• 한국재료학회지
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• 제19권12호
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• pp.644-648
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• 2009

Temperature dependency of resistivity of the carbon black-polyethylene composites below and above percolation threshold is studied based on the electrical conduction mechanism. Temperature coefficient of resistance of the composites below percolation threshold changed from minus to plus, increasing volume fraction of carbon black; this trend decreased with increasing volume fraction of carbon black. The temperature dependence of resistivity of the composites below percolation threshold can be explained with a tunneling conduction model by incorporating the effect of thermal expansion of the composites into a tunneling gap. Temperature coefficient of resistance of the composites above percolation threshold was positive and its absolute value increased with increasing volume fraction of carbon black. By assuming that the electrical conduction through percolating paths is a thermally activated process and by incorporating the effect of thermal expansion into the volume fraction of carbon black, the temperature dependency of the resistivity above percolation threshold has been well explained without violating the universal law of conductivity. The apparent activation energy is estimated to be 0.14 eV.

• E2M - 전기 전자와 첨단 소재
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• 제9권5호
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• pp.439-444
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• 1996

0.15(B $a_{0.95}$ S $r_{0.05}$)O-0.15(S $m_{2(1-x}$/N $d_{2x}$) $O_{3}$-0.7Ti $O_{2}$(x=0-10[m/o]) ceramics were fabricated by mixed oxide method. Microwave dielectric properties were investigated with contents of N $d_{2}$ $O_{3}$. In the case of specimen with N $d_{2}$ $O_{3}$(6[m/o]), dielectric constant, quality factor and temperature coefficient of resonant frequency were 78.14, 2938(at 3[GHz]) and +14.19[ppm/.deg. C], respectively. By comparison its properties with undoped specimen, dielectric constant and quality factor were highly improved, but the temperature coefficient of resonant frequency was increased to positive value......

• 대한기계학회논문집B
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• 제40권2호
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• pp.103-110
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• 2016

나노유체의 대류열전달 성능을 평가하는 센서로서 가는 백금 열선이 많이 사용되었다. 그러나 센서의 강도가 약해서 취급에 주의가 필요하고 측정실험에서 센서에 대한 엄밀한 교정과정을 생략하거나 정밀도 높은 기구들을 사용하지 않으면 비현실적인 대류열전달계수가 얻어졌다. 본 연구에서는 백금 열선 대신 더미스터 센서를 채택한 새로운 나노유체 대류 성능 평가장치를 제안하였고 그 작동 원리를 자세히 설명하였다. 순수 엔진오일에 대한 두 센서의 비교 실험을 통하여 더미스터 센서의 실용적 장점을 확인할 수 있었다. 제안된 장치는 개발된 나노유체의 채택 여부를 판단하는 유용한 도구로 사용될 수 있을 것이다.

• 한국전기전자재료학회논문지
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• 제20권6호
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• pp.496-501
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• 2007

In order to enhance sintering characteristics on the $ZnO-Pr_6O_{11}$ based multilayer chip varistors (MLVs), a response surface analysis using central composite design method were carried out. As a result, varistor voltage($V_{1mA}$), nonlinear coefficient ($\alpha$), leakage current ($I_L$) and capacitance (C) were considered to be mainly affected by sintered temperature and holding time. MLVs sintered at $1200^{\circ}C$ and above $1200^{\circ}C$ revealed poor electrical characteristics, possibly due to the reaction between electrode materials(Pd) and $ZnO-Pr_6O_{11}$ based ceramics. On the sintering temperature range $1150{\sim}1175^{\circ}C$, nonlinear coefficient ($\alpha$) and leakage current ($I_L$) were shown to be $60{\sim}69$ and below $0.3{\mu}A$, respectively. In particular, MLVs sintered at $1175^{\circ}C$, 1.5 hr and $2^{\circ}C/hr$ (cooling speed) showed stable ESD(Electrical Static Discharge) characteristics under the condition of 10 times at 8 Kv with deviation varistor voltage, and deviation nonlinear coefficient were 0.3% and 0.33% (at positive), 0.55% (at negative), respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.376-377
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• 2008

저압계동의 고장전류를 차단하기 위해서, 기중차단기(ACB), 배선용차단기(MCCB) 등을 사용하고 있는데, 저압차단기는 저압계통의 고장전류를 차단할 수 있으나, 고장전류를 효과적으로 제한하지 못하며, 차단기 내부의 아킹시간이 상대적으로 길므로, 저압차단기는 물론 주변 전력기기에 전기적/열적/기계적 스트레스를 주게 된다. 또한 지속적인 부하의 증가로 인해 저압계통의 단락전류는 점점 증가하는 추세에 있으므로 저압계통은 물론 고압계통에서도 고장전류를 보다 빠르고 효과적으로 제한 및 차단을 할 수 있는 한류형 차단기가 제안되고 있다. 저압계통의 경우, 정온도계수(Positive Temperature Coefficient, PTC) 특성을 가지는 한류소자를 기존 차단기에 직렬 혹은 병렬로 연결하여 저압계동의 고장전류를 매우 빠르고 효과적으로 제한 및 차단하는 추세이다. 본 연구에서는 정온도계수 특성을 가지는 소자를 이용하여 소형 저압차단기의 차단용량 향상에 기여할 수 있는지 검증하였다.

• Journal of Photoscience
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• 제4권3호
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• pp.105-112
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• 1997

The fluorescence quenching of 2, 5-di-(5-tert-butyl-2-benzoxazolyl)-thiophene (BBOT) by aniline in five different solvents namely heptane, hexane, cyclohexane, dioxane and acetonitrile has been carried out at room temperature with a view to understand the quenching mechanisms. The experimental results show positive deviation in the Stern-Volmer plots in all the solvents. In order to interpret these results we have invoked the Ground state complex and sphere of action static quenching models. Using these models various rate parameters have been determined. The magnitudes of these parameters suggest that sphere of action static quenching model agrees well with the experimental results. Hence this positive deviation is attributed to the static and dynamic quenching. Further, with the use of Finite Sink approximation model, it was possible to check these bimolecular reactions as diffusion-limited and to estimate independently distance parameter R$^1$ and mutual diffusion coefficient D. Finally an attempt has been made to correlate the values of R$^1$ and D with the values of the encounter distance R and the mutual diffusion coefficient D determined using the Edward's empirical relation and Stokes-Einstein relation.

• 한국재료학회지
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• 제22권12호
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• pp.658-663
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• 2012

The electrical properties of a laminated SMD type PTC thermistor for microcircuit protection were investigated as a function of polymer blowing agent addition. Green ceramics for multilayered $BaTiO_3$-based PTCRs were formed by doctor blade method of barium titanate powders; we successfully laminated the sintered ceramic chips to obtain 10 layer chip PTCRs with PTC effect. The sintered density increases with increasing sintering temperature. The electrical properties of the sintered samples were strongly dependent on the calcination and addition of a polymer blowing agent. When $BaTiO_3$ powders containing 0.2 mol% of $Y_2O_3$ were calcined at $1000^{\circ}C$ for 2 hrs, the resistivity jump was of 1-2 orders of magnitude. The resistivity at room temperature increases according to the polymer blowing agent addition. Also, the sample using the calcined powder showed a lower resistivity than that of the sample prepared using powders without calcinations. With an increase in the OBSH, the magnitude of the resistivity jumped as a function of the temperature increase. The resistivity of the sintered bodies after the addition of 0.5 wt% polymer blowing agent at $1290^{\circ}C$ for 2 h was shown to be about $8.5{\Omega}{\cdot}cm$; the jump order of the sintered bodies was shown to be on the order of $10^2$.

• 한국콘텐츠학회논문지
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• 제18권10호
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• pp.425-430
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• 2018

전기자동차 배터리 시스템은 낮은 온도에서 배터리 출력과 수명이 감소하는 문제가 발생한다. 상온 유지를 목적으로 Positive Temperature Coefficient(PTC) 히터가 사용되고 있다. 하지만 PTC 히터는 복잡한 절연구조로 인해 중량이 크다. 중량이 클수록 전기자동차의 연비가 감소한다. 반면에 인덕션 히터는 단순한 절연 구조로 중량 저감에 효과적이며 빠른 온도 상승 특성을 가지고 있다. 따라서 전기자동차용 히터는 인덕션 히터가 적합하다. 인덕션 히터는 LC공진 회로로 구성된다. 정전용량이 클수록 가격과 중량이 상승하기 때문에 인덕턴스를 높여 정전용량을 감소시켜야한다. 또한 인덕션 히터의 주 발열원은 철손이다. 따라서 전자기장 설계 관점에서 인덕턴스 및 철손의 최적화가 중요하다. 본 논문에서는 인덕션 히터 구조 변경에 따른 인덕턴스 및 철손을 다구찌 기법과 유한요소법(FEM) 시뮬레이션을 통해 분석하고 최적화 설계하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
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• pp.293-295
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• 1994

Barium Titanate ($BaTiO_3$) is one of the few titanateds which is cubic at room temperature. It has the perovskite structure, high dielectric constant (${\varepsilon}_r=300$) and a small temperature coefficient of resistance due to it's Low transition temperature ($Tc=120^{\circ}c$). PTCR (Positive Temperature Coefficient of Resistivity) thermistor in thin film $BaTiO_3$ system was prepared by using radio frequency (13.56MHz) and BC magnetron sputter equipment. Polycrystalline, and surface structure characteristics of the specimens were measured by X-ray diffraction (D-Max3, Rigaku, Japan), SEM(Scanning Electron Microscopy: M. JSM84 01, Japan), respectively. Temperature at below $600^{\circ}C$, $1000^{\circ}C$ to $700^{\circ}C$, and above $1100^{\circ}C$ for spotted $BaTiO_3$ thin films showed the amorphous, degree of crystal growth, and polycrystalline, respectively.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권9호
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• pp.510-515
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• 2000

The mechanical and electrical properties of the hot-pressed and annealed $\beta-SiC-TiB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of Al_2O_3+Y_2O_34. The result of phase analysis of composites by XRD revealed $\alpha-SIC(6H)\;TiB_2,\; and YAG(Al5Y3O12) crystal phase. The relative density and the mechanical properties of composites were increased with increasing $Al_2O_3+Y_2O_34 contents because YAG of reaction between $Al_2O_3\; and\; Y_2O_3$ was increased. The Flexural strength showed the highest value of 432.5MPa for composites added with 12wt% $Al_2O_3+Y_2O_34 additives at room temperature. Owing to crack deflection crack bridging phase transition and TAG of fracture toughness mechanism the fracture toughness showed 7.1MPa.m1/2 for composites added with 12wt% $Al_2O_3+Y_2O_34 additives at room temperature. The electrical resistivity and the resistance temperature coefficient showed the lowest of $6.0\times10-4\Omega.cm\; and\; 3.1\times10-3/^{\circ}C4 respectively for composite added with 12wt% \Omega additives at room temperature. The electrical resistivity of the composites was all positive temperature coefficient resistance (PTCR) in the temperature range of $25^{\circ}C\; to\; 700^{\circ}C$.