• Structural Engineering and Mechanics
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• 제91권1호
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• pp.75-86
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• 2024

In this paper, the porous metal PM-35 is proposed as the filler material of filled thin-walled tubes (FTTs), and a series of experimental study is conducted to investigate the dynamic behavior and energy absorption performance of PM-35 filled thin-walled tubes under impact loading. Firstly, cylinder solid specimens of PM-35 steel are tested to investigate the impact mechanical behavior by using the Split Hopkinson pressure bar set (SHP); Secondly, the filled thin-walled tube specimens with different geometric parameters are designed and tested to investigate the feasibility of PM-35 steel applied in FTTs by the orthogonal test. According to the results of this research, it is concluded that PM-35 steel is with the excellent characteristics of high energy absorption capacity and low yield strength, which make it a potential filler material for FTTs. The micron-sizes pore structure of PM-35 is the main reason for the macroscopic mechanical behavior of PM-35 steel under impact loading, which makes the material to exhibit greater deformation when subjected to external forces and obviously improve the toughness of the material. In addition, PM-35 steel core-filled thin-wall tube has excellent energy absorption ability under high-speed impact, which shows great application potential in the anti-collision structure facilities of high-speed railway and maglev train. The parameter V0 is most sensitive to the energy absorption of FTT specimens under impact loading, and the sensitivity order of different variations to the energy absorption is loading speed V0>D/t>D/L. The loading efficiency of the FTT is affected by its different geometry, which is mainly determined by the sleeve material and the filling material, which are not sensitive to changes in loading speed V0, D/t and D/L parameters.

• 동력기계공학회지
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• 제11권2호
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• pp.44-50
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• 2007

The oxidation behavior of commercial pure titanium is investigated in the temperature range of $727^{\circ}C{\sim}950^{\circ}C$ in mixed gases. The weight change is measured by TGA during oxidation in mixed gases. The oxidation behavior indicated by weight gain or the growth of oxide layer is based on the linear rate law at high temperatures. The structure of the oxide scale formed during oxidation is analysed by optical microscopy, electron probe microanalyzer, scanning electron microscope and x-ray diffraction. Oxide scales have a $TiO_2$ structure, and are constituted with multi-layered or two layered porous external one and a dense internal one. Ti-O solid solution region is formed at the interface of metal and scale layer. The formation of oxide scale is influenced by the oxidation temperature, time, crystal structure and the condition of atmosphere.

• 한국환경과학회지
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• 제12권12호
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• pp.1269-1276
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• 2003

In order to know the effect of atuoclaving on the heavy metal removal using chitosan, lead removal capacities and removal rates by various chitosans in aqueous solution were compared according to the various autoclaving time. The lead removal efficiencies and removal rates by the autoclaved chitosan were found to be on the order of 15 min(98％) ＞ 10 min(95％) ＞ 30 min(83％) ＞ 5 min(53％) ＞ 60 min(47％) ＞ 0 min(22％) chitosan. The molecular weight of chitosan was decreased by the increase of autoclaving time. Therefore, the heavy metal removal capacity was not well correlated to the molecular weight. Langmuir isotherm was well fitted to experimental results of equilibrium adsorption on chitosan. In order to examine the process of lead removal by the autoclaved chitosan, TEMs, SEMs and FT-IR analyses were used. The surface of autoclaved chitosan was much more porous and the lead removal was mainly occurred on the surface of chitosan. The structure of autoclaved chitosan was same as that of controlled chitosan.

• 한국표면공학회지
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• 제32권3호
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• pp.444-446
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• 1999

The structure and composition of anodic films, formed on 6063 commercial aluminium alloy at constant current density of $1.5A/^dm2$ with various superimposed cathodic current ratio, in the range 0~33%, in the 11% $H_2SO_4$ with various concentration of $CuSO_4{\cdot}5H_2O$, in the range 0~75 g/l, without cathodic current are generally porous-type and no sign of Cu co-deposition appearance, suggesting that cathodic current is an important factor in the Cu co-deposition. Comparison with the anodic film thickness measurement results obtained from anodic film formed by direct anodic current and anodic film formed by superimposed various portion of cathodic current, the portion of cathodic current of input current increases with decrease of anodic film thickness and increases with increase of concentration of $Cu_2S{\;}and{\;}Cu_2O$ in the anodic film.

• Journal of Electrochemical Science and Technology
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• 제15권1호
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• pp.32-50
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• 2024

Diabetes mellitus is one of the common chronic diseases, seriously threating to human health. The continuous monitoring of blood glucose concentration can effectively prevent diabetic diseases. The sensing performance of glucose non-enzymatic sensors is mainly determined by working electrode materials. Metal-organic frameworks (MOFs) are recognized as promising candidate for glucose sensor application, due to its large surface areas, ordered porous structure and nearly infinite designability. In this review, the sensing performance, research progress and future challenge of non-enzymatic glucose sensors based on MOF-based materials in recent years are presented. We hope that this review would provide valuable technology guidance for high performance non-enzymatic glucose sensors based on MOFs.

• 공업화학
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• 제26권3호
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• pp.239-246
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• 2015

나노 탄소재료를 복합화하면 기존 재료의 특성을 유지하면서 그 효율을 극대화할 수 있다. 여기에 이종원소를 부가하면 전기화학적인 특성이 디자인되므로, 나노 탄소재료의 복합화를 통해 한 종류의 나노 재료로부터 여러 강점을 얻을 수 있다. 특히 탄소나노섬유와 금속산화물을 복합화하면 탄소나노섬유의 전기이중층 뿐만 아니라 금속산화물의 산화 환원 반응을 이용하여 비축전 용량, 고율 특성, 수명 특성이 향상되고 높은 수준의 출력밀도가 유지되는 고용량 슈퍼 캐퍼시터용 전극 소재를 개발할 수 있다. 본 총설에서는 탄소의 고출력특성과 금속산화물의 고에너지 특성이 동시에 발현되는 금속산화물계 탄소나노섬유복합체의 제법과 응용에 대한 최신연구를 다루도록 하겠다.

• Journal of Electrochemical Science and Technology
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• 제11권4호
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• pp.384-391
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• 2020

Due to its characteristics of light weight, high energy density, good safety, long service life, no memory effect, and environmental friendliness, lithium-ion batteries (LIBs) are widely used in various portable electronic products. The capacity and performance of LIBs largely depend on the performance of electrode materials. Therefore, the development of better positive and negative materials is the focus of current research. The application of metal organic framework materials (MOFs) derivatives in energy storage has attracted much attention and research. Using MOFs as precursors, porous metal oxides and porous carbon materials with controllable structure can be obtained. In this paper, rod-shaped Co-MOF-74 was grown on Ni Foam (NF) by hydrothermal method, and then Co-MOF-74/NF precursor was heat-treated to obtain rodshaped Co₃O₄/NF. Ni Foam was skeleton structured, which effectively relieved. The change of internal stress changes and destroys the structural volume of the electrode material and reduces the capacity attenuation. Co₃O₄/NF composite material has a specific discharge capacity of up to 1858 mA h/g for the first time, and a reversible capacity of up to 902.4 mA h/g at a current density of 200 mA/g, and has excellent rate and impedance performance. The synthesis strategy reported in this article opens the way to design high-performance electrodes for energy storage and electrochemical catalysis.

• 한국표면공학회지
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• 제55권2호
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• pp.51-62
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• 2022

Metal-organic framework (MOF) is one of the representative porous materials composed of metal ions and organic linkers. In spite of many advantages of the MOFs such as high specific surface area and ease of structure control, drawbacks have become obstacles to the practical use of them with poor electrical conductivity and chemical stability. The ZIF-8, which is consisted of zinc and imidazole linker, is one of the solutions to improve the chemical stability issue. In addition, composites using the ZIF-8 and carbonbased materials are widely used to enhance the electrical conductivity. In this regard, supercapacitor is very attractive field for using the composites, because most of carbon-based materials are porous and conductive. Also, for sensor applications, the ZIF-8 composite is suitable material to meet the requirement in terms of the selectivity and sensitivity. This review summarizes recent progress of the composite materials with the ZIF-8 and the carbon-based materials for the supercapacitors and the chemical sensors. In particular, the composites are classified into ZIF-8-graphene, ZIF-8-carbon nanotube and ZIF-8-other carbon-based material.

• Bulletin of the Korean Chemical Society
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• 제25권5호
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• pp.639-646
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• 2004

Metal treated activated carbons are prepared using various metals. Adsorption behaviors, morphologies, as well as antibacterial effects of metal treated samples are compared before and after solvent washing. Adsorption isotherms are used to characterize the porous structure of metal treated activated carbons before and after the solvent washing with acetone or ethyl alcohol. From these data, it is noticed that the changes in physicochemical properties of metal treated activated carbons depend on the solvents employed. Similar results are observed from BET data obtained from nitrogen adsorption isotherms. From scanning electron microscopy (SEM) studies, the changes in shape and size of metal particles are observed after the samples are washed with solvents. These changes result in different blocking effects, which, in turn, affect the adsorption behavior of metal treated activated carbons. X-ray diffraction (XRD) patterns of the samples treated with different metals are different each other. High intense sharp peaks attributed to metals are observed from silver treated samples, while the peaks are not observed from copper treated samples. To compare thermodynamic behavior of metal treated activated carbons washed with different type of solvents, differential scanning calorimetric (DSC) analysis is carried out. The analysis shows similar endothermic curves for all of the samples. Finally, antibacterial effects of metal treated activated carbon against Escherichia coli are discussed. Comparing the effects among the metals employed, highest effects are obtained from Cd, while lowest effects are obtained from Cu. Antibacterial activity becomes higher with the increase of the amount of metals treated, Optimum concentrations of metals to treat activated carbons, obtained from a shake flask test, are known to be 0.4, 0.1, and 0.6 moles for Ag, Cd, and Cu, respectively.

• 전기화학회지
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• 제2권3호
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• pp.130-133
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• 1999

본 연구에서는 음주 측정에 적용할 수 있는 다공질 실리콘층으로 된 저농도의 캐퍼시턴스형 알코올 가스 측정용 센서를 제작하고, 상온에서 그 특성을 측정하였다. 기존의 $SnO_2$등의 금속 산화물 반도체를 이용한 센서는 저농도의 알코올을 정확하게 검지하기에 어려울 뿐만 아니라 감도를 높이기 위해 $200\~400^{\circ}C$로 가열이 필요하였다. 이에 비해 다공질 실리콘층을 이용한 센서는 넓은 표면적을 갖고 있어 상온에서도 감도가 양호할 뿐만 아니라 집적화 센서로 제작이 용이한 점을 갖고 있다. 실험은 증류수에 희석한 알코올 수용액을 체온과 같은 $36^{\circ}C$를 비롯하여 25와 $45^{\circ}C$로 유지한 상태에서 0에서 $0.5\%$의 농도범위에 대해서 $0.05\%$의 간격으로 120 Hz와 1 kHz의 두 주파수에서 측정하였다. 그 결과, 양호한 선형성과 함께 120 Hz의 주파수에서 측정하였을 때, $0.1\%$의 알코올 농도의 증분마다 $25,\;36,\;45^{\circ}C$의 알코올 수용액의 온도에 대해 각각 1.1, 2.6 및 $4.6\%$로 캐퍼시턴스의 증가율을 보였다.