• Corrosion Science and Technology
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• 제9권5호
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• pp.196-200
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• 2010

Recently porous metal has been used as supporting metal in planar type SOFC. In order to search optimum alloys for porous metal support and estimate the stability of metal-supported SOFC at high temperature, it is necessary to investigate the oxidation behaviors of porous material for metal support in comparison with dense material. Oxidation tests of porous and dense stainless steels were conducted at $600^{\circ}C$ and $800^{\circ}C$. Since the specific surface area of porous material is much larger than that of dense material, surface area should be considered in order to compare the oxidation rate of porous stainless steel with that of dense stainless steel. The specific surface area of porous body was measured using image analyzer. The weight gain of porous stainless steel was much greater than those of dense stainless steels due to its larger specific surface area. considering the specific surface area, the oxidation rate of porous stainless steel is likely to be the same as that of dense stainless steel with the same surface area. The change in chromium content in stainless steel during oxidation was also investigated. The experimental result in chromium content in stainless steel during oxidation corresponded with the calculated value. While the change in chromium content in dense stainless steel during oxidation is negligible, chromium content in porous stainless steel rapidly decreases with oxidation time due to its large specific surface area. The significant decrease in chromium content in porous stainless steel during oxidation may affect the oxidation resistance of porous stainless steel support and long term stability of metal-supported SOFC.

• 통합자연과학논문집
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• 제4권3호
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• pp.182-186
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• 2011

Chemical modification of porous silicon surface has been investigated to have different physical surface properties. Porous silicon modified with dodecyl functionality exhibits hydrophobic feature, however the oxidation of porous silicon to modify with hydroxyl group displays hydrophilic properties. Surface characterization for both dodecyl and hydroxyl derivatized porous silicon was investigated by FT-IR spectroscopy. To determine the surface coverage, the amine functionalized surface was reduced by dithiothreitol (DTT) and the released 2-thiopyridone was quantified by UV/vis spectroscopy.

• 통합자연과학논문집
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• 제3권3호
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• pp.148-152
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• 2010

Photoluminescence properties and surface morphologies of porous silicon etched with various applied current densities at fixed etching times. FE-SEM image of porous silicon surface indicated that the porous silicon prepared at currents below 200 mA exhibited very bright red photoluminescence properties. As the applied current densities increased, the photoluminescence efficiencies of porous silicon prepared at applied current densities above 300 mA decreased, and displayed the cracked surface on porous silicon. This cracked surface start to collapsed to give cracked domains.

• 설비공학논문집
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• 제17권1호
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• pp.25-32
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• 2005

Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface forming thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this work, the surface is treated to have thin porous layer on the surface. With this treatment, the liquid can be spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of an inclined surface has been conducted to verify the effectiveness of the surface treatment. It is measured that the evaporative heat transfer increases about $50\%$ by the porous layer treatment as compared with that from orignal bare surfaces.

• 한국세라믹학회지
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• 제45권12호
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• pp.832-838
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• 2008

Diatomite, bentonite and zeolite were used as porous materials for fabricating hygroscopic panels. Moisture adsorption and desorption of porous materials were investigated and hydrothermal method was applied to fabricate panels. Cheolwon diatomite and Pohang zeolite showed excellent characteristics of moisture adsorption and desorption. These characteristics were caused by higher surface area and pore volume of porous materials. Correlation coefficient between surface area and moisture adsorption content of porous materials was 0.93. Moisture adsorption contents were influenced by surface area and pore volume of panels, and surface area more effected on moisture adsorption. Correlation coefficient between surface area and moisture adsorption content of panels was 0.86. Moisture adsorption content of panel with 10% Pohang zeolite was $180\;g/m^2$ and that of 10% Cheolwon diatomite was $170\;g/m^2$. Moisture desorption content of panel with 10% Pohang zeolite was $105\;g/m^2$. Moisture adsorption contents of panel with porous materials were higher than that of panel without porous materials.

• 통합자연과학논문집
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• 제6권2호
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• pp.82-86
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• 2013

This paper describes a method for the preparation of porous polymethylmethacrylate showing optical reflectivity from the porous silicon template. A porous polymethylmethacrylate showing optical reflectivity was prepared by replicating porous silicon template which was obtained by applying a computer-generated periodic square current density and resulted in a mirror with high reflectivity in a specific narrow spectral region. A porous polymethylmethacrylate showing an excellent reflectivity was successfully obtained by dissolving the Porous silicon template from the porous polymethylmethacrylate composite film. A porous polymethylmethacrylate exhibited a sharp reflection resonance in the reflectivity spectrum. Surface image of the porous polymethylmethacrylate indicated that the surface of the porous polymethylmethacrylate film had a porous structure. These porous polymethylmethacrylate films in aqueous solutions were stable for several days without any degradation.

• 신재생에너지
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• 제2권2호
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• pp.4-8
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• 2006

Reduction of optical losses in crystalline silicon solar cells by surface modification is one of the most important issues of silicon photovoltaics. Porous Si layers on the front surface of textured Si substrates have been investigated with the aim of improving the optical losses of the solar cells, because an anti-reflection coating and a surface passivation can be obtained simultaneously in one process. We have demonstrated the feasibility of a very efficient porous Si AR layer, prepared by a simple, cost effective, electrochemical etching method. Silicon p-type CZ (100) oriented wafers were textured by anisotropic etching in sodium carbonate solution. Then, the porous Si layer were formed by electrochemical etching in HF solutions. After that, the properties of porous Si in terms of morphology, structure and reflectance are summarized. The surface morphology of porous Si layers were investigated using SEM. The formation of a porous Si layer about $0.1{\mu}m$ thick on the textured silicon wafer result in an effective reflectance coefficient Reff lower than 5% in the wavelength region from 400 to 1000nm. Such a surface modification allows improving the Si solar cell characteristics.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.183-186
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• 2006

Reduction of optical losses in crystalline silicon solar cells by surface modification is one of the most important issues of silicon photovoltaics. Porous Si layers on the front surface of textured Si substrates have been investigated with the aim of improving the optical losses of the solar cells, because an anti-reflection coating and a surface passivation can be obtained simultaneously in one process. We have demonstrated the feasibility of a very efficient porous Si AR layer, prepared by a simple, cost effective, electrochemical etching method. Silicon p-type CZ (100) oriented wafers were textured by anisotropic etching in sodium carbonate solution. Then, the porous Si layer were formed by electrochemical etching in HF solutions. After that, the properties of porous Si in terms of morphology, structure and reflectance are summarized. The surface morphology of porous Si layers were investigated using SEM. The formation of a porous Si layer about $0.1{\mu}m$ thick on the textured silicon wafer result in an effective reflectance coefficient $R_{eff}$ lower than 5% in the wavelength region from 400 to 1000nm. Such a surface modification allows improving the Si solar cell characteristics.

• 한국표면공학회지
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• 제56권1호
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• pp.1-11
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• 2023

Lubricant-impregnated nanoporous surfaces (LIS), which is created by impregnating water-immiscible oil into nanoporous surface structure, have been explored considering wide range of application fields. Due to the lubricant impregnated in nanoporous structure, the surface shows extreme de-wetting with a high mobility of water droplets, so that various functionalities can be realized. The lubricant layer inhibits the contact of corrosive media to porous structure as well as metal substrate, thus the surface improves the corrosion resistance. The water on the surface freeze without any contact to solid porous structure, showing a low ice adhesion for de-icing an anti-icing. The extremely high mobility of water droplets on lubricant-impregnated porous surfaces also contributes the enhancement of condensation heat transfer as well as water harvesting from fog and moisture. Moreover, the bacteria adhesion on metal surface forming biofilms causing serious hygiene issues can be inhibited on the lubricantimpregnated surfaces. Despite of such superior functionalities, the lubricant-impregnated porous surface has a limitation of lubricant depletion by external flow of fluids. Therefore, extensive efforts to improve the durability of lubricant-impregnated surface are required for practical applications.

• 자연과학논문집
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• 제12권1호
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• pp.31-39
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• 2002

전류밀도와 에칭시간을 변화시키면서 제작된 다공질 규소 초격자의 표면에서 Nd:YAG 레이저의 제2 고조파를 발생시켰다. 이로부터 대칭구조가 바뀌고 유전율이 상승됨이 관측되었다.