• Magazine of the Korea Concrete Institute
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• v.9 no.3
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• pp.149-156
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• 1997

In order to improve compressive strength of cement mortar, powder admixture(FAS) was mmufactured by mixing fly ash. Il-anhydite and silica hume, and superplasticizer was used for the control of fluidity reduction with the use of this admixture. Cement was substituted by 10, 20wt% of FAS respectively. At W/S = 0.40, the fluidity of' cement paste substituted by PAS was decreased. NSF and NT-2 were very effective fbr the control of fluidity reduction. As the particle size of U -anhydrite was fine, the fluidity of cement mortar was increased. The fluidity reduction of cement mortar substituted by 10wt% of FAS was controlled. The compressive strength of cement mortar substituted by 10wt% of FAS showed higher. value than that of 20wt%, expecially specimen(C1) substituted by 10wt% of $\gamma$ had the highest compressive strength value.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.66-71
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• 1995

This study reviews the internationally existing standards for fly ash and the other pozzolanic materials. The standards reviewed for this report covers the thirteen contries around the world including USA. It is found that the comparison of standards appeared to be different for technical test requirements from the country to country. This may be due to the different composition of fly ash produced in each different country as by-product. It is importantly shown that the four countries, including USA have standardized to compose the total 70% of $SiO_2+Al_2O_3+Fe_2O_3$. The other countries have required to have the individual chemical composition, such as 45% $SiO_2$ in Japan. The loss on ignition is generally in the range of 5-6%, but the maximum 12% was allowed in some countries. This depends on the quality of fly ash. The moisture content is generally less than 3% in all countries except India allows up to 12% The pozzolanic activity (as the compression) has been standardized that the 28 days curing in compression was subjected in all countries but 91 days curing in compression was tested in Japan. It is shown that KS L 5405 is almost identical to JIS A 6201.

• Journal of the Mineralogical Society of Korea
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• v.17 no.3
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• pp.277-288
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• 2004

Alkali-silica reaction (ASR) is a chemical reaction between alkalies in cement and chemically unstable aggregates and causes expansion and cracking of concrete. In the Present study, we studied the effects of metakaolin, which is a newly introduced mineral admixture showing excellent pozzolainc reaction property, on the inhibition of ASR. We prepared mortar-bars of various replacement ratios of metakaolin and conducted alkali-silica reactivity test (ASTM C 1260), compressive strength test and flow test. We also carefully analyzed the mineralogical changes in hydrate cement paste by XRD qualitative analysis. The admixing of metakaolin caused quick pozzolanic reaction and hydration reaction that resulted in a rapid decrease in portlandite content of hydrated cement paste. The expansion by ASR was reduced effectively as metakaolin replaced cement greater than 15%. This resulted in that the amounts of available portlandite decreased to less than 10% in cement paste. It is considered that the inhibition of ASR expansion by admixing of metakaolin was resulted by the combined processes that the formation of deleterious alkali-calcium-silicate gel was inhibited and the penetration of alkali solution into concrete was retarded due to the formation of denser, more homogeneous cement paste caused by pozzolanic effect. Higher early strength (7 days) than normal concrete was developed when the replacement ratios of metakaolin were greater than 15%. And also, late strength (28 days) was far higher than normal concrete for the all the replacement ratios of metakaolin. The development patterns of mechanical strength for metakaolin admixed concretes reflect the rapid pozzolanic reaction and hydration properties of metakaolin.

• Journal of the Korea Institute of Building Construction
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• v.7 no.1 s.23
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• pp.71-77
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• 2007

This paper is to investigate the effect of the curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of the compressive strength of the concrete was conducted using the equivalent age equation and the rate constant model proposed by Carino. Correction of Carino model was studied to secure the accuracy of strength development estimation by introducing correction factors regarding rate constant and age. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of BS has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• Clean Technology
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• v.7 no.2
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• pp.109-117
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• 2001

Whereas commonly used to make concrete having rich water contents as binder or mineral admixture, blast furnace slag has been rarely applied to manufacture in concrete based products having poor water contents. This study, for the multi-recycling of blast furnace slag, is to analyze strength enhancement mechanism of concrete based products using blast furnace slag. The results of this study are following. We found that blast furnace slag is very effective mineral admixture to manufacture high strength spacer having over $400kgf/cm^2$ in compressive strength. Also, enhancement of strength by blast-furnace slag are responsible to densified grading and pozzolanic reaction.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.75-78
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• 2005

This raper investigates the effect of curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of compressive strength of concrete was conducted using equivalent age equation and rate constant model. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of 35 has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• Proceedings of the Korean Institute of Building Construction Conference
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• v.y2004m10
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• pp.71-76
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• 2004

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

• Computers and Concrete
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• v.13 no.6
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• pp.739-748
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• 2014

In this article, by using experimental studies and artificial neural network has been tried to investigate the use of nano-silica as concrete admixture to reduce alkali-silica reaction. If there are reactive aggregates and alkali of cement with enough moisture in concrete, a gel will be formed. Then with high reactivity between alkali of cement and existence of silica in aggregates, this gel will expand by absorption of water, and causes expansive pressure and cracks be formed. At the time passes, this gel will reduce both durability and strength of the concrete. By reducing the size of silicate to nano, specific surface area of particles and number of atoms on the surface will be increased, which causes more pozzolanic activity of them. Nano-silica can react with calcium hydroxide ($Ca(OH)_2$) and produces C-S-H gel. In this study, accelerated mortar bar specimens according to ASTM C 1260 and ASTM C 1567, with different mix proportions were prepared using aggregates of Kerman, such as: none admixture and plasticizer, different proportions of nano-silica separately. By opening the moulds after 24 hour and curing in water at $80^{\circ}C$ for 24 hour, then curing in (1N NaOH) at $80^{\circ}C$ for 14 days, length expansion of mortar bars were measured and compared. It was noted that, the lowest length expansion of a specimens shows the best proportion of admixture based on alkali-silica reactivity. Then, prediction of alkali-silica reaction of concrete has been investigated by using artificial neural network. In this study the backpropagation network has been used and compared with different algorithms to train network. Finally, the best amount of nano silica for adding to mix proportion, also the best algorithm and number of neurons in hidden layer of artificial neural network have been offered.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.84-87
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• 1995

Production of high strength concrete requires a low water-cement ratio and this leads to the high cement content. Mineral admixture like fly ash(FA) is often cheaper than ordinary portland cement(OPC) and this factor in combination with possible improvement in workability and moderation of the heat evolution of the cement-rich mixes tends to encourage its use. The other mineral admisture that its use has been widly advocated is silica fume that increases compressive strength due to its pozzolanic reaction. The objective of this study is to assess the contribution of mineral admixtures(FA, SF) to the workability and the strength of concrete with low water-binder ratios. In this experimental study that investigates and analyzes the properties of fresh concrete. it is presented that using admixtures like flyash and silica fume as binding material increases properties of high strength flowing concrete having very low water cementitious ratios of 0.25 and 0.30.

• Journal of the Korean Ceramic Society
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• v.27 no.3
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• pp.437-443
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• 1990

The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.