• Title/Summary/Keyword: Potassium arsenite

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Effect of Arsenic Types in Soil on Growth and Arsenic Accumulation of Pteris multifida (토양 비소 오염원의 종류가 봉의꼬리의 생육 및 비소 축적에 미치는 영향)

  • Han, Ji Hyun;Kwon, Hyuk Joon;Lee, Cheol Hee
    • Korean Journal of Plant Resources
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    • v.27 no.4
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    • pp.344-353
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    • 2014
  • This study was carried out to analyze the effect of arsenic types on growth and arsenic accumulation ability of Pteris multifida. Among arsenic pollution sources, Sodium arsenate, Calcium arsenate, Sodium arsenite and Potassium arsenite were treated in horticultural compost contaminated with $500mg{\cdot}kg^{-1}$. P. multifida was cultivated for 12 weeks. The results of study, Calcium arsenate treatment showed slightly decreased growth of P. multifida. But, growth of P. multifida cultivated in the remaining arsenic treatment was similar to untreated control plot. With only short-term cultivation of 4 weeks, aerial part of P. multifida in Sodium arsenate treatment showed high arsenic accumulation of $2,289.5mg{\cdot}kg^{-1}DW$. The arsenic accumulation ($2,956.0mg{\cdot}kg^{-1}DW$) was the highest at 12 week. On the other hand, underground part showed the highest arsenic accumulation in Potassium arsenite treatment ($2,470.2mg{\cdot}kg^{-1}DW$) and Calcium arsenate treatment accumulated $1,060.7mg{\cdot}kg^{-1}DW$ of arsenic. Regardless of arsenic types, aerial part of P. multifida was absorbed more than $1000mg{\cdot}kg^{-1}DW$ of arsenic. And removal of arsenic in soil was also higher. Therefore, Pteris multida is considered to be suitable phytoremediation meterial of various arsenic contaminated areas.

Desorption and Oxidation Properties of Saturated Arsenate on LDHs (하이드로탈사이트류에 포화 흡착된 비소(V)의 탈착 및 산화 특성)

  • Park, Soon-Geel;Jung, Yong-Jun
    • Journal of Environmental Science International
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    • v.24 no.8
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    • pp.1015-1021
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    • 2015
  • In order to establish the design parameters of adsorption for arsenic compounds with hydrotalcite including chlorine ion, the basic properties of adsorption and desorption as well as the oxidation of As (III) were examined in batch tests. The maximum adsorption capacities of arsenite and arsenate were 6.2 mg-As(III)/g and 103 mg-As (V)/g, respectively. Although 80.4% of maximum desorption was shown in 20% NaOH solution, 5~10% of NaOH was recommended considering operating benefits, where the proper condition of the desorption was in the range of 73% to 80%. The most suitable desorption condition was in the combination of NaCl (10~20%) and NaOH (5~10%). Within 2 minutes, As (III) was easily oxidized to As (V) with 0.0001 N KMnO4, where the maximum oxidization ratio was shown to 98.9%.