening response. Mechanical properties were evaluated by a tensile and Vickers hardness test. Microstructural observation was also performed using a transmission electron microscope (TEM). It was revealed that pre-aging treatments play a great role in the bake-hardening response. In addition, it was found that the sphere-shaped nanosized clusters that can directly transit to the needle-shaped ${\beta}$" phase during the paint-bake process, not being dissolved into the matrix, are formed at 343 K. The result, reveals that the dominant factor of the bake-hardening response is the pre-aging temperature rather than the pre-aging time.

The Effect of Heat Treatment on the Tensile Properties of TiNi/6061Al Composites (TiNi/6061Al 복합재료의 인장특성에 미치는 열처리의 영향)

  • Park, Sung-Ki;Shin, Soon-Gi;Lee, Jun-Hee
    • Korean Journal of Materials Research
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    • v.13 no.1
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    • pp.64-68
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    • 2003
  • The 1.6 vol% and 2.5 vol% TiNi/6061Al composites were fabricated by permanent mold casting for investigating the effect of heat treatment on tensile strength for composites. The tensile strength without T6 treatment at 293 K was increased with increasing the volume fraction of TiNi fiber and at 363 K the higher the pre-strain, the higher the tensile strength. The tensile strength of the composite with $T_{6}$ treatment at 293 K was found to increase with increasing both the amount of pre-strain and the volume fraction of TiNi fiber and was higher than that without $T_{6}$ treatment. It should be noted that the tensile strength 2.5vol%TiNi/6061Al composites rolled at a 38% reduction ratio was the maximum value of 298 MPa. The tensile strength of composites decreased with increasing the reduction ratio over 38% because of the rupture of TiNi fiber.

Substitutability of coagulation process by pre-treatment of coagulation·flotation using natural algae coagulant (천연조류제거제를 활용한 응집·부상 전처리공정의 기존 응집공정 대체 가능성)

  • Jang, Yeo-Ju;Jung, Jin-Hong;Lim, Hyun-Man;Chang, Hyang-Youn;Kim, Weon-Jae
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.1
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    • pp.39-50
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    • 2017
  • In the coagulation/sedimentation (C/S) process of the water treatment process, the inflow of massive algal bloom causes many problems including fouling of filter media. This study was conducted to find out the way to remove the algae's harmful effects by addition of pre-treatment prior to C/S process. Many Jar-tests were conducted such as (1) ACF (Algae Coagulation Flotation) process using natural algae coagulant (Water $Health^{(R)}$), (2) ACF + C/S process and (3) C/S process with a variety of conditions using cultured algae. The average values of turbidity were (1) 0.42 NTU for ACF process, (2) 0.13 NTU for ACF + C/S process and (3) 0.25 NTU for C/S process. It was shown that the treatment efficiency of ACF process could get low turbidity results, and ACF + C/S process could achieve more efficient results than those of C/S process. Any negative effects of ACF process to the efficiency of C/S process were not observed in ACF + C/S process. In order to reduce the unfavorable effects of algae, it was found out that the introduction of ACF process in the forms of (1) ACF or (2) ACF + C/S could be one of the effective and alternative solutions.

Properties Variation According to Heat Treatment for Gas Turbine Blade(Bucket) Material of GTD-111DS (GTD-111DS 가스터빈 블레이드 재질의 열처리에 따른 재질 특성변화)

  • Park Sang-Yeal;Yang Sung-Ho;Kim Moon-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.3 s.246
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    • pp.349-355
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    • 2006
  • The gas turbine components is used on high temperature conditions which under severely circumstance with start-up and stop several times. Therefore, it is used nickel-base superalloys like and GTD-111DS. Damaged buckets on the t긴ade tip during operating are repaired per 24,000 hr to three times according to repair specification of manufacture. It is applied pre-heat, HIP(hot isostatic pressing) and post-heat treatment to support welding repair on blade tip effectively. On this study, It is utilize of $WRAP^{TM}$ (welding repair advanced process) method to make tension test specimens for this study, And then, material strength and characteristic for GTD-111DS was analyzed.

A Study on Pre-treatment Facility for Foodwaste and Sewage Sludge Mixture (음식폐기물과 하수슬러지 병합처리를 위한 전처리시설에 관한 연구)

  • Kim, Jong-Oh;Lee, Chang-Ho;Kim, Ji-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.1
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    • pp.84-89
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    • 2003
  • The purpose of this study was to evaluate and improve the pre-treatment facility for foodwaste and sewage sludge mixture treatment. The process of foodwaste pre-treatment consists of storage, classification with crushing, and thickening. The effluent of sewage treatment facility was used as the diluting and washing water. The panicle size of foodwaste after pre-treatment was almost under 2mm, the mixture of foodwastes and sewage sludge showed an advantage to the anaerobic digestion. The amount of gas production increased from 0.8ton/day ($CH_4$ : 0.5ton/day) to 3.5ton/day ($CH_4$ : 2.3ton/day) after the anaerobic digestion of the foodwastes and sewage sludge mixture. The amount of sludge cake increased from 11.2ton/day to 21.2ton/day. Therefore, the proper operation of the foodwaste pre-treatment facility was contributed to the efficient anaerobic digestion of foodwaste and sewage sludge mixture treatment.

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Comparison of Bacterial Biomass and Community of Granular Activated Carbon with or without UV Pre-treatment Process (UV 전처리 유무에 따른 입상활성탄의 세균 생체량 및 군집 구조 비교)

  • Lim, Jaewon;Kim, Seoyong;Kim, Jeongyong;Kim, Tae Ue
    • The Journal of the Korea Contents Association
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    • v.17 no.12
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    • pp.64-76
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    • 2017
  • Biolgical activated carbon (BAC) processes are known to effectively remove organic pollutants in raw water, and biomass and attached bacterial species play an important role in removing process. In the present study, changes of bacterial biomass in granular activated carbon (GAC) process according to the depth and operating period were investigated. In addition, changes of bacterial biomass were also confirmed after UV exposure prior to the GAC process. Results from this this study showed that the bacterial biomass was decreased dependently according to the depth of GAC process. In case of UV pre-treatment, the bacterial biomass was declined significantly over the period of operation. However, changes in bacterial community were not shown during operation period without UV pre-treatment process. In conclusion, findings from this study may provide the useful information about the management of BAC process.

Effects of ultrasound coupled with potassium permanganate pre-treatment of sludge on aerobic digestion

  • Demir, Ozlem
    • Advances in environmental research
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    • v.5 no.4
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    • pp.251-262
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    • 2016
  • The biodegradability and decomposition efficiencies increase with the pre-treatment of sludge in a digestion process. In this study, the feasibility of ultrasound coupled with potassium permanganate oxidation as a disintegration method and digestibility of aerobic reactor fed with disintegrated sludge with ultrasound coupled potassium permanganate were investigated. The first stage of the study focused on determining the optimum condition for ultrasonic pre-treatment for achieving better destruction efficiency of sludge. The second part of the study, the aerobic digestibility of sludge disintegrated with ultrasound and potassium permanganate oxidation alone and combined were examined comparatively. The results showed that when 20 min of ultrasonic pre-treatment applied, the specific energy output was 49384 kJ/kgTS with disintegration degree of 58.84%. During the operation of aerobic digester, VS/TS ratios of digesters fed with disintegrated sludge decreased indicating that disintegration methods could obviously enhance aerobic digestion performance. The highest reduction in volatile solids was 75% in the digester fed with ultrasound+potassium permanganate disintegrated sludge at the end of the operation compared to digester fed with raw sludge. Total Nitrogen (TN) and Total Phosphorus (TP) levels in sludge supernatant increased with this combined method significantly. Besides, it promoted the production of ${\bullet}OH$, thus enhancing the release of Carbon (C), Nitrogen (N) and Phosphorus (P) from the sludge. Disintegration with all methods used in this study could not improve Capillary Suction Time (CST) reduction in disintegrated digesters during the operation. The results demonstrated that the combined ultrasound treatment and potassium permanganate oxidation method improves the biodegradability compared to control reactor or their single application.

Evaluation of RO Process Feasibility and Membrane Fouling for Wastewater Reuse (하수처리수 재이용을 위한 RO 공정의 타당성 및 막오염 평가)

  • Hong, Keewoong;Lee, Sangyoup;Kim, Changwoo;Boo, Chanhee;Park, Myunggyun;An, Hochul;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.26 no.2
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    • pp.289-296
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    • 2010
  • The purpose of this study is to evaluate various pre-treatment methods and proprieties of water quality for wastewater reuse using reverse osmosis (RO) processes. Secondary effluents were sampled from wastewater treatment plants and lab scale pre-treatments and RO filtration test were conducted systematically. Specifically, different types of pre-treatments, such as coagulation, microfiltration and ultrafiltration, were employed to evaluate the removal efficiency of particle and organic matters which may affect the membrane fouling rate. RO process was later added to eliminate trace amounts of remaining organic matters and salt from the raw water for wastewater reclamation. The permeate through the RO process satisfied water quality regulations for industrial water uses. The experimental results showed that the initial fouling tendency differed not only by the feed water properties but also by the membrane characteristics. Membrane fouling was greater for the membranes with large surface roughness, regardless of the hydrophobicity and zeta potentials. Thus both careful consideration of pre-treatment options and proper selection of RO membrane are of paramount importance for an efficient operation of wastewater treatment.

Bioethanol Production using Endogenous Triticale Enzyme (라이밀 자체 효소를 이용한 바이오에탄올 생산)

  • Choi, Gi-Wook;Kim, Yule;Moon, Se-Kwon
    • KSBB Journal
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    • v.23 no.6
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    • pp.504-508
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    • 2008
  • The objectives of this study were to develope the economical process for bioethanol production from domestic triticale and investigate optimal fermentation conditions such as temperature, time, and enzyme concentration used to pre-treatment process. Triticale mash, containing 148 g of total sugar per 1 L of mash, was fermented with Saccharomyces cerevisiae CHY1011 at $33^{\circ}C$. Fermentation of mash supplemented with enzyme was completed within 48-60 hours, and the ethanol yield was 410.9 L/tonne of dry base. On the other hand, fermentation of mash without enzyme addition was completed within 36-48 hours, but the ethanol yield was 342.2 L/tonne of dry base. For optimal bioethanol production from triticale, viscosity reduction enzyme was added in the pre-treatment process, and the fermentation rate of triticale was 92.0-94.2%. In addition, the results showed that bioethanol production of triticale by low-temperature pre-treatment would provide higher ethanol production efficiency and lower operating costs.