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A Study on Organic Solvent Measurement Using Diffusive Sampler (확산포집기를 이용한 공기 중 유기용제 포집에 관한 연구)

  • Park, Mi Jin;Yoon, Chung Sik;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.4 no.2
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    • pp.208-223
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    • 1994
  • The purpose of this study was to evaluate the efficiency of diffusive(or passive) sampler in measuring airbone organic solvents. Diffusive samplers are generally simple in construction and do not require power for operation. The efficiency of the diffusive samplers has not sufficiently been investigated in Korea. Three types of samplers were studied in this study. The sampling and analytical results by passive samplers were compared with results by charcoal tube method recommended by NIOSH(National Institute for Occupational Safty and Health). The following characteristics are identified and studied as critical to the performance passive monitors; recovery, reverse diffusion, storage stability, accuracy and precision, face velocity and humidity, n-Hexane, TCE(trichloroethylene) and toluene were used as test vapors. A dynamic vapor exposure system consisting of organic vapor generator and sampling chamber for evaluating diffusive samplers are made. The results of the study are summarized as follows. 1. NIOSH recommands that the overall accuracy of a sampling method in the range of 0.5 to 2.0 times the occupational health standard should be ${\pm}25$ percent for 95 percent confidence level. Among three types of diffusive samplers, sampler A has permeation membrane and samplers Band C have diffusive areas, samplers A and B met the criterion that overall accuracy for 95% confidence level of the samplers were within ${\pm}25$ percent of the reference value. Sampler C had overall accuracy ${\pm}9.6%$ and ${\pm}11.8%$ in hexane and TCE, respectively. The concentration of toluene was overestimated in sampler C with overall accuracy of ${\pm}43.9%$. 2. The desorption efficiencies of diffusive samplers were 96-107%. 3. There was no significant sampe loss during four weeks of storage both with and without refrigeration. 4. There was no significant reverse diffusion, when the samplers were exposure to clean air for 2 hours after sampling for 2 hours at the level of 2 TLY. 5. In case of 8 hours sampling, relative differences(RD) of concentrations between charcoal tube method and diffusive method were 15-39%, 13-46%, and 4-35% for sampler A, B and C, respectively. The performance was poor in 8 hours sampling for multiple substance monitors. 6. At high velocity(100 cm/sec), samplers B and C overestimated the concentrations of organic vapors, and sampler A with permeation membrance gave better results. 7. At 80% relative humidity, samplers showed no siginificant effect. Low humidity also did not affect the diffusive samplers.

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Prediction of NOx emission for marine gas engines (선박용 가스엔진의 NOx 배출량예측에 관한 연구)

  • Jang, Ha-Seek;Lee, Ji-Woong;Lee, Kang-Ki;Choi, Jae-Sung
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.658-665
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    • 2014
  • Natural gas for marine diesel engine is considered as an important and clean source of energy because of simultaneously reducing the emission of NOx, SOx and GHG. Especially with a appearance of shale gas, the using of natural gas has been investigated aggressively and expected to expand rapidly. By the reports, gas engine and diesel engine were both in a similar performance in the power aspect, and the SFOC of gas engine was shown a little better than that of diesel engine. But the characteristics of exhaust gas emission were different according to various combustion technologies. And with lean burn technology, the emission of NOx could be reduced to 85% lower than that of diesel engine. In this paper, it was described that a simulation program has been developed to predict NOx emission. The developed program is adopted two-zone model and Wiebe function for combustion in cylinder. The effects of premixed and diffusive combustion could be simulated by using the excess air ratio as input data. And it was confirmed that the results of simulation were agreed with the general trends of exhaust gas emission according to various combustion conditions such as lean burn, premixed and diffusive combustion.

The Study on the Combustion and Ash Deposition Characteristics of Ash Free Coal and Residue Coal in a Drop Tube Furnace (DTF를 이용한 무회분 석탄과 잔탄의 연소 및 회 점착 특성에 관한 연구)

  • Moon, Byeung Ho;Kim, Jin Ho;Sh, Lkhagvadorj;Kim, Gyu Bo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.89-96
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    • 2015
  • Recently, much research has been put into finding the causes and solutions of slagging/fouling problems that occur at the end of the boiler. This slagging/fouling, caused by low-rank coal's ash, disturbs the thermal power and greatly reduces efficiency. In environmental aspects, such as NOx pollution, governments have been implementing restrictions on the quantity of emission gases that can be released into the atmosphere. To solve these problems, research on Ash Free Coal (AFC), which eliminates ash from low-rank coal, is in progress. AFC has advantages over similar high-rank coals because it increases the heating value of the low grade coal, reduces the contaminants that are emitted, and decreases slagging/fouling problems. In this study, using a DTF, the changes of NOx emissions, unburned carbon, and the characteristics of ash deposition were identified. KCH raw coal, AFC extracted from KCH, residue coal, Glencore, and Mixed Coal (Glencore 85wt% and residue coal 15wt%) were studied. Results showed that AFC had a significantly lower emission of NOx compared to that of the raw coal and residue coal. Also, the residue coal showed a higher reactivity compared to raw coal. And finally, In the case of the residue coal and mixed coal, they showed a lower ash deposition than that of low-rank coal.

Field Tracer Experiments under Severe Wether Conditions for the Validation of the Dispersion of Radioactive Materials (방사능 확산 검증을 위한 악기상 조건에서의 추적자 야외확산 실증실험)

  • Han, Moon Hee;Kim, Eun Han;Jeong, Hyo Joon;Jeong, Hae Sun;Park, Mi Sun;Hwang, Won Tae
    • Journal of Radiation Protection and Research
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    • v.38 no.4
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    • pp.208-213
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    • 2013
  • The suitability of the site criteria is a basic requirement for securing safety of nuclear power plants. The suitability should be confirmed through the estimation of environmental radiation effects at the exclusion area boundary under the severe weather conditions. In this study, field tracer experiments over short range of 1 km radius under severe weather conditions were conducted at flat area in Daejeon. Severe weather conditions are represented with stable atmospheric condition and low wind speed. In general, the condition is appeared at clean night time with weak wind. The analysis of the measured distribution of the released tracer gas shows two big differences between the results of the past experiments conducted under the favorable weather conditions. One is the difficulty of finding the typical distribution of the released tracer gas with peak concentration in the downwind direction. The other one is the appearance of the contour of the concentration of tracer gas at several hundred meters even though the gas released at 10 m height over the ground.

The evaluation of effectiveness of 3DCA using vacuum bag(Vac-Lock) for patient immobilization device (3DCA제작을 통한 Vac-Lock 사용시 효율성향상에 대한 연구)

  • Lee YoungChul;Lee ChulBin;Kang NoHyun;Kim DongEuk;Lee JungYong;Jeong InPyo
    • The Journal of Korean Society for Radiation Therapy
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    • v.16 no.1
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    • pp.67-72
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    • 2004
  • Purpose : Patient immobilization is crucial factor for radiation therapy. Generally, we have been used vacuum bag immobilization device(Vac-Lock) for whole body immobilization. In order to easily set up of vacuum bag(Vac-Lock), we made a 3DCA(3-Dimensional Conformal Accessary). The purpose of this study is evaluation of effectiveness of 3DCA using Vack-Lock for patient immobilization. Materials and Methods : We made 3DCA(3-Dimensional Conformal Accessary) tool of wooden boards. The reasons to choice of wooden boards are its easily handling nature and cheap expenses. Results : (1) We reduced man power from $5{\sim}6$persons to 1person to make immobilizations, (2) Shortened work time from 1hour to within 10minutes. (3) Avoid a collision to treatment gantry head. (4) Its shapes are smart and clean. Conclusion : We have made and used 3DCA(3-Dimensional Conformal Accessary) tool was very effective and convenience for the patients and users.

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Pervaporation of Butanol from their Aqueous Solution using a PDMS-Zeolite Composite Membrane (PDMS-Zeolite 복합막을 이용한 부탄올 투과증발)

  • Kong, Chang-In;Cho, Moon-Hee;Lee, Yong-Taek
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.816-822
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    • 2011
  • Pervaporation is known to be a low energy consumption process since it needs only an electric power to maintain the permeate side in vacuum. Also, the pervaporation is an environmentally clean technology because it does not use the third material such as an entrainer for either an azeotropic distillation or an extractive distillation. In this study, Silicalite-1 particles are hydrothermally synthesized and polydimethylsiloxane(PDMS)-zeolite composite membranes are prepared with a mixture of synthesized Silicalite-1 particles and PDMS-polymer. They are used to separate n-butanol from its aqueous solution. Pervaporation characteristics such as a permeation flux and a separation factor are investigated as a function of the feed concentration and the weight % of Silicalite-1 particles in the membrane. A 1,000 $cm^3$ aqueous solution containing butanol of low mole fraction such as order of 0.001 was used as a feed to the membrane cell while the pressure of the permeation side was kept about 0.2~0.3 torr. When the butanol concentration in the feed solution was 0.015 mole fraction, the flux of n-butanol significantly increased from 14.5 g/ $m^2$/hr to 186.3 g/$m^2$/hr as the Silicalite-1 content increased from 0 wt% to 10 wt%, indicating that the Silicalite-1 molecular sieve improved the membrane permselectivity from 4.8 to 11.8 due to its unique crystalline microporous structure and its strong hydrophobicity. Consequently, the concentration of n-butanol in the permeate substantially increased from 0.07 to 0.15 mole fraction. This composite membrane could be potentially appliable for separation of n-butanol from insitu fermentation broth where n-butanol is produced at a fairly low concentration of 0.015 mole fraction.

Slope Stability Analysis of New Gabion Wall System with Vegetation Base Materials for Stream Bank Stability and Rehabilitation (계안 복원을 위한 식생기반재 돌망태 옹벽의 계안 안정효과 분석)

  • Choi, Hyung Tae;Jeong, Yong-Ho;Park, Jae-Hyeon
    • Journal of Korean Society of Forest Science
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    • v.101 no.1
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    • pp.130-137
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    • 2012
  • This study has conducted to develop new gabion wall systems with vegetation base materials for stream bank stability and rapid rehabilitation. Vegetation base materials are primarily compounded with fine soil, organic composts and peat moss as plant fibers, a water retainer and a soil improver. Normally gabion wall systems resist the lateral earth pressures or stream power by their own weight. Therefore, fill material must have suitable weight, compressive strength and durability to resist the loading, as well as the effects of water and weathering. In this project, 100 to 200-mm clean, hard stones are basically specified, and about 50-mm rubbles are also used. Test application of new gabion wall system carried out in the stream bank of a small stream in the Gwangreung experimental forest, belonging to Korea Forest Research Institute (KFRI) in December 16th, 2006. As a result of the analysis of hydraulic stability of new gabion wall system, gabion wall system has highest threshold shear stress when the gabion wall covered by vegetation. New gabion wall system is highly resistant to sliding and overturning because safety coefficients exceed 1.5. As a result of term of slope stability analysis of new gabion wall system by Bishop and Fellenius methods, stability of stream bank was highly increased after the construction of gabion wall. Therefore, new gabion wall system is effective to stabilize unstable stream bank.

Power Enhance Effect on the Hybrid Cell Based on Direct Current Nanogenerator and an Organic Photovoltaic Device

  • Yun, Gyu-Cheol;Sin, Gyeong-Sik;Lee, Geun-Yeong;Lee, Ju-Hyeok;Kim, Sang-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.298-298
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    • 2013
  • Finding renewable and clean energy resources is essential research to solve global warming and depletion of fossil fuels in modern society. Recently, complex harvesting of energy from multiple sources is available in our living environments using a single device has become highly desirable, representing a new trend in energy technologies. We report that when simultaneously driving the fusion and composite cells of two or more types, it is possible to make an affect the other cells to obtain a greater synergistic effect. To understand the coupling effect of photovoltaic and piezoelectric device, we fabricate the serially integrated hybrid cell (s-HC) based on organic solar cell (OSC) and piezoelectric nanogenerator (PNG). The size of increased voltage peaks when OSC and PNG are working on is larger than the case when only PNG is working. This voltage difference is the Voc change of OSC, not the voltage change of PNG and current density difference between these two cases is manifested more clearly. When the OSC and PNG are working in s-HC at the same time, piezoelectric potential (VPNG) is generated in ZnO and theoretical total voltage is sum of voltage of an OSC (VOSC) and VPNG. However, electrons from OSC are influenced by piezoelectric potential in ZnO and current loss of OSC in whole circuit decreases. As a result, VOSC increases temporarily. Current shows the similar behavior. PNG acts a resistance in the whole circuit and current loss occurs when the electrons from OSC pass through the PNG. But piezoelectric potential recover current loss and decrease the resistance of PNG. Our PNG can maintain piezoelectric potential when the strain is held owing to the LDH layer while general PNG cannot maintain piezoelectric potential. During the section that strain is held, voltage enhancement effect is maintained and same effect appeared even turn off the light. Actually at this time, electrons in ZnO nanosheets move to LDH and trapped by the positive charges in this layer. After this strain is held, piezoelectric potential of ZnO nanosheets is disappeared but potential difference which is developed by negative charge dominant LDH layer is remained. This potential acts similar role like piezoelectric potential in ZnO. Electrons from the OSC also are influenced by this potential and the more current flows.

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A Study on the Establishment of Allowable Criteria for Sailing Ships at Offshore Wind Farms (해상풍력발전단지해역 선박 통항 허용기준 설정에 관한 연구)

  • Ohn, Sung-Wook;Lee, Chang-Hyun;Kim, Cheol-Seong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.7
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    • pp.841-847
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    • 2018
  • Since global energy consumption and demand for energy have dramatically risen, a focus on environmental problems and sustainability has become more important. Clean and renewable energy sources such as offshore wind power generation have received attention among new renewable energy options as alternative energy resources. Due to maintenance and operational perspectives, offshore wind farms have been planned for installation in many coastal waters. However, development of offshore wind farms faces interference from existing maritime traffic along the planned areas. In order to safely and effectively govern marine traffic in the vicinity of wind farms and inner areas, standard criteria are suggested to allow vessels to sail the internal waters of offshore wind farm areas. Therefore, the purpose of this study is to establish allowable criteria for sailing vessels and safety zones for offshore wind farms by investigating the local regulations of various offshore wind farm cases overseas. The commended inner safety zone of wind farms is proposed to be a distance of 150 % of the rotation diameter of the wind turbine rotor and a distance of 200 m from the outer wind turbine for the outer safety zone. Besides this, the allowable criteria for sailing vessels within a wind farm is proposed to have an air draft of 14.47 m south-west wind farm sea areas for a minimum margin to avoid hull contact through evaluation of the tide and height of a wind turbine. further studies will be needed to establish vessel sailing criteria among adjacent offshore wind farms as well as vessel sailing criteria within a single offshore wind farm.

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.