• 제목/요약/키워드: Porous surface

검색결과 1,500건 처리시간 0.044초

공유결합으로 다공성 막에 고정화된 효소에 의한 이산화탄소 포집 (Carbon Dioxide Sequestration of Enzyme Covalently Immobilized on Porous Membrane)

  • 박진원
    • KSBB Journal
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    • 제28권4호
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    • pp.225-229
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    • 2013
  • Bovine Carbonic anhydrase (BCA) was immobilized on a submicro-porous membrane through covalent immobilization. The immobilization was conducted on the porous membrane surface with the treatment of polyethyleneimine, glutaraldehyde, and the anhydrase, in sequence. The immobilization was confirmed using X-ray photon spectrometer. The pH values of carbon-dioxide saturated solution with buffer were monitored with respect to time to calculate the catalytic activities of hydration of carbon-dioxide for free and immobilized CA. The catalytic rate constant values for free CA, immobilized CA on polystyrene nanoparticles, and immobilized CA on a porous cellulose acetate membrane were 0.79, 0.67, and 0.56 $s^{-1}$, respectively. Reusability was studied up to 10 cycles of $CO_2$ sequestration. The activity for the CA immobilized on the membrane was kept to 95% after 10 cycles, and comparable to the CA on the nanoparticles. The stabilities for heat and storage were also investigated for the three cases. The results suggested that the CA immobilized the membrane had the least loss rate of the activity compared to the others. From this study, the porous membrane was feasible as a carrier for the CA immobilization in hydration and sequestration of carbon-dioxide.

고분자 복제 템플릿 방법을 이용하여 제조된 다공성 탄화규소의 미세구조 특성 (Characterization of Microstructure on Porous Silicon Carbide Prepared by Polymer Replica Template Method)

  • 이윤주;김수룡;김영희;신동근;원지연;권우택
    • 한국세라믹학회지
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    • 제51권6호
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    • pp.539-543
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    • 2014
  • Foam type porous silicon carbide ceramics were fabricated by a polymer replica method using polyurethane foam, carbon black, phenol resin, and silicon powder as raw materials. The influence of the C/Si mole ratio of the ceramic slurry and heat treatment temperature on the porous silicon carbide microstructure was investigated. To characterize the microstructure of porous silicon carbide ceramics, BET, bulk density, X-ray Powder Diffraction (XRD), and Scanning Electron Microscope (SEM) analyses were employed. The results revealed that the surface area of the porous silicon carbide ceramics decreases with increased heat treatment temperature and carbon content at the $2^{nd}$ heat treatment stage. The addition of carbon to the ceramic slurry, which was composed of phenol resin and silicon powder, enhanced the direct carbonization reaction of silicon. This is ascribed to a consequent decrease of the wetting angles of carbon to silicon with increasing heat treatment temperature.

Fractional order GL model on thermoelastic interaction in porous media due to pulse heat flux

  • Alzahrani, Faris S.;Abbas, Ibrahim A.
    • Geomechanics and Engineering
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    • 제23권3호
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    • pp.217-225
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    • 2020
  • In this paper, the thermoelastic interactions in a two-dimension porous body are studied. This problem is solved by using the Green and Lindsay (GL) generalized thermoelasticity model under fractional time derivative. The derived approaches are estimated. with numeral results which are applied to the porous mediums in simplifying geometrical. The bounding plane surface of the present half-space continuum is subjected to a pulse heat flux. We use the Laplace-Fourier transforms methods with the eigenvalues approach to solve the problem. The numerical solutions for the field functions are obtained numerically using the numerical Laplace inversion technique. The effects of the fractional parameter and the thermal relaxation times on the temperature field, the displacement field, the change in volume fraction field of voids distribution and the stress fields have been calculated and displayed graphically and the obtained results are discussed.

다공성 매질의 건조 해석 (COMPUTATIONAL ANALYSIS ON DRYING OF POROUS MEDIA)

  • 이주석;이창환;배영민;문영준
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2009년 추계학술대회논문집
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    • pp.145-150
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    • 2009
  • In this study, characteristics of microwave and convective drying are studied by using a multiphase porous media model. Temperature and moisture profiles for hot-air convective heating and microwave heating of 1-D porous media with varying time and space are numerically investigated. This result shows the microwave drying method is more effective than the convective drying method. Comparing to convective drying, microwave drying can increase temperature and evaporation rate significantly since microwave generates internal heat and increases internal pressure, which results in moisture movement toward the surface on which moisture is vaporized.

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재생골재를 사용한 포러스 콘크리트의 수질정화 특성에 관한 실험적 연구 (An Experimental Study on Water-Purification Properties of Porous Concrete Utilizing Recycled Aggregate)

  • 김정환;조광연;조청휘;이봉춘;박승범
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.925-928
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    • 2001
  • Recently great efforts and investment have been made in order to achieve economical production by applying new methods like minimization of man-Power into construction field. This paper describe the performance of water purification, to which living organisms can adapt, and the physical properties of porous concrete with continuous voids. Although conventional concrete has been regarded as a destroyer of nature, water and air can pass freely through concrete when it is made porous by forming continuous voids. this not only enables plants to vegetables, but also makes it possible for microscopic animals and plants, including bacteria, to attach to and inhabit uneven surface as well as internal voids when the concrete is provided in a natural water area or waterside area. As a result, Porous concrete using recycled aggregate improved the performance of water purification.

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Pressure Effect on Safranine Penetration in Some Hardwood Species

  • Chong, Song-Ho;Ahmed, Sheikh Ali;Park, Byung-Su;Chun, Su-Kyoung
    • 한국가구학회지
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    • 제18권2호
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    • pp.111-119
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    • 2007
  • An experiment was conducted to know the safranine impregnation distance from surface to inward using 6 different hardwood species. During impregnation, 3 parameters were applied-vacuum, pressure and soaking time. Only vacuum treatment did not increase the permeability of wood. Vacuum followed by pressure increased the penetration depth of safranine in radial, tangential and longitudinal direction. Longitudinal penetration was found easy to impregnate. Comparing with radial and tangential direction, radial penetration was found easy. There was a striking difference among sapwood and heartwood permeability. Safranine input depth was found highest in diffused porous wood rather than in ring porous wood. At increased vacuum and pressure, safranine penetration was found easy.

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도핑농도의 선택도를 이용한 국부적 다공질 실리콘의 형성 (Localized formation of porous silicon usin gdoping concentration selectivity)

  • 이주혁;김성진;이성필;이철진;최복길;박천만;심관수
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 하계종합학술대회논문집
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    • pp.465-468
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    • 1998
  • For porous silicon layer to be used as active layer in various devices, it is necessary to be formed locally along with a designed pattern on the wafer. However, there is still no suitable masking layer to withstand against the high concentration of HF for a time of some minutes up to some hours during the anodic process effectively. In this work, we investigated the property of selectivity between p$^{+}$ and n layers to form localized porous silicon even without a mask by the difference of the anodic I-V characteristics on the doping level and doping type. The width of the pattern made in the sample was 2mm, and the formed porous silicon layer was observed by SEM to see the morphology on the cross section below the surface. As the results, it was found that the selectivity was reasonable for the pattern size over 100.mu.m.m.

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다공성 세라믹스와 다공질층을 포함하는 적층세라믹스의 제조에 관한 연구;II. 불균일 적층소결체 (Fabrication of Porous Ceramics and Multilayered Ceramics Containing Porous Layers; II. Heterogeneous Laminates)

  • 이해원;윤복규;송휴섭
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1323-1329
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    • 1994
  • Tape casting and lamination were used to produce heterogeneous laminates with alternating layers of different porosity and homogeneous laminates with component layers of the same porosity. The pore structure was investigated for heterogeneous laminates, and bend strength was measured for comparison with that of homogeneous laminates. For a reference, strength measurement was made for the porous body fabricated by sintering samples dry-pressed at low pressure with spray-dried granules. Strength increase, in the range 50~120 MPa, was achieved in the presence of the surface dense layer, while extensive delamination, presumably responsible for enhanced fracture toughness, took place through the internal porous layer.

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OPTICAL CHARACTERISTICS OF POROUS SILICON CARBIDE BY PHOTOLUMINESCENCE SPECTROSCOPY

  • Lee, Ki-Hwan;Du, Ying-Lei;Lee, Tae-Ho
    • Journal of Photoscience
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    • 제6권4호
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    • pp.183-186
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    • 1999
  • We have been prepared the porous silicon carbide (PSC) by electrochemical etching of silicon carbide single crystals. Samples of PSC have been studied by the methods of scanning electron microscope (SEM) and photoluminescence (PL). Two PL bands attributed to the blue and green light emission were observed in this study. According to the anodization conditions, the main source of emission in the oxidized layers of PSC lies in the different surface defect centers which consist of different geometrical structures due to the polytypes. It means that origin of these PL bands may be existed in different size pores simultaneously. The present results indicate that the high energy band comes from the top porous layers while the low energy band comes from the lower porous layers.

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