• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.163-169
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• 1997

The sea water resistance of cement and concrete must be considered when it is used for construction on the seashore of in the ocean. The concrete specimens using seven type of cements such as ordinary Portland cement, moderate heat Portland cement, sulfate resistance Portland cement, type A. B. C Portland blastfurnace slag cement and Portland flyash cement were immersed for 10 years in seawater in Kunsan. This study proved that moderate heat Portland cement, sulfate resistance Portland cement, type A Portland blastfurnace slag cement had higher resistance for seawater.

• Journal of Dental Rehabilitation and Applied Science
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• v.23 no.1
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• pp.79-84
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• 2007

Mineral Trioxide Aggregate(MTA) has been used in Endodontic treatment successfully for more than 10 years. But the high cost of MTA limits its use in endodontics in Korea. Recently many studies have been done to compare MTA and Portland cements. To investigate the chemical constitutions of MTA (Proroot MTA, Tulsa Dental), Gray Portland cement (Lafarge Halla cement), White Portland cement(Union corp), and fast setting cement (SSangyong cement), we performed SEM(scanning electron microscope)(S4700, Hitachi) examination and EDS(Energy dispersive spectrometry)(emax, Horiba) analysis. SEM examination and EDS analysis were committed to and performed in SNU DRI (Seoul National University Dental Research Institute). We found that particles of MTA were relatively round, uniform in size, and compactly packed compared to Portland cements. Chemical constitutions of MTA, GPC, WPC and FSC were similar. It was shown that MTA contains much BiO2 . MTA and WPC showed less heavy metals such as Fe and Mg compared to GPC and FSC. FSC showed remarkably high aluminum content.

• Journal of the Korean Ceramic Society
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• v.49 no.3
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• pp.260-265
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• 2012

Impedance spectroscopy was used to monitor the hydration in the electrical/dielectric behaviors of chemical mechanical planarization (CMP)-blended cement mixtures. The electrical responses were analyzed using their equivalent circuit models, leading to the separation of the bulk and electrode based responses. The role of the CMP slurry was monitored as a function of the relative compositions of the CMP-blended cements, i.e. water, CMP slurry, and ordinary Portland cement. The presence of $Al_2O_3$ nanocrystals in the CMP slurries appeared to accelerate the hydration process, along with a more tortuous microstructure in the hydration, with enhanced hydration products. The frequency-dependent impedance spectroscopy was proven to be a highly efficient approach for evaluating the electrical/dielectric monitoring of the change in the pore structure evolution that occurs in CMP-blended cements.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04b
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• pp.687-692
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• 1998

This paper covers concrete durability made with portland cement type I and V, and granulated blast furnace slag blended cements 40 and 60%. Typical properties of cements and compressive strength development, drying shrinkage, carbonation, freezing and thawing properties of concretes were investigated. In addition, effects of CI penetration on various concretes with/without a freezing and thawing treatment were also studied. Portland cement type I and V were superior to the blended cement in the properties of compressive strength development, drying shrinkage, carbonation and freezing and thawing durability. In the respect of resistant of CI Blended cement showed better than the portland cement due to high permeability. But the blended cement with a freezing and thawing treatment presented a much decreased resistance of CI penetration.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.05a
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• pp.289-294
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• 2001

This study concerns the cement-solidification/stabilization of the waste with high concentration heavy metals. Compressive strength and leaching test of heavy metals were evaluated for ing types of cements and the effect of the additives of Hauyne clinker and slag were also cussed. Using ordinary portland cement, rapid hardening portland cement and the cement with additives solidification materials, it shows that the strength and stability of concrete is satisfactory and superiority is in the order of rapid hardening portland cement > the cement with additives > nary portland cements.

• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.609-616
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• 1989

For the development of high durable portland cement, it was tested that the some physical properties of ordinary portland cements (OPC) treated with 0.3-1.5wt.% asphalt and 0.5-1.0wt.% carbon black. From the results, the contact angles of water against cements treated with more than 0.6wt.% asphalt were increased over 80 degrees, the initial and the final setting times of cement paste were delayed about 20min. according to the every 0.3wt.% increase of asphalt. The first and the second pick heights of the hydration curve of the cement were considerabely decreased and the induction period of that was increased. And so, the cumulative hydration heat of the cement which was treated with 0.6wt.% asphalt and 0.5wt.% carbon black was lower about 10cal/g than that of ordinary portland cement during 42 hydration times.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.293-298
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• 1997

Corrosion of steel reinforcing in concrete deteriorated by freezing/thawing and carbonation was characterized. Concrete specimens were prepared using various kinds of cements such as ordinary portland cement (type I), low heat portland cement (type IV, belite rich cement), sulphate resistance portland cement (type V), blast furnace slag portland cement and ternary blended cement. Of various cements, type V and type IV with lower $C_3A$ content revealed better steel corrosion resistance after freezing/thawing and carbonation. $C_3A$ content in cement might affect freezing/thawing resistance in sea water.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.490-494
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• 2011

This paper reports the use of supplementary cementing materials (SCMs) derived from local resources, for the partial replacement of Portland cement to reduce $CO_2$ emission during cement production. Replacement of Portland clinkers up to 20 wt.% with SCMs in normal cements reduced $CO_2$ emission by 0.18 kg $CO_2$/kg. The compressive strength exceeded the standard specification for Portland cement ASTM C-150. Blended cement samples containing 20% Portland clinker replacement had compressive strengths of 37 MPa after 28 days of curing time. The microstructure evolution of blended cement at a composition of 80:20 was similar to that of the 100% Portland cement, where the structure between days 28 and 56 reached a steady state. Blended cements with compositions of 70:30 and 60:40 still showed progress of CSH plate formation and the lack of massive structure development. It is shown that the use of supplementary cementing materials could be as one of alternative ways to reduce $CO_2$ emissions during cement production.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.641-644
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• 2006

Considering properties of the low-heat concrete mixed with the blended cements, the influences compared blended cements with ordinary portland cement made experiments on. (1) Blended cements were superior to OPC in the fresh concrete flow that the use of blended cements reduced chemical admixture. (2) The more the use of additive increase, the more bleeding happens. So it is considered to heights, order, and rate of placement, curing methods and so on. (3) The use of blended cements increase long term strength after 28 days, but decrease early strength and durability. So it is considered to the curing methods and early frost damage, and endurance limit.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.714-717
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• 2000

To consider sulfate resistance of cement pastes and motars for 3 types of portland cements which have different $C_3A$ contents an silicate ratio($C_3S/C_2S$), they were immersed in 5% sodium sulfate solution for 400 days. SEM analysis and ($Ca(OH)_2$ contents of cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of ($C_3$ and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement pastes, and compressive strength and length change of cement mortars, were performed to investigate the effects of C3A and ($Ca(OH)_2$ contents. According to the results of this study, low heat portland cement had a good sulfate resistances because of a small quantity of gypsum and ettringite due to less ($Ca(OH)_2$ contents. However, ordinary portland cement had an adverse result. This was also confirmed by SEM analysis.