• Title/Summary/Keyword: Porous nano ceramic structure

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Development of Nano Ceramic Structures for HEPA Type Breathing Wall (HEPA Filter형 숨쉬는 벽체용 나노세라믹 여재개발)

  • Kim, Jong-Won;Ahn, Young-Chull;Kim, Gil-Tae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.4
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    • pp.274-279
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    • 2008
  • In the perspective of saving energy in buildings, high performance of insulation and air tightness for improving the heating and the cooling efficiency has brought the positive effect in an economical view. However, these building energy saving technologies cause the lack of ventilation, which is the direct cause of increasing the indoor contaminants, and it is also very harmful to residents because they spend over 90% of their time in the indoor area. Therefore, the ventilation is important to keep indoor environment clean and it can also save energy consumption. In this study, a HEPA type breathing wall is designed as a passive ventilation system to collect airborne particles and to supply fresh outdoor air. To make fine porous structures, polymer nano fibers which were made by electro spinning method are used as a precursor. The nano fibers are coated with SiO2 nano particles and finally the HEPA type breathing wall is made by sintering in the electric furnace at $300\sim500^{\circ}C$. The pressure drops of nano ceramic structure are 8.2, 25.5 and 44.9 mmAq at the face velocity of 2.0, 5.9 and 8.8 cm/s, respectively. Also the water vapor permeability is $3.6g/m^2{\cdot}h{\cdot}mmHg$. In this research, the porous nano ceramic structures are obtained and the possibility for the usage of a material for HEPA type breathing wall can be obtained.

Pore Structure Modification and Characterization of Porous Cordierite with Chemical Vapor Infiltration (CVI) SiC Whisker (화학증착 탄화규소 휘스커에 의한 다공성 코디어라이트의 기공구조 개질 및 특성평가)

  • Kim, Ik-Whan;Kim, Jun-Gyu;Lee, Hwan-Sup;Choi, Doo-Jin
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.132-137
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    • 2008
  • The main purpose of this study is enhancing the filtering efficiency, performance and durability of filter by growing SiC whiskers on cordierite honeycomb substrate. The experiment was performed by Chemical Vapor Infiltration (CVI) in order to control pore morphology of substrate. Increasing the mechanical strength of porous substrate is one of important issues. The formation of "networking structure" in the pore of porous substrate increased mechanical strength. The high pressure gas injection to the specimen showed that a little of whiskers were separated from substrate but additional film coating enhanced the stability of whisker at high pressure gas injection. Particle trap test was performed. More nano-particle was trapped by whisker growth at the pore of substrate. Therefore it is expected that the porous cordierite which deposited the SiC whisker will be the promising material for the application as filter trapping the nano-particles.

Printability of coating layer with nano silica sol for inkjet printing high-end photo paper (나노 실리카 졸을 이용한 잉크젯 프린팅용 고품질 인쇄용지 도공층의 인쇄적성)

  • Kim, Hye-Jin;Nahm, Sahn;Han, Kyu-Sung;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.352-358
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    • 2019
  • In recent years, printing paper with a function of information delivery and aesthetic value has attracted a great attention with increasing market demand for coated paper that is capable of high quality printing. The coated paper for inkjet printing with high-quality of photorealistic grades requires the coating layer with a good wettability and porous surface structure in order to improve the printability of ink. In this study, the coated paper was prepared using polyvinyl alcohol (PVA) and surface treated nano silica sol with silane coupling agent. It was confirmed that the coating layer with surface treated nano silica sol showed a uniform pore distribution and flat surface roughness. Glossiness of the prepared printing paper was similar to that of commercial high quality photo paper. Especially, the coated paper with surface treated nano silica sol showed improved printability with excellent roundness of the printed dot of ink. These results indicates that the coating layer with excellent wettability and uniform pore distribution can be formed by using the nano-silica particles with improved dispersibility through the surface treatment of the silane coupling agent.

Nano-Structure Control of SiC Hollow Fiber Prepared from Polycarbosilane (폴리카보실란으로부터 제조된 탄화규소 중공사의 미세구조제어)

  • Shin, Dong-Geun;Kong, Eun-Bae;Cho, Kwang-Youn;Kwon, Woo-Tek;Kim, Younghee;Kim, Soo-Ryong;Hong, Jun-Sung;Riu, Doh-Hyung
    • Journal of the Korean Ceramic Society
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    • v.50 no.4
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    • pp.301-307
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    • 2013
  • SiC hollow fiber was fabricated by curing, dissolution and sintering of Al-PCS fiber, which was melt spun the polyaluminocarbosilane. Al-PCS fiber was thermally oxidized and dissolved in toluene to remove the unoxidized area, the core of the cured fiber. The wall thickness ($t_{wall}$) of Al-PCS fiber was monotonically increased with an increasing oxidation curing time. The Al-PCS hollow fiber was heat-treated at the temperature between 1200 and $2000^{\circ}C$ to make a SiC hollow fibers having porous structure on the fiber wall. The pore size of the fiber wall was increased with the sintering temperature due to the decomposition of the amorphous $SiC_xO_y$ matrix and the growth of ${\beta}$-SiC in the matrix. At $1400^{\circ}C$, a nano porous wall with a high specific surface area was obtained. However, nano pores grew with the grain growth after the thermal decomposition of the amorphous matrix. This type of SiC hollow fibers are expected to be used as a substrate for a gas separation membrane.

Synthesis of Ceria Nanosphere by Ultrasonic Spray Pyrolysis

  • Kim, Jong-Young;Kim, Ung-Soo;Cho, Woo-Seok
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.249-252
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    • 2009
  • Nanocrystalline ceria particles were prepared by using the ultrasonic spray pyrolysis method. The prepared ceria particles were found to be spherical and non-agglomerated by the SEM and TEM analyses. It was found that carrier gas influences the size and morphology. It was found that the air stream of carrier gas results in porous agglomerated structure of ceria abrasives, whereas solid nano-sphere can be obtained in a more oxidizing atmosphere.

Porous bioactive glass ceramics for bone-tissue regeneration

  • Yun, Hui-Suk;Kim, Seung-Eon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.7.2-7.2
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    • 2009
  • Nanoporous bioactive glass(NBG) ceramic with well interconnected pore structures were fabricated bytriblock copolymer templating and sol-gel techniques. Hierarchically porous BGbeads were also successfully synthesized by controlling the condition of solvent.The beads have hierarchically nano- and macro-pore structure with a sizesbetween several tens nanometers and several hundred micrometers. Both NBG andBG beads show superior bone-forming bioactivity and good in vitrobiodegradability. Biocompatibility both in vitro and in vivo were examed andwas revealed that it largely relies on the pore morphology as well ascomposition. Our synthetic process can be adapted for the purpose of preparingvarious bioceramics, which have excellent potential applications in the fieldof biomaterials such as tissue engineering and drug storage.

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Multi-scale simulation of drying process fey porous materials using molecular dynamics (part 3: multi-scale simulation) (분자동역학을 이용한 다공성 물질 건조공정 멀티스케일 시뮬레이션(3부: 멀티스케일 시뮬레이션))

  • Baik S.M.;Keum Y.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.168-174
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    • 2005
  • In this study, the numerical simulation of drying processes for porous materials is performed by employing the hierarchical multi-scale modeling and the nano-scale material properties obtained from the molecular dynamics simulation. The multi-scale simulation system is set up using pre- and post-processors and the drying process of electric porous ceramic insulator is simulated. The temperature, moisture, residual stress, and displacement distributions are compared with those based on homogenized properties.

Manufacture of High Density Graphite Using Coal Tar Pitch (석탄계 피치를 이용한 고밀도 흑연 제조)

  • Cho, Kwang-Youn;Kim, Kyung-Ja;Riu, Doh-Hyung;Lim, Kwang-Hyun;Kim, Jung-Il;Shin, In-Cheol;Lim, Yun-Soo;Joo, Heyok-Jong
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.839-845
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    • 2006
  • Graphite has hexagonal closed packing structure with two bonding characteristics; (1) van der waals bonding between c axis, and (2) covalent bonding in the a and b axis. The weak van der waals bonds cause self-lubricant property, and the strong covalent bonds cause excellent electric and thermal conductivity. Furthermore, graphite is chemically very inert because of the material composed of only carbon elements. Thus, graphite is very useful for mechanical sealing materials. However, Graphite have porous microstructure because starting materials of graphite produce many volatile during the manufacturing processes. This causes low density of graphite, which is unsuitable for the mechanical sealing materials. Thus, further impregnation process is generally needed to enhance the graphite density. In this work, high density graphite is prepared with the principle of densification when coke and pitch binder, prepared from thermal treatment of coal tar pitch, become dehydrogenation during graphitization or carbonization.

Fabrication of Solid Oxide Fuel Cells with Electron Beam Physical Vapor Deposition: I. Preparation of Thin Electrolyte Film of YSZ (전자빔 물리증착을 이용한 고체 산화물 연료전지의 제조 : I. YSZ 박막 전해질의 제조)

  • Kim, Hyoungchul;Koo, Myeong-Seo;Park, Jong-Ku;Jung, Hwa-Young;Kim, Joosun;Lee, Hae-Weon;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.85-91
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    • 2006
  • Electron Beam Physical Vapor Deposition (EB-PVD) was applied to fabricate a thin film YSZ electrolyte with large area on the porous NiO-YSZ anode substrate. Microstructural and thermal stability of the as-deposited electrolyte film was investigated via SEM and XRD analysis. In order to obtain an optimized YSZ film with high stability, both temperature and surface roughness of substrate were varied. A structurally homogeneous YSZ film with large area of $12\times12\;cm^2$ and high thermal stability up to $900^{\circ}C$ was fabricated at the substrate temperature of $T_s/T_m$ higher than 0.4. The smoother surface was proved to give the better film quality. Precise control of heating and cooling rate of the anode substrate was necessary to obtain a very dense YSZ electrolyte with high thermal stability, which affords to survive after post heat treatment for fabrication a cathode layer on it as well as after long time operation of solid oxide fuel cell at high temperature.

$Ba[Ce_{0.9}Y_{0.1}]O_{3-\delta}$ - Ni Composite Membrane for Hydrogen Separation by Aerosol Deposition Method (에어로졸 증착법[aerosol depostion method]에 의한 $Ba[Ce_{0.9}Y_{0.1}]O_{3-\delta}$ - Ni 수소분리막 제조)

  • Park, Young-Soo;Byeon, Myeong-Seob;Choi, Jin-Sub;Kim, Jin-Ho;Hwang, Kwang-Taek
    • Journal of Hydrogen and New Energy
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    • v.21 no.2
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    • pp.117-122
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    • 2010
  • BCY($Ba(Ce_{0.9}Y_{0.1})O_{3-\delta}$) oxide, shows high protonic conductivity at high temperatures, and are referred to as hydrogen separation membrane. For high efficiency of hydrogen separation ($H_2$ flux and selectivity) and low fabrication cost, ultimate thin and dense BCY-Ni layer have to be coated on a porous substrate such as $ZrO_2$. Aerosol depostion (AD) process is a novel technique to grow ceramic film with high density and nano-crystal structure at room-temperature, and would be applied to the fabrication process of AD integration ceramic layer effectively. XRD and SEM measurements were conducted in order to analyze the characteristics of BCY-Ni membrane fabricated by AD process.